Abstract
Detailed experimental studies of the electronic structure of the valence and conduction bands of the mixed conductor β-LiAl indicate that a quasi-gap opens at the Fermi level, and the conduction states are highly localized, as opposed to the theoretical band structure calculations that predict predominant metallic behavior. Evidence for complex lithium migration effects involving the surface of LiAl, induced by particle (electron or ion) bombardment, and mechanical treatment, has been obtained as a by-product of these experiments.
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References
D. L. Barney: US DOE Report ANL-80–128, Argonne National Laboratory, February 1981.
W. Fischer: Solid State Ionics 3/4, 413 (1981).
B. N. McNicol and D. A. J. Rand (eds.): Power Sources for Electric Vehicles, Elsevier, Amsterdam-New York, 1984.
R. Thümmel and W. Klemm: Z. Anorg. Allg. Chem. 376, 44 (1970).
E. Zintl and G. Brauer: Z. Phys. Chem. B20, 245 ( 1933
C. J. Wen, B. A. Boucamp, R. A. Huggins and W. Weppner: J. Electrochem. Soc. 126, 2258 (1979).
K. Kishio and J. O. Brittain: J. Phys. Chem. Solids 40, 933 (1979).
L. N. Hall, T. O. Brun, G. W. Crabtree, J. E. Robinson, S. Susman and T. Tokuhiro: Solid State Commun. 48, 547 (1983).
M. Yahagi: Phys. Rev. B24, 7401 (1981).
K. Kuriyama, T. Nozaki and T. Kamijoh: Phys. Rev. B26, 2235 (1982).
J. Hafner and W. Weber: Phys. Rev. B33, 747 (1985) and the references therein.
W. Hückel: Structural Chemistry of Inorganic Compounds, Elsevier, Amsterdam, 1951.
K.-S. Din, R. Chin and I. M. Curelaru: MSE-UofU Report, 1985.
I. M. Curelaru, K.-S. Din, S. Susman, T. O. Brun and K. J. Volin: submitted for publication.
I. M. Curelaru, G.-E. Jang, E. E. Koch, K. Horn, J. Ghijsen, R. L. Johnson, S. Susman, T. O. Brun and K. J. Volin: to be published.
I. M Curelaru, G.-E. Jang, T. A. Callcott, K. L. Tsang, C. H. Zhang, S. Susman, T. O. Brun and K.J. Volin: to be published.
I. M. Curelaru, K.-S. Din and G.-E. Jang: unpublished.
Handbook of Auger Electron Spectroscopy, JEOL, Tokyo, 1981.
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© 1989 Plenum Press, New York
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Curelaru, I.M. et al. (1989). Electronic Structure, Bonding, and Lithium Migration Effects Involving the Surface of the Mixed Conductor β-LiAi. In: Tuller, H.L., Balkanski, M. (eds) Science and Technology of Fast Ion Conductors. NATO ASI Series, vol 199. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0509-5_21
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DOI: https://doi.org/10.1007/978-1-4613-0509-5_21
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