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Photoemission Phenomena at Metallic and Semiconducting Electrodes

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Abstract

The original photoelectric effect was discovered by Hertz(1) in 1887 while he was investigating the properties of electromagnetic waves. It was observed that a spark would jump a gap between two electrodes more readily when the electrodes were illuminated with light, ultraviolet light having a greater effectiveness than light from the visible region of the spectrum. This simple observation, however, was to have profound impact on our conception of how radiation and matter interact.

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References

  1. H. Hertz, Ann. Phys. 31, 421, 983 (1887).

    Google Scholar 

  2. A. Einstein, Ann. Phys. 17, 132 (1905).

    CAS  Google Scholar 

  3. O. W. Richardson, Phil. Mag. 23, 615 (1912); 24, 570 (1912).

    Google Scholar 

  4. J. J. Thomson, Phil Mag. 2, 674 (1926).

    CAS  Google Scholar 

  5. W. Uspensky, Z. Physik 40, 456 (1926);

    CAS  Google Scholar 

  6. A. L. Hughes and L. A. DuBridge, Photoelectric Phenomena, McGraw-Hill, New York (1932), p. 202.

    Google Scholar 

  7. G. Wentzel, Probleme der Modernen Physik, Sommerfeld Festschrift, Leipzig (1928), p. 79.

    Google Scholar 

  8. R. H. Fowler, Phys. Rev. 38, 45 (1931).

    CAS  Google Scholar 

  9. A. Modinos, Field, Thermionic and Secondary Electron Emission Spectroscopy, Plenum Press, New York (1984).

    Google Scholar 

  10. E. C. Becquerel, C. R. Acad. Sci. 9, 143 (1839).

    Google Scholar 

  11. Yu. Ya. Gurevich, Yu. V. Pleskov, and Z. A. Rotenberg, Photoelectrochemistry, Consultants Bureau, New York (1980).

    Google Scholar 

  12. H. Berg, Naturwissenschaften 47, 320 (1960).

    CAS  Google Scholar 

  13. H. Berg and P. Reissmann, J. Electroanal. Chem. 24, 427 (1970).

    CAS  Google Scholar 

  14. M. Heyrovsky, Nature 200, 1356 (1965).

    Google Scholar 

  15. M. Heyrovsky, Croat. Chem. Acta. 45, 247 (1973).

    CAS  Google Scholar 

  16. L. I. Korshunov, Ya. M. Zolotovitskii, and V. A. Benderskii, Russ. Chem. Rev. 40(8), 699 (1971).

    Google Scholar 

  17. G. C. Barker and A. W. Gardner, Osnovnye voprosy sovremennoi teoreticheskvi Electrokhimii, p. 118, MIR, Moscow (1965).

    Google Scholar 

  18. G. C. Barker, A. W. Gardner, and G. Bottura, J. Electroanal, Chem. 45, 21 (1973).

    CAS  Google Scholar 

  19. G. C. Barker, Electrochim. Acta 13, 1221 (1968).

    CAS  Google Scholar 

  20. A. M. Brodskii and Yu. Ya. Gurevich, Sov. Phys. JETP 27, 114 (1968).

    Google Scholar 

  21. D. E. Grider, Ph.D. thesis, Iowa State University (1980).

    Google Scholar 

  22. R. Borjas Severeyn, Ph.D. thesis, Louisiana State University (1984).

    Google Scholar 

  23. R. H. Fowler, Phys. Rev. 38, 45 (1931).

    CAS  Google Scholar 

  24. R. H. Fowler, Statistical Mechanics, Cambridge Press, Cambridge, Chapter XI (1955).

    Google Scholar 

  25. L. A. DuBridge and W. W. Roehr, Phys. Rev. 39, 99 (1932).

    CAS  Google Scholar 

  26. L. A. DuBridge, Phys. Rev. 39, 108 (1932).

    CAS  Google Scholar 

  27. D. B. Matthews and S. U. M. Khan, Aust. J. Chem. 28, 253 (1975).

    CAS  Google Scholar 

  28. J. O’M. Bockris and S. U. M. Khan, Quantum Electrochemistry, Plenum Press, New York (1979), Chapter 12.

    Google Scholar 

  29. A. I. Baz, Ya. B. Zeldovich, and A. M. Perelomov, Scattering, Reactions, and Disintegrations in Nonrelativistic Quantum Mechanics, Nauka, Moscow (1966).

    Google Scholar 

  30. R. G. Newton, Scattering Theory of Waves and Particles, McGraw-Hill, New York (1967).

    Google Scholar 

  31. A. B. Brodskii and Yu. Ya. Gurevich, Dokl. Akad. Nauk SSSR 178(4), 868 (1968).

    CAS  Google Scholar 

  32. Yu. Ya. Gurevich, A. M. Brodskii, and V. G. Levich, Electrokhimiya 3, 1302 (1967).

    CAS  Google Scholar 

  33. Yu. V. Pleskov and Z. A. Rotenberg, J. Electroanal. Chem. 20, 1 (1969).

    CAS  Google Scholar 

  34. A. M. Brodskii, Yu. Ya. Gurevich, and V. G. Levich, Phys. Status Solidi 40, 139 (1970).

    Google Scholar 

  35. H. Gerischer, D. M. Kolb, and J. K. Sass, Adv. Phys. 27, 437 (1978).

    CAS  Google Scholar 

  36. L. I. Korshunov, Ya. M. Zolotovitskii, and V. A. Benderskii, Electrokhimiya 4, 499 (1968).

    CAS  Google Scholar 

  37. Z. A. Rotenberg and Yu. V. Pleskov, Electrokhimiya 4, 826 (1968).

    CAS  Google Scholar 

  38. R. DeLevie and J. C. Kreuser, J. Electroanal Chem. 21, 221 (1969).

    CAS  Google Scholar 

  39. Yu. V. Pleskov, Z. A. Rotenberg, and V. I. Lakomov, Electrokhimiya 6, 1787 (1970).

    CAS  Google Scholar 

  40. Yu. V. Pleskov and Z. A. Rotenberg, Russ. Chem. Rev. 41, 21 (1972).

    Google Scholar 

  41. Ya. M. Zolotovitskii, L. I. Korshunov, and V. A. Benderskii, Izv. Akad. Nauk. SSSR 4, 802 (1972).

    Google Scholar 

  42. Z. A. Rotenberg, Electrokhimiya 10, 1031 (1974).

    CAS  Google Scholar 

  43. V. V. Yakushev, A. M. Skundin, and V. S. Bagotskii, Elektrokhimiya 20, 99 (1984).

    CAS  Google Scholar 

  44. G. D. Mahan, in: Electron and Ion Scattering of Solids (L. Fiermans, J. Vennik, and W. Dekeyser, eds.), NATO Adv. Study Inst. Ser., Ser. B. Physics, Vol. 32, pp. 1–53, Plenum Press, New York.

    Google Scholar 

  45. G. D. Mahan, Phys. Rev. B 2, 4334 (1970).

    Google Scholar 

  46. P. J. Feibelman and D. E. Eastman, Phys. Rev. B 10, 4932 (1974).

    CAS  Google Scholar 

  47. I. Adawi, Phys. Rev. 134, A788 (1964).

    Google Scholar 

  48. J. K. Sass and H. J. Lewerenz, J. Phys. C 5, 277 (1972).

    Google Scholar 

  49. A. M. Brodskii and Yu. Ya. Gurevich, Theory of Electronic Emission from Metals, Nauka, Moscow (1973).

    Google Scholar 

  50. W. N. Hansen, in: Advances in Electrochemistry and Electrochemical Engineering (P. Delahay and C. W. Tobias, eds.), Vol. 9, pp. 1–60, John Wiley and Sons (1973).

    Google Scholar 

  51. L. I. Korshunov, Ya. M. Zolotovitskii, and V. A. Benderskii, Elektrokhimiya 5, 716 (1969).

    CAS  Google Scholar 

  52. J. K. Sass and H. Gerischer, in: Photoemission and the Electronic Properties of Surfaces, (B. Feuerbacher et al., eds.), Chapter 16, Wiley-Interscience, New York (1978).

    Google Scholar 

  53. B. Feuerbacher and R. F. Willis, J. Phys. C 9, 169 (1976).

    CAS  Google Scholar 

  54. D. Mohilner, Electronanalytical Chemistry (A. J. Bard, ed.), Vol. 1, p. 241, Marcel Dekker, New York (1966).

    Google Scholar 

  55. Z. A. Rotenberg, V. I. Lakomov, and Yu. V. Pleskov, Elektrokhimiya 9, 11 (1973).

    CAS  Google Scholar 

  56. Z. A. Rottenberg, V. I. Lakomov, and Yu. V. Pleskov, Elektrokhimiya 9, 152 (1973).

    Google Scholar 

  57. Z. A. Rotenberg and Yu. V. Pleskov, Electrokhimya 5, 982 (1969).

    CAS  Google Scholar 

  58. D. Grider, P. Lange, H. Neff, and K. Ho, Vacuum 31, 563 (1981).

    CAS  Google Scholar 

  59. R. G. Kokilashvili, V. V. Eletskii, and Yu. V. Pleskov, Elektrokhimiya 20, 1075 (1984).

    CAS  Google Scholar 

  60. W. E. Spicer and R. C. Eden, Int. Conf. on the Physics of Semiconductors, Proceedings, July 23–29, 1968, Vol. 1, Nauka, Leningrad (1968).

    Google Scholar 

  61. E. O. Kane, Phys. Rev. 127, 131 (1962).

    CAS  Google Scholar 

  62. G. W. Gobeli and F. G. Allen, Phys. Rev. 127, 141 (1962).

    CAS  Google Scholar 

  63. M. D. Krotova and Yu. V. Pleskov, Sov. Phys. Solid State 15, 1871 (1974).

    Google Scholar 

  64. Yu. Ya. Gurevich, Elektrokhimiya 8, 1564 (1972).

    CAS  Google Scholar 

  65. Yu. Ya. Gurevich, M. D. Krotova, and Yu. V. Pleskov, J. Electroanal. Chem. 75, 339 (1977).

    CAS  Google Scholar 

  66. K. Gottfied, Quantum Mechanics, Vol. 1: Fundamentals, The Benjamin Cumming Co., London (1966), pp. 443–444.

    Google Scholar 

  67. J. Callaway, Quantum Theory of the Solid State, Academic Press, New York (1974), pp. 24–28.

    Google Scholar 

  68. G. Gilat, J. Comp. Phys. 10, 432 (1972).

    CAS  Google Scholar 

  69. Ref. 66, pp. 521–525.

    Google Scholar 

  70. J. J. Scheer and J. Van Laar, Phillips Research Reports 16, 323 (1961).

    CAS  Google Scholar 

  71. G. W. Gobeli and F. G. Allen, in: Solid Surfaces (H. C. Gattor, ed.), p. 402, North-Holland Publishing Co., Amsterdam (1964).

    Google Scholar 

  72. G. W. Gobeli, F. G. Allen, and E. O. Kane, Phys. Rev. Lett. 21, 94 (1964).

    Google Scholar 

  73. G. W. Gobeli and F. G. Allen, in: Semiconductors and Semimetals (R. K. Willardson and A. C. Beer, eds.), Vol. 2, pp. 253–280, Academic Press, New York (1966).

    Google Scholar 

  74. G. W. Gobeli and F. G. Allen, J. Chem. Phys. Solids 14, 23 (1960).

    CAS  Google Scholar 

  75. T. E. Fischer, Surface Sci. 13, 30 (1969).

    CAS  Google Scholar 

  76. W. A. Harrison, Solid State Theory, Dover Publications, New York (1979), pp. 140–142.

    Google Scholar 

  77. C. Kittle, Introduction to Solid State Theory, 5th Edition, John Wiley, New York (1976), pp. 218–219.

    Google Scholar 

  78. Yu. Ya. Gurevich and Yu. V. Pleskov, in: Semiconductors and Semimetals (R. K. Willardson and A. C. Beer, eds.), Vol. 19, Chapter 4, Academic Press, New York (1983).

    Google Scholar 

  79. Yu. V. Pleskov, in: Comprehensive Treatise of Electrochemistry (J. O’M. Bockris, B. E. Conway, and E. Yeager, eds), Vol. 1, Chapter 6, Plenum Press, New York (1980).

    Google Scholar 

  80. R. Borjas Severeyn and R. J. Gale, J. Electroanal. Chem. 150, 619 (1983).

    Google Scholar 

  81. M. D. Krotova and Yu. V. Pleskov, Fiz. Tverd. Tela. 15, 2806 (1973).

    CAS  Google Scholar 

  82. E. Meyer, Dissertation, Tech. Univ., Munich (1973).

    Google Scholar 

  83. G. V. Boikova, M. D. Krotova, and Yu. V. Pleskov, Elektrokhimiya 12, 922 (1976).

    CAS  Google Scholar 

  84. Yu. Ya. Gurevich, M. D. Krotova, and Yu. Ya. Pleskov, J. Electroanal Chem. 75, 339 (1977).

    CAS  Google Scholar 

  85. R. Borjas Severeyn and R. J. Gale, Mol. Cryst. Liq. Cryst. 107, 227 (1984).

    Google Scholar 

  86. C. E. Krohn and J. S. Thompson, Chem. Phys. Lett. 65, 132 (1979).

    CAS  Google Scholar 

  87. R. E. Malpas, K. Itaya, and A. J. Bard, J. Am. Chem. Soc. 101, 2535 (1979).

    CAS  Google Scholar 

  88. G. V. Amerongen, D. Guyomard, R. Heindl, M. Herlem, and J.-L. Sculfort, J. Electrochem. Soc. 129, 1998 (1982).

    Google Scholar 

  89. M. Herlem, D. Guyomard, C. Mathieu, J. Belloni, and J.-L. Sculfort, J. Phys. Chem. 88, 3826 (1984).

    CAS  Google Scholar 

  90. J. Vondrak, J. Buldska, I. Jakubec, and J. Velek, Electrochim. Acta 29, 315 (1984).

    CAS  Google Scholar 

  91. J. O’M. Bockris and K. Uosaki, J. Electrochem. Soc . 125, 223 (1977).

    Google Scholar 

  92. J. O’M. Bockris, K. Uosaki, and H. Kita, J. Appl. Phys. 52, 808 (1981).

    CAS  Google Scholar 

  93. J. O’M. Bockris and K. Uosaki, in: (J. B. Goodenough and M. Stanley Whittingham, eds.) Adv. Chem. Ser. No. 163, Solid State Chemistry of Energy Conversion and Storage, pp. 33–70, American Chemical Society, Washington, D.C. (1977).

    Google Scholar 

  94. J. O’M. Bockris and K. Uosaki, Int. J. Hydrogen Energy 3, 157 (1977).

    Google Scholar 

  95. H. Gerischer, in: Advances in Electrochemistry and Electrochemical Engineering (P. Delahay and C. W. Tobias, eds.), Vol. 1, p. 139, John Wiley and Sons, New York (1961).

    Google Scholar 

  96. A. J. Nozik, Ann. Rev. Phys. Chem. 29, 189 (1978).

    CAS  Google Scholar 

  97. A. J. Nozik, in: Photochemical Conversion and Storage of Solar Energy (J. S. Connolly, ed.), Chapter 10, Academic Press, New York (1981).

    Google Scholar 

  98. D. S. Boudreaux, F. Williams, and A. J. Nozik, J. Appl Phys. 51, 2158 (1980).

    CAS  Google Scholar 

  99. G. Cooper, J. A. Turner, B. A. Parkinson, and A. J. Nozik, J. Appl Phys. 54, 6463 (1983).

    CAS  Google Scholar 

  100. F. Williams, and A. J. Nozik, Nature 271, 137 (1978).

    CAS  Google Scholar 

  101. J. A. Turner and A. J. Nozik, Appl Phys. Lett. 41, 101 (1982).

    CAS  Google Scholar 

  102. A. J. Nozik, in: Photovoltaic and Photoelectrochemical Solar Energy Conversion (F. Cardon, W. P. Gomes, and W. Dekeyser, eds.), pp. 263–312, Plenum Press, London, published in cooperation with NATO Scientific Affairs Division (1981).

    Google Scholar 

  103. A. J. Nozik, D. S. Boudreaux, R. R. Chance, and F. Williams, in: Interfacial Photoprocesses: Energy Conversion and Synthesis (M. S. Wrighton, ed.), Adv. Chem. Ser. No. 184, pp. 155–171, American Chemical Society, Washington, D. C. (1980).

    Google Scholar 

  104. J. A. Turner, J. Manassen, and A. J. Nozik, Appl. Phys. Lett. 37, 488 (1980).

    CAS  Google Scholar 

  105. F. Williams and A. J. Nozik, Nature 312, 21 (1984).

    CAS  Google Scholar 

  106. M. S. Matheson, in: Physical Chemistry: An Advanced Treatise (H. Eyring, ed.), Vol. 7, p. 533, Academic Press, New York (1975).

    Google Scholar 

  107. R. Gilmont and S. J. Silvis, Am. Lab., December, 46 (1974).

    Google Scholar 

  108. D. T. Sawyer and J. L. Roberts, Jr., Experimental Electrochemistry for Chemists, John Wiley and Sons, New York (1974).

    Google Scholar 

  109. D. D. Perrin, W. L. F. Armarego, and D. R. Perrin, Purification of Laboratory Chemicals, 2nd Edition, Pergamon Press, New York (1981).

    Google Scholar 

  110. T. E. Furtak and D. W. Lynch, J. Electroanal. Chem. 79, 1 (1977).

    CAS  Google Scholar 

  111. V. G. Bozhkov, G. A. Kataev, G. F. Kovtuneko, and K. V. Saldatenko, Elektrokhimiya 7, 549 (1971).

    CAS  Google Scholar 

  112. R. Greef, Instrumental Methods in Electrochemisty, Ellis Horwood Series in Physical Chemistry, Halsted, New York (1985).

    Google Scholar 

  113. M. C. H. McKubre and D. D. Macdonald, in: Comprehensive Treatise of Electrochemistry (R. E. White, J. O’M. Bockris, B. E. Conway, and E. Yeager, eds.), Vol. 8, Chapter 1, Plenum Press, New York (1984).

    Google Scholar 

  114. E. H. Fisher, Laser Focus, November (1977).

    Google Scholar 

  115. G. M. Hieftje and G. Horlick, Am. Lab., March, 76 (1981).

    Google Scholar 

  116. T. H. Ridgway and H. B. Mark, Jr., in: Comprehensive Treatise of Electochemistry (R. E. White, J. O’M. Bockris, B. E. Conway, and E. Yeager, eds.), Vol. 8, Chapter 2, Plenum Press, New York (1984).

    Google Scholar 

  117. G. T. Bennet and J. C. Thompson, J. Chem. Phys. 84, 1901 (1986).

    Google Scholar 

  118. Z. A. Rotenburg, V. I. Lakomov, and Yu. V. Pleskov, J. Electroanal. Chem. 27, 403 (1970).

    Google Scholar 

  119. V. V. Eletskii and Yu. V. Pleskov, Elektrokhimiya 10, 179 (1974).

    CAS  Google Scholar 

  120. S. Kh. Samvelyan, Z. A. Rotenberg, and V. G. Mairanovskii, Elektrokhimiya 19, 1319 (1983).

    CAS  Google Scholar 

  121. S. D. Babenko, V. A. Benderskii, A. G. Krivenko, and V. A. Kurmaz, J. Electroanal. Chem. 159, 163 (1983).

    CAS  Google Scholar 

  122. D. J. Schiffrin, Faraday Discuss Chem. Soc. 56, 75–95 (1973).

    CAS  Google Scholar 

  123. Z. A. Rotenberg and N. M. Rufman, J. Elektrokhimiya 19, 1349 (1983).

    CAS  Google Scholar 

  124. Z. A. Rotenberg and N. M. Rufman, J. Electroanal. Chem. 175, 153 (1984).

    CAS  Google Scholar 

  125. D. Bradley and J. Wilkinson, J. Chem. Soc. (A), 531 (1967).

    Google Scholar 

  126. A. Singh, H. D. Gesser, and A. R. Scott, Chem. Phys. Lett. 2, 271 (1968).

    CAS  Google Scholar 

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Severeyn, R.B., Gale, R.J. (1988). Photoemission Phenomena at Metallic and Semiconducting Electrodes. In: Gale, R.J. (eds) Spectroelectrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0985-7_3

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