Abstract
The synthesis and the study of metallosiloxane polymers is of a considerable interest due to their unique properties, which include high thermal stability and electrical conductivity. The chemistry of metallosiloxane polymers has already been studied for 25–30 years. The question about their structure was open until the beginning of 1990 when we have first obtained and structurally characterized poly (phenylmetallosiloxane)s (PPMS), containing bivalent transition metal atoms: nickel, manganese, copper and cobalt1-4, which were named the cage-like poly (phenylmetallosiloxane)s8.
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References
O.I.Shchegolikhina, A.A.Zhdanov, V.A.Igonin, Yu.E.Ovchinnikov, V.E.Shklover, Yu.T.Struchkov, Synthesis and structure of unusual skeletal cylindrical nickel cyclo-hexasiloxanolates, Organomet. Chem. USSR. 4:39 (1991).
V.A.Igonin, S.V.Lindeman, K.A.Potekhin, V.E.Shklover, Yu.T.Struchkov, O.I.Shchegolikhina, A.A.Zhdanov, I.V.Razumovskaya, The structure of sandwich complexes of Ni with macrocyclic 12-membered cis-hexaphenylcyclohexasiloxanolate ligands, Organom. Chem. USSR. 4:383 (1991).
V.A.Igonin, O.I.Shchegolikhina, S.V.Lindeman, M.M.Levitsky, Yu.T.Struchkov, A.A.Zhdanov, Novel class of transition metal coordination compouds with macrocyclic organosiloxanolate ligands, their synthesis and crystal structure, J.Organomet. Chem. 423:351 (1992).
V.A.Igonin, S.V.Lindeman, Yu.T.Struchkov, O.I.Shchegolikhina, A.A.Zhdanov, Yu.A.Molodtsova, I.V.Razumovskaya, Structures of complexes of copper with macrocyclic organosiloxanolates ligands, Organomet. Chem. USSR. 4:672 (1991).
O.I.Shchegolikhina, Yu.A.Molodtsova, Yu.A.Pozdnyakova, T.V.Strelkova, A.A.Zhdanov, Framework metallosiloxanes for synthesis stereoregular siloxanes cycles, Dokl. Akad. Nauk, 325:1186(1992), [Dokl. Chem. 325(1992)] (Engl. Transl.).
I.V.Blagodatskikh, O.I.Shchegolikhina, Yu.A.Pozdnyakova, Yu.A.Molodtsova, A.A.Zhdanov, Applicaton of size exclusion chromatography to the structural study of polyorganometallosiloxanes, Russ. Chem. Bull. 43:(1994), in press.
P.V.Wright and M.S.Beevers, Preparation of cyclic polysiloxanes, in: “Cyclic Polymers”, J.A.Symlyen, ed., Elsevier Applied Science Publishers, N-Y (1986), p. 85–134.
A.A.Zhdanov, O.I.Shchegolikhina, Yu.A.Molodtsova, Peculiarities of the synthesis of cage-like metallosiloxanes, Russ. Chem. Bull. 42:917(1992).
K.A.Andrianov and A.A.Zhdanov, Synthesis of polyphenylalumosiloxanes. The reaction of the exchange interaction of sodium alkylsilantriols with aluminium chloride., Dokl. Akad. Nauk. SSSR 114:1005(1957) (in Russian).
M.Bartolin, A.Guyot, Preparaton de quelques polymetallophenylsiloxanes. Compt. Rend. C264:1694 (1967).
I.L.Dubchak, V.E.Shklover, M.M.Levitskii, A.A.Zhdanov, Yu.T.Struchkov, Crystal structure of siloxanes and silazanes. XIX. Oktahydrate of sodium cis- 1,3,5 -triphenylcyclotrisiloxane-1,3,5-triolate, Zh. Strukt. khimii, 15:103 (1980).
I.V.Blagodatskikh, Yu.A.Pozdnykova, O.I.Shchegolikhina, A.A.Zhdanov, Investigation of polyphenylironsiloxane structure, Russ. Chem. Bull. 1995, in press.
L.M.Khananashvilli and K.A.Andrianov. “Technology of Elementoorganic Monomers and Polymers”. Khimia, Moscow (1983), 415 p. (in Russian).
A.Yu.D’yakonov, O.I.Shchegolikhina, A.D.Kolbanovskii, A.G.Knizhnik, A.L.Buchachenko, A.A.Zhdanov, M.M.Levitskii, Heteroorganic metal-containing paramagnetic and ferromagnetic polymers. 1. Polyferro- and polycobaltsiloxanes, structure and magnetic properties, Bull. Acad. Sci. USSR, Div. Chem. Sci. 39:2271 (1990).
A.A.Zhdanov, A.L.Buchachenko, O.I.Shchegolikhina, R.A.Stukan, A.G.Knizhnik, M.M.Levitskii, Heteroorganic metal-containing paramagnetic and ferromagnetic polymers. 2. Investigation of thermal condensation of polymetalloorganosilloxanes, Bull. Acad. Sci. USSR, Div. Chem. Sci., 40:520 (1991).
A.A.Zhdanov, A.L.Buchachenko, A.Yu.D’yakonov, O.I.Shchegolikhina, M.M.Levitskii. Heteroorganic metal-containing paramagnetic and ferromagnetic polymers. 3. Magnetic properties of the thermal condensation of polymetallic organosiloxanes, Bull. Acad. Sci. USSR, Div. Chem. Sci. 40:680 (1991).
M.Tikadzumi, Physics of Ferromagnetism. Mir, Moscow, 1983, 245 p. (Russian translation).
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Shchegolikhina, O.I., Blagodatskikh, I.V., Pozdnyakova, Y.A., Zhdanov, A.A. (1996). Poly(Phenylmetallosiloxane)S: Synthesis, Structure and Properties. In: Pittman, C.U., Carraher, C.E., Zeldin, M., Sheats, J.E., Culbertson, B.M. (eds) Metal-Containing Polymeric Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0365-7_18
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DOI: https://doi.org/10.1007/978-1-4613-0365-7_18
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