Abstract
Schiff bases have been synthesized from heterocyclic amines and hydroxy aromatic aldehydes to undertake the hydrolysis in a wide range of pH values in various organized assemblies such as micelles, reversed micelles and microemulsions. The intermediacy of carbinolamine during Schiff base hydrolysis has been investigated by designing monolayer-forming Schiff bases and carrying out: surface studies. Hydrolysis studies in reversed micelles and microemulsions have also supported the formation of carbinolamine intermediate during hydrolysis.
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© 1989 Plenum Press, New York
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Behera, G.B., Mishra, B.K., Mishra, P., Senapati, S. (1989). Evidence for Carbinolamine Intermediate in Schiff Base Hydrolysis. In: Mittal, K.L. (eds) Surfactants in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0839-3_18
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DOI: https://doi.org/10.1007/978-1-4613-0839-3_18
Publisher Name: Springer, Boston, MA
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