Biomimetic Reactions Using Organized Polymeric Supports

  • G. Wulff

Abstract

For the preparation of polymeric supports possessing organized structures, an imprinting procedure on the basis of template approach was used in crosslinked polymers as well as in silicas. In this manner, chiral cavities possessing definite shapes and specific arrangements of the functional groups (corresponding to the templates) were obtained within the polymer. These polymers could be used for separation of racemates. Using an analogous procedure, functional groups with defined cooperativity could be obtained on the surfaces of silica. Highly reactive 1.3.2-dioxaborole moieties were attached to polymers and were used as reagents for an aldol type reaction with aldehydes. In this manner, α,β-dihydroxy aldehydes, particularly carbohydrates are thus obtained.

Keywords

High Performance Liquid Chromatography Boron Aldehyde MeOH Diol 

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Copyright information

© Plenum Press, New York 1990

Authors and Affiliations

  • G. Wulff
    • 1
  1. 1.Institute of Organic Chemistry & Macromolecular ChemistryUniversity of DüsseldorfDüsseldorfGermany

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