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Investigation of the Ion-Binding Properties of Tactic Poly(Methacrylic Acids) Using Terbium (III) Ion as a Fluorescent Probe

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Metal-Containing Polymeric Materials

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Abstract

The lanthanides have fourteen 4ƒ electrons successively added to the lanthanum, La, configuration. These elements are highly electropositive and form a very stable tripositive cation, Ln3+, as their primary oxidation state. The radius of these ions decrease with increasing atomic number in a trend known as the lanthanide contraction. The elements are highly electropositive because the sum of the first three ionization enthalpies is relatively low. They easily form +3 ions in solids, such as oxides, and in complexes while existing as [Ln(H2O)n]3+ in aqueous solution. Other oxidation states are also possible, for example, Ce4+, Sm2+, Eu 2+, and Yb2+ are all stable in aqueous solutions and in solids.

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References

  1. C. K. Jørgensen, Orbitals in Atoms and Molecules, Academic, New York (1962), Chap. 11.

    Google Scholar 

  2. T. Moeller, The Chemistry of the Lanthanides, Reinhold, New York (1963), Chap. 3 & 4.

    Google Scholar 

  3. G. Schwarzenbach, Advances in Inorganic Chemistry and Radiochemistry, Vol. 3, H. J. Emeleus and A. G. Sharpe, eds., Academic, New York (1961), p. 265.

    Google Scholar 

  4. E. Nieboer and W. A. E. McBryde, Can. J. Chem., 51, 2511 (1973).

    Article  Google Scholar 

  5. R. J. P. Williams and J. D. Hale, Struct. Bonding, 1, 249 (1966).

    Article  CAS  Google Scholar 

  6. R. G. Pearson, J. Chem. Educ., 56, 581 (1968).

    Article  Google Scholar 

  7. G. Klopman, J. Am. Chem. Soc., 90, 223 (1968).

    Article  Google Scholar 

  8. T. Moeller, Inorganic Chemistry Series One, K. W. Bagnall, ed., University Park Press, Baltimore (1972), Vol. 7, p. 275.

    Google Scholar 

  9. G. Blasse and A. Bril, Phillips Technical Review, 31, (10), 314 (1970).

    CAS  Google Scholar 

  10. R. D. Peacock, Struct. Bond., 22, 84, (1975).

    Google Scholar 

  11. F.S. Richardson, Chem. Rev, 82, 541 (1982).

    Article  CAS  Google Scholar 

  12. F. S. Richardson, J. D. Saxe, S. A. Davis, and T. R. Faulkner, Mol. Phys., 42, 401 (1981).

    Article  Google Scholar 

  13. J. P. Morley, J. D. Saxe, and F. S. Richardson, Mol. Phys., 47, 379, (1982).

    Article  CAS  Google Scholar 

  14. J. D. Saxe, J. P. Morley, and F. S. Richardson, Mol. Phys., 47, 407, (1982).

    Article  CAS  Google Scholar 

  15. F.S.Richardson, Inorg. Chem., 19, 2806, (1980).

    Article  CAS  Google Scholar 

  16. F. S. Richardson, Chem. Rev., 79, 17, (1979).

    Article  CAS  Google Scholar 

  17. F. S. Richardson, and T. R. Faulkner, J. Chem. Phys., 76, 1595, (1982).

    Article  CAS  Google Scholar 

  18. J. D. Saxe, T. R. Faulkner, and F. S. Richardson, J. Chem. Phys., 76, 1607, (1982).

    Article  CAS  Google Scholar 

  19. W. D. Horrock’s, Jr., and D. R. Sudnick, Acc. Chem. Res., 14, 384, (1981).

    Article  Google Scholar 

  20. W. D. Horrock’s, Jr., reference 19

    Google Scholar 

  21. H. G. Brittain, S. P. Kelty, J. A. Peters, J. Coord. Chem., 23, 21, (1991).

    Article  CAS  Google Scholar 

  22. J. Kido, Y. Okamoto, Makromol. Chem., Macromol. Symp., 59, 83 (1992).

    Article  Google Scholar 

  23. J. Kido, H. G. Brittain, and Y. Okamoto, Macromolecules, 21, 1872, (1988).

    Article  CAS  Google Scholar 

  24. V. Crescenzi, H. G. Brittain, N. Yoshino, and Y. Okamoto, J. Polym. Sci.: Polym. Phys. Ed., 23,437, (1985).

    CAS  Google Scholar 

  25. I. Nagata, Y. Okamoto, Macromolecules, 77, 773, (1977).

    Google Scholar 

  26. W. T. Carnall, P. R. Fields, K. Rajnak, J. Chem. Phys., 49, 4447, (1968).

    Article  CAS  Google Scholar 

  27. W. T. Carnall, P. R. Fields, K. Rajnak, J. Chem. Phys., 49, 4412, (1968).

    Article  CAS  Google Scholar 

  28. A. Rudman, S. Paoletti, and H. G. Brittain, Inorg. Chem., 24, 1283,(1985).

    Article  CAS  Google Scholar 

  29. O.L. Malta, Molecular Physics, 42, (1), 65, (1981).

    Article  Google Scholar 

  30. R. D. Peacock, Struct. Bond., 22, 84, (1975).

    Google Scholar 

  31. G. Odian, Principles of Polymerization, 2nd Edition, John Wiley & Sons, New York, p568, (1970).

    Google Scholar 

  32. E. M. Loebl and J. J. O’Neill, J. Polym. Sci., 45, 538, (1960).

    Article  CAS  Google Scholar 

  33. E. M. Loebl and J. J. O’Neill, Polym. Prepr. Am. Chem. Soc. Div. Polym. Chem., 3, 466, (1962).

    CAS  Google Scholar 

  34. Loebl, reference 31

    Google Scholar 

  35. J. J. O’Neill, E. M. Loebl, A. Y. Kandanian, and H. Morawetz, J. Polym. Sci., A-1,3, 4201 (1965).

    Google Scholar 

  36. L. Costantino, V. Crescenzi, F. Quadrifoglio, and V. Vitagliano, J. Polym. Sci., A-1,2, 5771, (1967).

    Google Scholar 

  37. M. Menger, P. A. Chicklo, and M. J. Sherrod, Tetrahedron Letters, 30, 6943, (1989).

    Article  CAS  Google Scholar 

  38. J. B Lando and J. Semen, J. Macromol. Sci.,-Phys., B7(2), 297–317 (1973).

    Article  CAS  Google Scholar 

  39. Y. Muroga, I., Noda, and M. Nagasawa, Macromolecules, 18, 1580, (1985).

    Article  CAS  Google Scholar 

  40. H. Luján-Upton, Part I: Investigation on the Ion-Binding Properties of Carboxy - Containing Compounds using Terbium (III) Ion as a Fluorescent Probe, Ph.D. Thesis, Polytechnic University, Appendix, p72, January 1995.

    Google Scholar 

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Author information

Authors and Affiliations

  1. Department of Chemistry and the Polymer Research Institute, Polytechnic University, 6 Metrotech Center, Brooklyn, NY, 11201, USA

    Hannia Luján-Upton & Yoshiyuki Okamoto

Authors
  1. Hannia Luján-Upton
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  2. Yoshiyuki Okamoto
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Editor information

Editors and Affiliations

  1. Mississippi State University, Mississippi State, Mississippi, USA

    Charles U. Pittman Jr.

  2. Florida Atlantic University, Boca Raton, Florida, USA

    Charles E. Carraher Jr.

  3. City University of New York, New York, New York, USA

    Martel Zeldin

  4. Rider College, Lawrenceville, New Jersey, USA

    John E. Sheats

  5. Ohio State University, Columbus, Ohio, USA

    Bill M. Culbertson

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© 1990 Plenum Press, New York

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Luján-Upton, H., Okamoto, Y. (1990). Investigation of the Ion-Binding Properties of Tactic Poly(Methacrylic Acids) Using Terbium (III) Ion as a Fluorescent Probe. In: Pittman, C.U., Carraher, C.E., Zeldin, M., Sheats, J.E., Culbertson, B.M. (eds) Metal-Containing Polymeric Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0669-6_30

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  • DOI: https://doi.org/10.1007/978-1-4613-0669-6_30

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-7919-8

  • Online ISBN: 978-1-4613-0669-6

  • eBook Packages: Springer Book Archive

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