Abstract
Rare earth (R) iron garnets (R3Fe5O12) have excellent properties for magnetic, magneto-optic and microwave applications. For magnetic bubble memory devices requiring single crystal films of several micrometer thickness an epitaxial technique had to be developed. The know-how concerning congruently melting non-magnetic garnet crystal growth from the melt for laser applications was used to grow gallium gadolinium garnet as suitable substrate crystals. On wafers of these crystals single crystal layers can be grown by liquid phase epitaxy (LPE) from very diluted high temperature solutions known from the flux growth of yttrium iron garnet (YIG) for microwave applications. Substrate crystals with garnet structure having a lattice constant in the range from 1.22 nm to 1.26 nm are now available [1]. This allows the growth of magnetic garnet layers with a wide variety of compositions to tailor the properties for various applications. LPE is a well suited process to study crystal growth phenomena, too. Some advantageous features of garnet LPE with respect to crystal growth will be discussed. Occasionally comparison to LPE of semiconductors is made.
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References
D. Mateika, Substrates for epitaxial garnet layers, in: “Current Topics in Materials Science”, E. Kaldis, ed., Vol. 11, North Holland, Amsterdam (1984).
S. Geller, Crystal chemistry of garnets, Z. Krist., 125:1 (1967).
W. Tolksdorf and W. Wolfmeier, in: Landolt-Börnstein, New Series Group III, Vol. 12, Part a, Springer Berlin (1978).
G. Winkler, “Magnetic Garnets”, Vieweg, Wiesbaden (1981).
B. Strocka, P. Hoist and W. Tolksdorf, An empirical formula for the calculation of lattice constants of oxide garnets based on substituted yttrium and gadolinium iron garnets, Philips J. Res., 33:186 (1978).
P. J. Besser, J. E. Mee, P. E. Elkins and D. M. Heinz, A stress model for heteroepitaxial magnetic oxide films grown by chemical vapor deposition, Mat. Res. Bull., 6:1111 (1971).
W. Tolksdorf, Preparation and imperfections of magnetic materials with garnet structure. Physics of Magnetic Garnets, LXX Corso Soc., Italiana di Fisica, Bologna, Italy (1978).
B. Knörr and W. Tolksdorf, Lattice parameter and misfits of gallium garnets and iron garnet epitaxial layers at temperatures between 294 and 1300 K, Mat. Res. Bull., 19:1507 (1984).
E. A. Giess, M. M. Faktor, R. Ghez and C. F. Guerci, Gadolinium gallium garnet liquid phase epitaxy and the physical chemistry of garnet molten solutions, J. Crystal Growth, 56:576 (1982).
S. L. Blank and J. W. Nielsen, The growth of magnetic garnets by liquid phase epitaxy, J. Crystal Growth, 17:302 (1972).
H. D. Jonker, Investigation of the phase diagram of the system PbO-B2O3-Fe203-Y203 for the growth of single crystals of Y3Fe5012, J. Crystal Growth, 28:231 (1975).
S. Knight, B. S. Hewitt, D. L. Rode and S. L. Blank, Measurement of the diffusion coefficient of rare earth species in PbO-B2O3 flux used for liquid phase epitaxial growth of magnetic garnet films, Mat. Res. Bull., 9:895 (1974).
J. E. Davies and E. A. Giess, The stability of the supersaturated state in isothermal fluxed melts used for magnetic garnet LPE, J. Crystal Growth, 30:295 (1975).
K. Fischer, D. Linzen, E. Sinn and S. Bornmann, Equilibrium reactions in oxidic high temperature solutions used for liquid phase epitaxy of garnets, J. Crystal Growth, 52:729 (1981).
K. Fischer and P. Görnert, On the solubility of garnets in Pb0/B2O3 high temperature solvents, Crystal Res. & Technol., 17:775 (1982).
P. Görnert and F. Voigt, High temperature solution growth of garnets: theoretical models and experimental results, jLn: “Current Topics in Materials Science”, E. Kaldis, ed., Vol. 11, North Holland, Amsterdam (1984).
E. Sinn, D. Linzen and K. Fischer, The importance of the oxygen ion concentration for oxidic high temperature solution, Cryst. Res. Technol., 20:965 (1985).
V. van Erk, A solubility model for rare earth iron garnets in a PbO/B2O3 solution, J. Crystal Growth, 46:539 (1979).
C.-P. Klages, W. Tolksdorf and G. Kumpat, The influence of excess iron oxide on the solubility of yttrium iron garnet and its growth kinetics on (111) substrates, J. Crystal Growth, 65:556 (1983).
C.-P. Klages and W. Tolksdorf, LPE growth of bismuth substituted gadolinium iron garnet layers: systematization of experimental results, J. Crystal Growth, 64:275 (1983).
C.-P. Klages and W. Tolksdorf, Segregation in garnet LPE, J. Crystal Growth, 79:110 (1986).
E. A. Giess, M. M. Faktor and F. C. Frank, The liquidus temperature and growth-dissolution kinetics of garnet liquid phase epitaxy, J. Crystal Growth, 46:620 (1979).
R. Ghez and E. A. Giess, Liquid phase epitaxial growth kinetics of magnetic garnet films grown by isothermal dipping with axial rotation, Mat. Res. Bull., 8:31 (1973).
J. M. Robertson, M. W. van Toll, J. P. H. Heynen, W. H. Smits and T. de Boer, Thin single crystalline phosphor layers grown by liquid phase epitaxy, Philips J. Res., 35:354 (1980).
P. Hansen, B. Hill and W. Tolksdorf, Optical switching with bismuthsubstituted iron garnets, Phiips Techn. Rev., 41:34 (1983/84).
P. Hansen, K. Witter and W. Tolksdorf, Magnetic and magneto-optic properties of lead and bismuth substituted iron garnet films, Phys. Rev., B27:6608 (1983).
P. Hansen, K. Vetter and W. Tolksdorf, Magnetic and magneto-optic properties of bismuth-and aluminium-substituted garnet films, J. Appl. Phys., 55:1052 (1984).
P. Röschmann and W. Tolksdorf, Epitaxial growth and annealing control of FMR properties of thick homogeneous Ga substituted yttrium iron garnet films, Mat. Res. Bull., 18:449 (1983).
C.-P. Klages, Site selectivity in praseodymium-and bismuthsubstituted gadolinium gallium garnet epilayers, Mat. Res. Bull., 19:633 (1984).
T. Hibiya, Y. Morishige and J. Nakashima, Growth and characterization of liquid-phase epitaxial Bi-substituted iron garnet films for magneto-optic application, Jap. J. Appl. Phys., 24:1316 (1985).
H. J. Levinstein, S. Licht, R. W. Landorf and S. L. Blank, Growth of high-quality garnet thin films from supercooled melts, Appl. Phys. Letters, 19:486 (1971).
W. Tolksdorf, H. Dammann, E. Pross, B. Strocka, H. J. Tolle and P. Willich, Growth of yttrium iron garnet multi-layers by liquid phase epitaxy for single mode magneto-optic waveguides, J. Crystal Growth, 83:15 (1987).
V. G. Levich, “Physicochemical Hydrodynamics”, Prentice Hall (1962).
H. Schlichting, “Boundary-Layer Theory”, McGraw-Hill, New York (1979).
F. Rosenberger, “Fundamentals in Crystal Growth I”, Springer, Heidelberg (1979).
J. A. Burton, R. C. Prim and W. P. Slichter, The distribution of solute in crystals grown from the melt: Part I, Theoretical, J. Chem. Phys., 21:1987 (1953).
S. Bruckenstein, M. I. Bellavance and B. Miller, The electrochemical response of a disk electrode to angular velocity steps, J. Electrochem. Soc., 120:1351 (1973).
J. C. Brice, Trends in liquid phase epitaxy, in: “1976 Crystal Growth and Materials”, E. Kaldis and H. J. Scheel, eds., 571, North-Holland, Amsterdam (1977).
P. Willich, W. Tolksdorf and D. Obertop, Electronprobe microanalysis of epitaxial garnet films, J. Crystal Growth, 53:483 (1981).
R. Ghez and E. A. Giess, The temperature dependence of garnet liquid phase epitaxial growth kinetics, J. Crystal Growth, 27:221 (1974).
E. A. Giess and R. Ghez, Liquid phase epitaxy, _iii: “Epitaxial Growth, Part A”, 183, Academic Press, New York (1975).
B. van der Hoek and W. van Erk, The interfacial and volume transport processes during LPE growth of garnets, J. Crystal Growth, 58:537 (1982).
W. Tolksdorf and I. Bartels, Facet formation of yttrium iron garnet layers grown epitaxially on spheres, J. Crystal Growth, 54:417 (1981).
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© 1989 Plenum Press, New York
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Tolksdorf, W. (1989). Liquid Phase Epitaxy of Garnets. In: Arend, H., Hulliger, J. (eds) Crystal Growth in Science and Technology. NATO ASI Series, vol 210. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0549-1_25
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DOI: https://doi.org/10.1007/978-1-4613-0549-1_25
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