Summary
Containment of organic species within microporous materials such as zeolites influences their modes of molecular motion. This manifests itself in a range of ways, including a reduction in the volume that is readily accessible to the molecules by translation, constraints upon the molecular conformational space, restricted modes of molecular reorientation, or altered vibrational frequencies. The perspectives on certain of the motional properties of sorbates and of tetramethylammonium cations within zeolites provided by simple molecular modelling, neutron powder diffraction, 13C and 2H(D) NMR, and inelastic and quasielastic neutron scattering are outlined and illustrated by selected recent results.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Work supported in part by the U. S. Department of Energy, BES-Materials Sciences, under contract W-31–109-ENG-38.
Breek, D. W. Zeolite Molecular Sieves: Structure, Chemistry and Use; Wiley and Sons: London, 1973. Reprinted, R. E. Krieger: Malabar Fl, 1984.
Barrer, R. M. Zeolites and Clay Minerals as Sorbents and Molecular Sieves; Academic Press: London, 1978.
Barrer, R. M. Hydrothermal Chemistry of Zeolites; Academic Press: London, 1982.
Olson, D.; Bisio, A. Eds. Proc. Sixth Int. Zeolite Conf.; Butterworths: Surrey, UK, 1984.
Murakami, Y.; Iijima, A.; Ward, J. W. Eds. New Developments in Zeolite Science and Technology; Kodansha: Tokyo - Elsevier: Amsterdam, 1986.
Newsam, J. M. Science 1986,231, 1093–1099.
Vaughan, D. E. W.In Properties and Applications of Zeolites; Chem. Soc: London, 1980; Special Pub. No. 33, pp. 294-328.
Ruthven, D. M. Principles of Adsorption and Adsorption Processes; Wiley-Inter-science: New York, 1984.
Suffritti, G.; Gamba, A. Int. Rev. Phys. Chem. 1987, 6, 299–314.
Newsam, J. M. Aspects of Zeolite Structure Modeling and Graphics, in preparation
Jackson, R. A.; Catlow, C. R. A. Molec. Simulation, in press.
Ooms, G.; van Santen, R. A.; den Ouden, C J. J.; Jackson, R. A.; Catlow, C. R. A.J. Phys. Chem. 1988, 92, 4462–4465
Meier, W. M.; Villiger, H. Z. Kristallogr. 1969, 729, 411–423.
Baerlocher, Ch.; Hepp, A.; Meier, W. M. DLS-76 - A Program for Simulation of Crystal Structures by Geometric Refinement (ETH, Zurich Report, 1977)
Ramdas, S.; Thomas, J. M.; Betteridge, P. W.; Cheetham, A. K.; Davies, E. K. Angew. Chem., Int. Ed. Engl. 1984,25, 671–679.
Fyfe, C. A.;Kennedy, G. J.; De Schutter, C. T.; Kokotailo, G. T. J. Chem. Soc, Chem. Commun. 1984, 541–542.
Kiselev, A. V. J. Chem. Tech. Biotechnol. 1979, 29, 673–685.
Kiselev. A. V.; Du, P. Q. J. Chem. Soc, Faraday Trans. II1981, 77, 17–32.
Wright, P. A.; Thomas, J. M.; Cheetham, A. K.;Nowak, A. K. Nature (London) 1985,318, 611–614
Fitch, A. N.; Jobic, H.; Renouprez, A. J. Phys. Chem. 1986, 90, 1311–1318.
Bezus, A. G.; Kocirik, M.; Kiselev, A. V.; Lopatkin, A. A.; Vasilyeva, E. A. Zeolites 1986,6, 101–106.
Nowak, A. K.; Cheetham, A. K. In New Developments in Zeolite Science Technology; Murakami, Y.; Iijima, A.; Ward, J. W. Eds. Kodansha: Tokyo - Elsevier: Amsterdam, 1986; pp. a475–579.
Newsam, J. M.; Silbernagel, B. G.; Garcia, A. R.; Hulme, R. J. Chem. Soc, Chem. Commun. 1987, 664–666.
Nowak, A. K.; Cheetham, A. K.; Pickett, S. D.; Ramdas, S. Molec. Simulation, in press.
Silbernagel, B. G.; Garcia, A. R.; Newsam, J. M.; Hulme, R., in preparation.
Binder, K. Ed. Monte Carlo Methods in Statistical Physics, Second Edition; Springer-Verlag: New York, 1987.
Fieldler, K.; Grauert, B. Adsorption Sei. Technol. 1986, 3, 181–187.
Kono, H.; Takasaka, A. J. Phys. Chem. 1987, 97, 4044–4055.
Heerman, D. Computer Simulation Methods in Theoretical Physics; Springer-Verlag: New York, 1986.
Demontis, P.; Suffritti, G. B.; Alberti, A.; Quartieri, S.; Fois, E. S.; Gamba, A. Gazz. Chim. Ital. 1986, 116, 459–466.
Yashonath, S.;Thomas, J. M.; Nowak, A.; Cheetham, A. K. Nature (London) 1988, 331, 601–604.
Newsam, J. M. Physica 1986,136B, 213–217.
Newsam, J. M Materials Science Forum 1987,27/28, 385–396
Taylor, J. C. Zeolites, 1987, 7, 311–318.
Richardson, J. W.; Pluth, J. J.; Smith, J. V. J. Phys. Chem. 1988, 92, 243–247.
van Koningsveld, H.; van Bekkum, H.; Jansen, J. C. Acta Cryst. 1987, B43, 127–132.
Baerlocher, Ch.; Meier, W. M. Helv. Chim. Acta 1969,52, 1853–1860.
Jarman, R. H.; Melchior, M. T. J. Chem. Soc, Chem. Commun. 1984, 414–415.
Melchior, M. T.; Vaughan, D. E. W.; Jarman, R. H.; Jacobson, A. J. presented at Rocky Mtn. Conf. Applied Spectroscopy, Denver CO, Aug. 8, 1984.
Hayashi, S.; Suzuki, K.; Shin, S.; Hayamizu, K.; Yamamoto, O. Chem. Phys. Lett. 1985, 113, 368–371.
Derouane, E. G.; Nagy, J. B. Chem. Phys. Lett. 1987,137, 341–344.
Meier, W. M.; Olson, D. H. Atlas of Zeolite Structure Types; Butterworths: London, 1987.
Fraissard,J.;Ito, T.; Springuel-Huet, M.; Demarquay, J. In New Developments in Zeolite Science Technology, Murakami, Y.; Iijima, A.; Ward, J. W. Eds.; Kodansha: Tokyo - Elsevier: Amsterdam, 1986; p. 393.
Ripmeester, J. A.; Ratcliffe, C. I., in preparation
Eckman, R. R.; Vega, A. J. J. Am. Chem. Soc. 1983, 105, 4841–4842.
Eckman, R. R.; Vega, A. J. J. Phys. Chem. 1986, 90, 4679–4683.
Hasha, D. L.; Miner, V. W.; Garces, J. M.; Rocke, S. C. ACS Symp. Ser. 1985, 288, 485–497.
Zibrowius, B.; Caro, J.; Pfeifer, H. J. Chem. Soc, Faraday Trans. II1988, 84, 2347–2356
Egelstaff, P. A.; Stretton Downes, J.; White, J. W. In Molecular Sieves; Barrer, R. M. Ed.; Soc. Chem. Ind.: London, 1968; pp. 306–318.
Howard, J.; Waddington, T. C.; Wright, C. J. J. Chem. Soc. Faraday Trans. II 1977, 73, 1768–1787.
Dutta, P. K.; Del Barco, B.; Shieh, D. C. Chem. Phys. Lett. 1986, 727, 200–204.
Ratcliffe, C. I.;Waddington, T. C. J. Chem. Soc., Faraday Trans. II 1976, 72, 1935–1956
Brun, T. O.; Iton, L. E.; Kleb, R.; Newsam, J. M.; Beyerlein R. A.; Vaughan, D. E. W. J. Am. Chem. Soc. 1987, 109, 4118–4119.
Brun, T. O.; Trouw, F.; Curtiss, L. A.; Iton, L. E.; Newsam, J. M.,in preparation
Cohen de Lara, E.;Kahn, R.;Mezei, F. J. Chem. Soc, Faraday Trans. II1983, 79, 1911–1920.
Jobic, H.; Bee, M.; Renouprez, A. Surf. Sei. 1984,140, 307–320.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1990 Plenum Press, New York
About this chapter
Cite this chapter
Newsam, J.M., Silbernagel, B.G., Melchior, M.T., Brun, T.O., Trouw, F. (1990). Motion of Organic Species Occluded or Sorbed Within Zeolites [1]. In: Atwood, J.L. (eds) Inclusion Phenomena and Molecular Recognition. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0603-0_32
Download citation
DOI: https://doi.org/10.1007/978-1-4613-0603-0_32
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-7887-0
Online ISBN: 978-1-4613-0603-0
eBook Packages: Springer Book Archive