Skip to main content

Evidence for Carbinolamine Intermediate in Schiff Base Hydrolysis

  • Chapter
Surfactants in Solution
  • 423 Accesses

Abstract

Schiff bases have been synthesized from heterocyclic amines and hydroxy aromatic aldehydes to undertake the hydrolysis in a wide range of pH values in various organized assemblies such as micelles, reversed micelles and microemulsions. The intermediacy of carbinolamine during Schiff base hydrolysis has been investigated by designing monolayer-forming Schiff bases and carrying out: surface studies. Hydrolysis studies in reversed micelles and microemulsions have also supported the formation of carbinolamine intermediate during hydrolysis.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. R.W. Layer, Chem. Rev. 63, 489 (1963).

    Article  CAS  Google Scholar 

  2. P.A.S. Smith, in “Open Chain Nitrogen Compounds”, Vol 1, p. 327, Benjamin, New York, (1965).

    Google Scholar 

  3. R.L. Reeves, in “The Chemistry of Carbonyl Groups”, S. Patai, Editor, Vol 1, p. 600, Interscience, New York, (1966).

    Google Scholar 

  4. S. Dayagi and Y. Dagani, in “The Chemistry of Carbon-Nitrogen Double- Bond”, S. Patai, Editor, p. 61, Interscience, New York, (1970).

    Google Scholar 

  5. B.L. Horecker, S. Pontremoli, C. Ricci and T. Cheng, Proc. Natl. Acad. Sci., U.S., 47, 1949 (1961).

    Google Scholar 

  6. E. Grazi, T. Cheng and B.L. Horecker, Biochem Biophys, Res Commun, 7, 250 (1962).

    CAS  Google Scholar 

  7. E. Grazi, P.T. Rowley, T. Cheng, 0. Tchola and B.L. Horecher, ibid, 9, 38 (1962).

    Google Scholar 

  8. J.C. Speck, Jr, P.T. Rowley and B.L. Horecker, J. Am. Chem. Soc, 85, 1012, 1963.

    Article  CAS  Google Scholar 

  9. G.A. Hamilton and F.H. Vfestheimer, ibid, 81, 6332 (1959).

    Google Scholar 

  10. I. Fridovich and F.H. westheimer, ibid, 84, 3208 (1962).

    Google Scholar 

  11. F.H. Westheimer, Proc. Chem. Soc., 253 (1963).

    Google Scholar 

  12. R.A. MDrton and G.A.J. Pitt, Progr. Chem. Org. Natl. Prod., 14, 244 (1957).

    Google Scholar 

  13. R. Hubbard, Proc. Natl. Phys. Lab. London Symp. No. 8, 151 (1958).

    Google Scholar 

  14. R.K. Chaturvedi and E.H. Cordes, J. Am. Chan. Soc., 89, 4631 (1967).

    Article  CAS  Google Scholar 

  15. H.C. Dunathan, Adv. Enzymol, 35, 79 (1971).

    CAS  Google Scholar 

  16. A.C. Dash and R.K. Nanda, J. Am, Chem. Soc., 91, 6944 (1969).

    Article  CAS  Google Scholar 

  17. A.C. Dash, B. Dash and S. Praharaj, J. Chen. Soc. Dalton, Trans. 2063 (1981).

    Google Scholar 

  18. J.J. Charette and E. de Hoffmann, J. Org. Chan., 44, 2256 (1979).

    Article  CAS  Google Scholar 

  19. J. Sunamoto, T. Hamada, T. Seto and S. Yamamoto, Bull. Chem. Soc. Jpn, 53, 583 (1980).

    Article  CAS  Google Scholar 

  20. M.K. Raval and U.C. Biswal, J. Theor. Biol, 115, 137 (1985).

    Article  CAS  Google Scholar 

  21. S. Senapati, B.K MLshra and G.B. Behera, Colloids Surfaces.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1989 Plenum Press, New York

About this chapter

Cite this chapter

Behera, G.B., Mishra, B.K., Mishra, P., Senapati, S. (1989). Evidence for Carbinolamine Intermediate in Schiff Base Hydrolysis. In: Mittal, K.L. (eds) Surfactants in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0839-3_18

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-0839-3_18

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8108-5

  • Online ISBN: 978-1-4613-0839-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics