Abstract
Sodium beta″ alumina is a non-stoichiometric sodium aluminate known for its rapid transport of Na+ ions. The Unique ability of B″ alumina to exhibit divalent and trivalent cation motion permits optically active ions to be introduced in the structure by low temperature ion exchange techniques. The synthesis, structure and optical properties of Nd3+ exchanged B″ alumina are reviewed in this paper. The material exhibits interesting optical properties, including laser action in small platelet crystals. The structure of the conduction plane, the presence of Na+ and its motion all appear to have a significant influence on optical properties
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References
G. C. Farrington and B. Dunn, “Divalent β′ aluminas: high conductivity solid electrolytes for divalent cations”, Solid State Ionics 7, 267 (1982).
G.C. Farrington, B. Dunn and J. O. Thomas, “ The lanthanide β′ aluminas,” Appl. Phys. A. 32, 159 (1983).
G. Rohrer, P. Sutter, S. Sattar and G. C. Farrington, Simulation and measurement of Na+ β′ alumina, submitted for publication.
D. L. Yang, unpublished results.
W. Carrillo-Cabrera, J. O. Thomas and G.C. Farrington, “The ionic distribution in trivalent Gd+ beta′ alumina,” Solid State Ionics 9/10, 245 (1983).
J. O. Thomas, M. Alden, G. J. Mclntyre and G. C. Farrington, “Shortrange ordering in Ba2+ β′ alumina at 295K,” Acta Cryst. B 40, 208 (1984).
P. Davies, A. Petford and M. O’Keefe, “Investigations of cation order in Nd, Gd and Eu β′ alumina using high resolution TEM”, Solid State Ionics, in press.
M. Jansen, S. J. Alfrey, O. M. Stafsudd, D. L. Yang, B. Dunn and G. C. Farrington, “Nd3+ beta′ alumina platelet laser”, Opt. Letts. 9 119 (1984).
A. J. Alfrey, O. M. Stafsudd, B. Dunn, D. L. Yang and L. Salmon, “Analysis of the absorption spectrum of Nd:Na β′ alumina,” submitted for publication.
A. J. Alfrey, O. M. Stafsudd, B. Dunn, D. L. Yang and L. Salmon, “Single pass gain in Nd:Na beta′ alumina,” submitted for publication.
K. G. Frase, J. O. Thomas and G. C. Farrington, “Temperature dependence of the Na+ distribution in beta′ alumina,” Solid State Ionics 9/10, 307 (1983).
J. J. Fontanella, M. C. Wintergill, D. L. Yang, B. Dunn and C. G. Andeen, “Electrical relaxation of neodymium-sodium beta ′ alumina,” Phys. Rev. in press.
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© 1987 Springer-Verlag Berlin Heidelberg
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Dunn, B., Thomas, J.O., Farrington, G.C. (1987). Beta″ Alumina: A Solid Electrolyte as a Solid-State Laser Host. In: Di Bartolo, B. (eds) Spectroscopy of Solid-State Laser-Type Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0899-7_15
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DOI: https://doi.org/10.1007/978-1-4613-0899-7_15
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-8235-8
Online ISBN: 978-1-4613-0899-7
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