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The Influence of the Solvents on the Electronic Spectra of Some Aromatic Molecules and their Dipole Moments in the Excited State. The Solvent Effects on the Aniline Electronic Band at 34,870 cm-1

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Chemical Reactivity in Liquids

Abstract

In a preceeding series of papers [1–8], was investigated the influence of the solvents on the spectral bands of benzene, chlorobenzene, bromobenzene, toluene, anisole, benzaldehyde, nitrobenzene, and benzonitrile with the aim to establish the behaviour differences between monosubstituted benzene molecules with the first and second order susbstituents in solutions, i.e. to contribute to the elucidation of the interactions in the solute-solvent systems determining the spectral displacements, and to evaluate the dipole moments of the solute molecules in their excited states as indices of reactivity. In the series of monosubstituted benzenes the aniline molecule has a place apart due to the presence of the amino group, and it is the object of this investigation.

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References

  1. V. Macovei, Rev. Roumaine Chim., 20: 1413 (1975).

    CAS  Google Scholar 

  2. V. Macovei, Rev. Roumaine Chim., 21: 193 (1976)

    CAS  Google Scholar 

  3. V. Macovei, Anal. Sti. Univ. “Al.I.Cuza”, Iasi, Sect.I,b,22: 51 (1976)

    CAS  Google Scholar 

  4. V. Macovei, Rev. Roumaine Chim., 25: 651, (1980)

    CAS  Google Scholar 

  5. V. Macovei and G. Bourceanu, unpublished results

    Google Scholar 

  6. V. Macovei, Anal. Sti. Univ. “Al.I.Cuza” Iaso, Sect.I,B,22:61 (1976)

    CAS  Google Scholar 

  7. V. Macovei, Rev. Roumaine Chim., 21: 1137 (1976)

    CAS  Google Scholar 

  8. V. Macovei, Rev. Roumaine Chim., 21: 1137 (1976)

    CAS  Google Scholar 

  9. F.A. Matsen, J. Am. Chem. Soc., 72: 5243 (1950)

    Article  CAS  Google Scholar 

  10. A.L. Sklar, J. Chem. Phys., 7: 984 (1939)

    Article  CAS  Google Scholar 

  11. K.F. Herzfeld, Chem. Rev., 41: 233 (1942)

    Article  Google Scholar 

  12. A.L. Sklar, Rev. Mod. Physik., 14: 232 (1942)

    Article  CAS  Google Scholar 

  13. H. Huckel, Z. Physik, 72: 310 (1931)

    Article  CAS  Google Scholar 

  14. W. Wheland, J. Am. Chem. Soc., 64: 900 (1931)

    Article  Google Scholar 

  15. S. Nagakura and H. Baba, J. Atm. Chem. Soc., 74: 5693 (1952)

    Article  CAS  Google Scholar 

  16. H. Sponer and E. Teller, Rev. Mod. Phys., 13: 76 (1941)

    Article  Google Scholar 

  17. H.H. Jaffe and M. Orchin, “Theory and Applications of Ultraviolet Spectroscopy” Wiley, New York (1964)

    Google Scholar 

  18. L. Doub and J.M. Vandenbelt, J. Am. Chem. Soc., 69: 2714 (1947)

    Article  CAS  Google Scholar 

  19. P.C. Upadhya, G. Baruah, K.N. Upadhya and D.K. Rai, Isr J. Chem, 9: 7 (1971)

    CAS  Google Scholar 

  20. L. Doub and J.M. Vandenbelt, J. Am. Chem. Soc., 71: 4114 (1949)

    Article  Google Scholar 

  21. L. Doub and J.M. Vandenbelt, J. Am. Chem. Soc., 77:4535 (1955)

    Article  CAS  Google Scholar 

  22. N. Fuson, C. Garrigou-Lagrange and M.L. Josien, Spectrochim. Acta., 16: 106 (1960)

    Article  CAS  Google Scholar 

  23. F.A. Trombetti and C. Zauli, Boll. Sci. Fac. Chim., Bologna, 21: 202 (1963)

    CAS  Google Scholar 

  24. N.S. Bayliss and E.G. Mc Rae, J. Phys. Chem., 58, 1002 (1964)

    Article  Google Scholar 

  25. F. London, Z. Physik, 63: 245 (1930)

    Article  CAS  Google Scholar 

  26. O. Sverdlova,Opt. i Spektrosk., 2: 31 (1963)

    CAS  Google Scholar 

  27. E.G. McRae, J. Phys. Chem., 61:562 (1957)

    Article  CAS  Google Scholar 

  28. W.J. Hehre, L. Radom and J.A. Pople, J. Am. Chem. Soc., 94: 1496 (1972)

    Article  CAS  Google Scholar 

  29. O.A. Osipov, V.J. Minkin, and A.D. Garnovskii, “Spravochinic po Dipol’nym Momentam”, Izd. “Vysshaia Shkola”, Moskva, 1971.

    Google Scholar 

  30. A.L. McClellan, “Tables of Experimental Dipole Moments”, W.H. Freeman, San Francisco, California, 1963

    Google Scholar 

  31. N. Mataga and T. Kubota, “Molecular Interactions and Electronic Spectra”, M. Dekker, Inc., New-York, 1966

    Google Scholar 

  32. D. York, Canad. J. Phys., 44: 1079 (1966)

    Article  Google Scholar 

  33. P. Suppan, J. Chem. Soc. (A), 1968, 3125

    Google Scholar 

  34. M. Lamotte, G.A. Gerhold and J. Joussot-Dubien, J. Chim. Phys., 67: 2006 (1970)

    CAS  Google Scholar 

  35. “Manualul Inginerului Chimist”, vol.1, Ed. Tehnica, Bucuresti, 1951

    Google Scholar 

  36. L.S. Prabhumirashi, D.K. Narayanann Kutty and A.S. Bhide, Spectrochim, Acta, 39A: 663 (1983)

    CAS  Google Scholar 

  37. N. Mataga, Bull. Chem. Soc. Japan, 36: 1607 (1963)

    Article  CAS  Google Scholar 

  38. P. Suppan, Spectrochim. Acta, 41 A: 1353 (1985)

    Google Scholar 

  39. A.E. Lutskii, S. Gol’berkova and P.M. Bugai, Zhur.obshchei Khim, 33: 1624 (1963)

    CAS  Google Scholar 

  40. C.V. Cumper and A. Singleton, J. Chem. Soc., 1968 B, 649

    Google Scholar 

  41. S. Nagakura and H. Baba, J. Am. Chem. Soc., 74: 5693 (1952)

    Article  CAS  Google Scholar 

  42. W. Gordy, W.V. Smith and R.F. Trambarulo, “Microvave Spectroscopy” Wiley and Sons, New York, 1953

    Google Scholar 

  43. A. Few and J.W. Smith, J. Chem. Soc., 1938, 1958

    Google Scholar 

  44. S. Nagakura and H. Baba, J. Chem. Soc., Japan, 71: 527 (1950)

    CAS  Google Scholar 

  45. J.C.D. Brand, D.R. Williams and T.J. Cook, J. Mol. Spectroscopy, 20: 359 (1966)

    Article  CAS  Google Scholar 

  46. T.J. Bhattacharyga, Indian J. Phys., 36: 33 (1962)

    Google Scholar 

  47. S.F. Mason, J. Chem. Soc., 1958, 3619

    Google Scholar 

  48. P. Kreuger, Canad. J. Chem., 40: 2300 (1962)

    Article  Google Scholar 

  49. D.G. Lister and J.K. Tiler, Chem. Commun., 152 (1966)

    Google Scholar 

  50. R. Andersen and J.M. Prausnitz, J. Chem. Phys., 39: 1225 (1963)

    Article  Google Scholar 

  51. N.S. Rao and K.K. Jatkar, Quart. J. Ind. Sci., 51: 65 (1942) 6:1 (1943)

    Google Scholar 

  52. G. Briegleb, “Elektronen-Donator-Acceptor Komplexe”, Springer Verlag, Berlin, 1967

    Google Scholar 

  53. A.F. Kapustinskii and S.I. Drakin, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, 5: 435 (1947)

    Google Scholar 

  54. W.E. Wyat, Trans. Faraday Soc., 25: 48 (1929)

    Article  Google Scholar 

  55. R.P. Rostogi and R.K. Nigam, Trans. Faraday Soc., 55: 2005 (1959)

    Article  Google Scholar 

  56. J.R. Goates, R.J. Sullivan and J.B. Ott, J. Chem. Phys., 63: 589 (1954)

    Google Scholar 

  57. B.S. Neporent and N.G. Bakhshiev, Opt.i. Spektrosk., 8: 77 (1960)

    Google Scholar 

  58. A. Weissberger, E.S. Proskauer, J.A. Riddich and E.E. Toops, “Technique of Organic Chemistry”, vol.VII - ″Organic “Organic Solvents”, 2-nd ed., Interscience, New-York, 1955

    Google Scholar 

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Authors and Affiliations

  1. The Physical Chemistry Laboratory, The Faculty of Technological chemistry, The Politechnical Institute, Iassy, Rumania

    Vasile Macovei & Ana Sasu

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  1. Vasile Macovei
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  2. Ana Sasu
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  1. Pierre and Marie Curie University, Paris, France

    Michel Moreau  & Pierre Turq  & 

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© 1988 Plenum Press, New York

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Macovei, V., Sasu, A. (1988). The Influence of the Solvents on the Electronic Spectra of Some Aromatic Molecules and their Dipole Moments in the Excited State. The Solvent Effects on the Aniline Electronic Band at 34,870 cm-1 . In: Moreau, M., Turq, P. (eds) Chemical Reactivity in Liquids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1023-5_11

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  • DOI: https://doi.org/10.1007/978-1-4613-1023-5_11

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8297-6

  • Online ISBN: 978-1-4613-1023-5

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