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Biomimetic Reactions Using Organized Polymeric Supports

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Biomimetic Polymers

Abstract

For the preparation of polymeric supports possessing organized structures, an imprinting procedure on the basis of template approach was used in crosslinked polymers as well as in silicas. In this manner, chiral cavities possessing definite shapes and specific arrangements of the functional groups (corresponding to the templates) were obtained within the polymer. These polymers could be used for separation of racemates. Using an analogous procedure, functional groups with defined cooperativity could be obtained on the surfaces of silica. Highly reactive 1.3.2-dioxaborole moieties were attached to polymers and were used as reagents for an aldol type reaction with aldehydes. In this manner, α,β-dihydroxy aldehydes, particularly carbohydrates are thus obtained.

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Author information

Authors and Affiliations

  1. Institute of Organic Chemistry & Macromolecular Chemistry, University of Düsseldorf, Universitätsstr. 1, D-400, Düsseldorf, Germany

    G. Wulff

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  1. G. Wulff
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Editor information

Editors and Affiliations

  1. Dept. of Chemistry, Youngstown State University, Youngstown, Ohio, 44555, USA

    Charles G. Gebelein

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© 1990 Plenum Press, New York

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Wulff, G. (1990). Biomimetic Reactions Using Organized Polymeric Supports. In: Gebelein, C.G. (eds) Biomimetic Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0657-3_1

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  • DOI: https://doi.org/10.1007/978-1-4613-0657-3_1

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-7913-6

  • Online ISBN: 978-1-4613-0657-3

  • eBook Packages: Springer Book Archive

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