Abstract
The study of chemistry is the study of chemical reactivity, — of how reactions take place. It is known that chemical transformations take place through a sequence of elementary reactions. These elementary reactions determine the outcome of the reaction sequence. In the past one determined the overall reaction, possibly determined the kinetics of the reaction, and the dependence on parameters such as the dielectric constant or the proton affinity of the solvent. From these data one then created a mechanism which explained the reactions. Now it has become possible to measure the elementary reactions that make up mechanisms. These measurements have become sufficiently routine so that the chemist, who wants to learn more about a particular chemical reaction, can find a technique to help him.
Work performed under the auspices of the Office of Basic Energy Sciences, Division of Chemical Science, US-DOE under contract number W-31-109-ENG-38
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
Beck, G., J. Radioanal. Nucl. Chem. 101, 151 (1986).
Beck, G., Rev. Sci. Instrum. 47, 849 (1976).
Beck, G., Rev. Sci. Instrum. 45, 318 (1974).
Beck, G., Rev. Sci. Instrum. 50, 1147 (1979).
Beck, G., Lindenau, D. and Schnabel, W., Macromolecules 10, 135 (1977).
Beitz, J., Jonah, C. and Sullivan, J. C. Radiochimica Acta 40, 7 (1986).
Bernasconi, C.F., Ed. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1986.
Bromberg, A., Schmidt, K. H. and Meisel, D., J. Am. Chem. Soc. 107, 83 (1985).
Chance, B. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Hammes, G.G., Ed. Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1974, p. 5.
Closs, G. L., Calcaterra, L. T., Green, N. J., Penfield, K. W. and Miller, J. R. J. Phys. Chem. 90, 3673 (1986).
Dorfman, L. M. and Sauer, M. C. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Bernasconi, C.F., Ed., Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1986, p. 493.
Eyring, E. M. and Hemmes, P. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Bernasconi. C.F., Ed., Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1986, p. 219.
Eigen, M. and De Mayer, L. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Hammes. G.G., Ed., Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1974, p. 63.
Gratton, E., Jameson, D. M., and Hall, R. D., Ann. Rev. Biophys. Bioeng. 13, 105 (1984).
Gratton, E., Spectroscopy 1 #6, 28 (1985).
Hammes, G.G., Ed. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1974.
Hunt, J. W., Greenstock, C. L. and Bronskill, M. J. Int. J. Radiat. Phys. Chem. 4, 87 (1972).
Jonah, C. D., Matheson, M.S. and Meisel, D. J. Am. Chem. Soc. 100, 1449 (1978).
Kinoshia, K., Ito, M., Suzuki, V. Rev. Sci. Instrum. 58, 932(1987).
Knoche, W. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Hammes, G.G., Ed. Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1974, p. 187.
Knoche, W. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Bernasconi, C.F., Ed., Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1986, p. 191.
Laidler, K. J. “Chemical Kinetics”, second edition, McGraw-Hill: New York, 1965.
Luthjens, L. H., Rev. Sci. Instrum. 44, 1661 (1973).
Maughan, R. L., Michael, B. D. and Anderson, R. F. Radiat. Phys. Chem. 11, 229 (1978).
Qin, L., Tripathi, G. N. R. and Schuler, R. H. J. Phys. Chem. 91, 1905 (1987).
Schmidt, K. H. Int. J. Radiat. Phys. Chem. 4, 439 (1972).
Schmidt, K. H., Gordon, S., and Mulac, W. A. Rev. Sci. Instrum. 47, 356 (1976).
Schmidt, K. H., Gordon, S., Thompson, M., Sullivan, J. C. and Mulac, W. A. Radiat. Phys. Chem. 21, 321 (1983).
Schwarz G. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Bernasconi, C.F., Ed., Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1986, p. 27.
Stuehr, J. E. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Bernasconi, C.F., Ed., Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1986, p. 247.
Sullivan, J. C., Rydberg, J., Miller, W. F. Acta Chem. Scand. 13, 2029(1959).
Swift T. J. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Hammes, G.G., Ed., Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1974, p. 521.
Trifunac, A. D., Lawler, R. G., Bartels, D. M. and Thurnauer, M. C., Prog. Reaction Kinetics 14, 43 (1986).
Turner, D. H. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Bernasconi, C.F., Ed., Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1986, p. 141.
Warman, J. M. in “The Study of Fast Processes and Transient Species by Electron Pulse Radiolysis”, Baxendale, J.H., and Busi, F. Eds., D. Reidel: Dordrecht, Holland, 1982, p. 129.
Warman, J. M, De Haas, M. P., Oervering, H., Verhoeven, J. W., Paddon-Row, M. N., Oliver, A. M. and Hush, N. S., Chem. Phys. Lett., 128, 95 (1986).
West, M. A. in “Investigations of Rates and Mechanisms of Reactions”, Techniques of Chemistry, Bernasconi, C.F., Ed., Vol. 6, Part II, 3rd Edition, Wiley Interscience: New York, 1986, p. 391
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1988 Plenum Press, New York
About this chapter
Cite this chapter
Jonah, C.D. (1988). Techniques for Studying Fast Reactions in Liquids. In: Moreau, M., Turq, P. (eds) Chemical Reactivity in Liquids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1023-5_1
Download citation
DOI: https://doi.org/10.1007/978-1-4613-1023-5_1
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-8297-6
Online ISBN: 978-1-4613-1023-5
eBook Packages: Springer Book Archive