Abstract
Matrix isolation is one of the principal tools in mechanistic studies of chemical reactions, especially of photochemical ones [1]. The two routine methods employed for reaching the situation of molecular trapping and isolation in solid environments are either cooling a mixture of organic solvents below its glass-forming temperature[1], or preparing a rigid polymeric plastic material from organic monomers [2].
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References
I.R. Dunkin, Chem. Soc. Rev., 1 (1974).
R. Reisfeld and C.K. Jørgensen, Structure Bonding, 49: 1 (1982).
D. Avnir, D. Levy and R. Reisfeld, J.Phys.Chem., 88: 5956 (1984).
D. Levy, R. Reisfeld and D. Avnir, Chem.Phys.Lett. 109: 593 (1984).
D. Avnir, V.R. Kaufman and R. Reisfeld, J.Non-Cryst.Solids, 74: 395 (1985).
D. Avnir, V.R. Kaufman and R. Reisfeld, J.Non-Cryst.Solids, 74: 395 (1985).
V.R. Kaufman and D. Avnir, this volume.
S.Sakka And K. Kamiya, J. Non-Cryst.Solids, 42: 403 (1980).
Vycor is an example of a phase-separated glass. See, D. Rojanski et al., this volume.
T. Tani, H. Namikawa, K. Arai and A. Makishima, J.Appl.Phys. in press;
T. Tani, A. Makishima, A. Itani and U.Itoh, presented in this Symposium.
M. Yamane, S. Aso, O. Okano and T. Sakaiano, J.Mat.Sci., 14: 607 (1979).
Photochemistry of Dyed and Pigmented Polymers“, N.S. Allen and J.F. McKellar, Eds., Appl. Sci. Publishers, London 1980.
D. Levy and D. Avnir, in preparation.
D. Levy, M.Sc. Thesis, The Hebrew University, 1984;
D. Avnir, R. Reisfeld and D. Levy, Israel Patent Application 69794, Sept. 23rd, 1983.
R.T. Parker, R.S. Freedlander and R.B. Deulap, Anal.Chim.Acta 119:189 (1980); 120: 1 (1980).
P. de Mayo, L.V. Natarajan and W.R. Ware, ACS Symp. Ser. 278: 1 (1985).
H. Dislich, J. Non-Cryst. Solids, 57:371 (1983);
C. J. Brinker and G.W. Scherer, Ibid., 70: 301 (1985).
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© 1988 Plenum Press, New York
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Levy, D., Avnir, D. (1988). Isolation and Trapping of Organic Photoactive Molecules in Silica Glass Matrices at Room Temperature. In: Scher, H. (eds) Unconventional Photoactive Solids. Institute for Amorphous Studies Series. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0727-3_20
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DOI: https://doi.org/10.1007/978-1-4613-0727-3_20
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