Abstract
Epoxidation of olefins is an important way to functionalize hydrocarbons for intermediates in fine chemicals industry [1]. Organic peracids are still used as stoichiometric reagents, but, the use of hydrogen peroxide or organic hydroperoxides appears more convenient and cost effective. These reagents require a transition metal complexes as catalysts; most of them are titanium, vanadium, molybdenum or tungsten based [2].
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Gelbard, G., Sherrington, D.C., Breton, F., Benelmoudeni, M., Charreyre, MT., Dong, D. (1996). Polymers with Ligated Peroxotungstic Units: Organophosphoryl Macroligands for the Catalytic Epoxidation of Alkenes. In: Pittman, C.U., Carraher, C.E., Zeldin, M., Sheats, J.E., Culbertson, B.M. (eds) Metal-Containing Polymeric Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0365-7_21
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DOI: https://doi.org/10.1007/978-1-4613-0365-7_21
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