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Metal Coordination Polymers: Eight-Coordinate Cerium(IV) and Zirconium(IV) Polymers with Varied Flexibility, Conjugation, and Stability Through Ligand Variation

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Metal-Containing Polymeric Materials

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Abstract

Tractable (soluble) linear transition metal coordination polymers in which the metal ions are a necessary part of the backbone (and without which the polymer will stay intact) have proven difficult to synthesize.1-6 Bis(tetradentate) Schiff-base ligands coupled with zirconium(IV) ions large enough for eight- coordination can be used to overcome this insolubility,7-8 and recently an analogous soluble cerium(IV) Schiff-base polymer has been prepared.9 Although a number of reports had appeared regarding polymeric systems in which lanthanide metal ions are attached to a branch of a polymer chain10-14 or solid state species that either remain insoluble in all solvents or fall apart into small molecules when dissolved,15-17 soluble linear polymers with lanthanide ions in their backbone had been lacking prior to our study of catena-poly [cerium(IV)-µ-N,N′,N″,N‴-tetrasalicylidene(3,3′-diaminobenzidinato)-O,-N,N′,O′:O″,N″,N‴ ,O‴], [Ce(tsdb)]n.9

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Authors and Affiliations

  1. Departments of Chemistry, University of Massachusetts, Amherst, 01003, MA, USA

    Ronald D. Archer, Huiyong Chen & Jon A. Cronin

  2. Departments of Chemistry, Smith College, Northampton, 01060, MA, USA

    Sharon M. Palmer

Authors
  1. Ronald D. Archer
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  2. Huiyong Chen
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  3. Jon A. Cronin
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  4. Sharon M. Palmer
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Editor information

Editors and Affiliations

  1. Mississippi State University, Mississippi State, Mississippi, USA

    Charles U. Pittman Jr.

  2. Florida Atlantic University, Boca Raton, Florida, USA

    Charles E. Carraher Jr.

  3. City University of New York, New York, New York, USA

    Martel Zeldin

  4. Rider College, Lawrenceville, New Jersey, USA

    John E. Sheats

  5. Ohio State University, Columbus, Ohio, USA

    Bill M. Culbertson

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© 1990 Plenum Press, New York

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Archer, R.D., Chen, H., Cronin, J.A., Palmer, S.M. (1990). Metal Coordination Polymers: Eight-Coordinate Cerium(IV) and Zirconium(IV) Polymers with Varied Flexibility, Conjugation, and Stability Through Ligand Variation. In: Pittman, C.U., Carraher, C.E., Zeldin, M., Sheats, J.E., Culbertson, B.M. (eds) Metal-Containing Polymeric Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0669-6_5

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  • DOI: https://doi.org/10.1007/978-1-4613-0669-6_5

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-7919-8

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