Abstract
Thermoplastic rubber is truly a useful and versatile class of polymer. It has the solubility and thermoplasticity of polystyrene, while at ambient temperatures it has the toughness and resilience of vulcanized natural rubber or polybutadiene. This characteristic results from its unique molecular structure. Visualize the simplest thermoplastic rubber molecule: a rubbery midblock with two plastic endblocks. This situation is pictured schematically in Fig. 1 where the diamonds represent monomer units in the plastic endblocks and the circles represent monomer units in the rubbery midblock. Such a molecule is called a block copolymer.
deceased
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Ceresa, R. J. (ed.), “Block and Graft Copolymerization,” Vol. 1, New York, John Wiley & Sons, 1973.
U.S. Patent 3,239,478 (1966).
Zelinski, R., and Childers, C. W., Rubber Chem. and Tech., 41, 161 (1968).
Marrs, O. L., and Edmonds, L. O., Adhesives Age, 15–20 (Dec. 1971).
Saunders, J. H., and Frisch, K. C., “Polyurethanes, Chemistry and Technology,” New York, Interscience Division of John Wiley & Sons, 1962.
Meier, D. J., J. Poly Sci., Part C, 26, 81–98 (1969).
Morton, M., et al., ibid, p. 99–115.
Beecher, J. F. et al., ibid, p. 117–134.
Bradford, E. B., and Vanzo, E., J. Poly Sci., Part A-1, 6, 1661–1670 (1968).
LeGrand, D. G., Polymer Letters, 8, 195–198 (1970).
Folkes, M. J., and Keller, A., Polymer, 12, 222–236 (1971).
Kaelble, D. H., Trans Soc. Rheology, 15, 235–258 (1971).
Inoue, T., et al., Macromolecules, 4, 500–507 (1971).
Lewis, P. R., and Price, C., Polymer, 13, 20–26 (1972).
Uchida, T., et al., J. Poly Sci., Part A-1, 10, 101–121 (1972).
Kampf, G., et al., J. Macromol Sci-Phys., B6, 167–190 (1972).
“Raw Materials for Hot Melts,” CA Report No. 55, Technical Assn. of the Pulp and Paper Industry, 1 Dunwoody Park, Atlanta, Ga. 30341.
Hildebrand, J. H., “The Solubility of Nonelectrolytes,”New York, Van Nostrand Reinhold, 129, 424–439 (1950).
Hansen, C. M., and Beerbower, A., in “Kirk-Othmer Encyclopedia of Chemical Technology,” Supplementary Vol., 2nd Ed., Interscience Division of John Wiley & Sons, 889–910, 1971 (includes tabulation).
Nelson, R. C., et al., J. Paint Technology, 42, 636–652 (1970).
Burrell, H., Paper 44, ACS Div. of Org. Coat, and Plast. Chem., Washington D.C., Preprints, 367–375, (Sept. 1971).
Gardon, J. L., “Encyclopedia of Polymer Science and Technology”, Vol. 3, New York, Interscience Division of John Wiley & Sons, 833–862, 1965 (includes tabulation).
“Shell Chart of Solvent Properties,” Bulletin IC:71–18R, Shell Chemical Company, Houston, Texas 77001.
“Solubility Parameters-Synthetic Resins, Related Materials, Solvents,” Hercules Inc., Wilmington, Del. 19899.
“Solubility Contours for Hydrocarbon Resins,” Pennsylvania Industrial Chemical Corp., 120 State St., Clairton, Pa. 15025.
Hagman, J. F., “Solvent Systems for Neoprene-Predicting Solvent Strength,” E. I. duPont deNemours and Co., Wilmington, Del.
Hoy, K. L., J. Paint Technology, 42, 76–118 (1970) (includes tabulation).
“Test Methods for Pressure Sensitive Tapes,” 6th Ed., Pressure Sensitive Tape Council, 1201 Waukegan Rd., Glenview, 111. 60025.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1990 Van Nostrand Reinhold, New York, NY
About this chapter
Cite this chapter
Harlan, J.T., Petershagen, L.A. (1990). Thermoplastic Rubber (A-B-A Block Copolymers) in Adhesives. In: Skeist, I. (eds) Handbook of Adhesives. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0671-9_13
Download citation
DOI: https://doi.org/10.1007/978-1-4613-0671-9_13
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-8019-4
Online ISBN: 978-1-4613-0671-9
eBook Packages: Springer Book Archive