Abstract
Carbamates1 have already gained an important place among pesticides. They do not have the persistence so detrimental to most of the organochlorine compounds but they are degraded less rapidly than the organophosphorus compounds. Like the latter they are cholinesterase inhibitors.
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References
Argauer, R. J.: Determination of residues of Banol and other carbamate pesticides after hydrolysis and chloroacetylation. J. Agr. Food Chem. 17, 888 (1969).
Aue, W. A., C. W. Gehrke, R. C. Tindle, D. L. Stalling, and C. D. Ruyle: Application of the alkali-flame detector to nitrogen containing compounds. J. Gas Chromatog. 5, 381 (1967).
Bache, C. A., and D. T. Lise: Microwave emission residue analysis of carbamate and triazine pesticides. J. Gas Chromatog. 6, 301 (1968).
Bache, C. A., L. E. St. John, Jr., and D. J. Lise: Gas chromatographic analysis of insensitive pesticides as their halomethyldimethylsilyl derivatives. Anal. Chem. 40, 1241 (1968).
Beckman, H., Y. Giang, and J. Qualia: Preparation and detection of derivatives of Temik and its metabolites as residues. J. Agr. Food Chem. 17, 70 (1969).
Bowman, M. C., and M. Beroza: Determination of Niagara NIA-10242 and its phenol degradation product in corn silage and milk and determination of other carbamates by GLC of their thiophosphoryl derivatives. J. Assoc. Official Anal. Chemists 50, 926 (1967a).
Bowman, M. C., and M. Beroza: Determination of residues of Mobil MC-A-600 (benzo (b) thien-4-yl methylcarhamate) and its hydrolysis product (benzo (b)thiophene-4-ol) in coastal Bermuda grass and milk. T. Agr. Food Chem. 15, 894 (1967b).
Bowman, M. C., and M. Beroza: Determination of Mesurol and five of its metabolites in apples, pears, and corn by gas chromatography. J. Assoc. Official Anal. Chemists 52, 1054 (1969).
Butler, L. I., and L. M. Mcdonoucx: Method for the determination of residues of carbamate insecticides by electron-capture gas chromatography. J. Agr. Food Chem. 16, 403 (1968).
Bowman, M. C., and M. Beroza: Specific GLC method for determining residues of carbaryl by electron capture detection after derivative formation. J. Assoc. Official Anal. Chemists 53, 495 (1970).
Cassil, C. C., R. P. Stanovick, and R. F. Coox: A specific gas chromatographic method for residues of organic nitrogen pesticides. Residue Reviews 26, 63 (1969).
Chiba, M., and H. V. Morley: Thin-layer chromatography as a rapid screening method for the determination of carbaryl and 1-naphthol residues without cleanup. J. Assoc. Official Agr. Chemists 47, 667 (1964).
Cook, R. F., R. P. Stanovick, and C. C. Cassn.: Determination of carbofuran and its carbamate metabolite residues in corn using a nitrogen-specific gas chromatographic detector. J. Agr. Food Chem. 17, 277 (1969).
Coulson, D. M.: Electrolytic conductivity detector for gas chromatography. J. Gas Chromatog. 3, 134 (1965).
Coulson, D. M.:Selectivedetection of nitrogen compounds in electrolytic conductivity gas chromatography. J. Gas Chromatog. 4, 285 (1966).
Crosby, D. G., and J. B. Bowers: Amine derivatives for pesticide residue analysis. J. Agr. Food Chem. 16, 839 (1968).
Eberle, D. O., and F. A. Gunther: Chromatographic, spectrometric, and irradiation behavior of five carbamate insecticides. J. Assoc. Official Agr. Chemists 48, 927 (1965).
Ebinc, W.: Gaschromatographische Analyse insektizider Carbamate. Chimia 19, 501 (1965).
Finocchiaro, J. M., and W. R. Benson: Thin-layer chromatography of some carbamate and phenylurea pesticides. J. Assoc. Official Anal. Chemists 50, 888 (1967).
Fishbein, L., and W. L. Zielinski, Jr.: Gas chromatography of trimethylsilyl derivatives. I. Pesticidal carbamates and ureas. J. Chromatog. 20, 9 (1965).
Giuffbma, L.: A flame ionization detector highly selective and sensitive to phosphorus—A sodium thermionic detector. J. Assoc. Official Agr. Chemists 47, 293 (1964).
Gutenmann, W. H., and D. J. Lisx: Gas chromatographic residue determination of Sevin as brominated 1-naphthyl acetate. J. Agr. Food Chem. 13, 48 (1965).
Holden, E. R., W. M. Jones, and M. Beroza: Determination of methyl-and dimethylcarbamate insecticides by gas chromatography of their 2,4-dinitroaniline derivatives. J. Agr. Food Chem. 17, 56 (1969).
Hughes, R. E., Jr., and V. H. Freed: The determination of ethyl N, N-di-npropylthiocarbamate (EPTC) in soil by gas chromatography. J. Agr. Food Chem. 9, 381 (1961).
Ives, N. F., and L. Giuffrida: Investigation of thermionic detector response for the gas chromatography of P, N, As, and Cl organic compounds. J. Assoc. Official Anal. Chemists 50, 1 (1967).
Johnson, D. P.: Determination of Sevin insecticide residues in fruit and vegetables. J. Assoc. Official Agr. Chemists 47, 283 (1964).
Krishna, J. G., H. W. Dorough, and J. E. Casida: Synthesis of N-methylcarbamates via methyl isocyanate-C14 and chromatographic purification. J. Agr. Food Chem. 10, 462 (1962).
Kuhr, R. J., and J. E. Casida: Persistent glycosides of metabolites of methylcarbamate insecticide chemicals formed by hydroxylation in bean plants. J. Agr. Food Chem. 15, 814 (1967).
Landowne, R. A., and S. R. Lipsky: The electron-capture spectrometry of halo-acetates: A means of detecting ultramicro quantities of sterols by gas chromatography. Anal. Chem. 35, 532 (1963).
Lau, S. C., and R. L. Marxmiller: Residue determination of Landrin insecti cide by trifluoroacetylation and electron-capture gas chromatography. J. Agr. Food Chem. 18, 413 (1970).
Mckinley, W. P., D. E. Coffin, and K. A. Mccully: Cleanup process for pesti- cide residue analysis. J. Assoc. Official Agr. Chemists 47, 863 (1964).
Maitlen, J. C., L. M. Mcdonough, and M. Beroza: Determination of residues of 2-methyl-2-(methylthio) propionaldehyde O-(methylcarbamoyl) oxime (UC-21149, Temik), its sulfoxide, and sulfone by gas chromatography. J. Agr. Food Chem. 16, 549 (1968).
Maitlen, J. C., L. M. Mcdonough, and M. Q: Rapid method for the extraction, cleanup, and GLC determination of toxic residues of Temik. J. Assoc. Official Anal. Chemists 52, 786 (1969).
Martin, R. L.: Fast and sensitive method for determination of nitrogen. Anal. Chem. 38, 1209 (1966).
Metcalf, R. L., T. R. Fukuuto, G. Collins, K. Borck, S. Abd El-Aziz, R. Munoz, and C. C. Cassil: Metabolism of 2,2-dimethyl-2,3-dihydrobenzofuranyl-7 N-methylcarbamate (Furadan) in plants, insects, and mammals. J. Agr. Food Chem. 16, 300 (1968).
Morley, H. V.: Adsorbents and their application to column cleanup of pesticide residues. Residue Reviews 16, 1 (1966).
Patchett, G. G.: Evaluation of the electrolytic conductivity detector for residue analyses of nitrogen-containing pesticides. J. Chromatog. Sci. 8, 155 (1970).
Pieper, G. R., and R. P. Miskus: Determination of Zectran residues in aerial forest spraying. J. Agr. Food Chem. 15, 915 (1967).
Ralls, J. W., and A. Cortes: Determination of Sevin in green beans by bromination and electron capture gas chromatography. J. Gas Chromatog. 2, 132 (1964).
Ramasamy, M.: The identification and determination of organophosphorus and carbamate insecticides by thin-layer chromatography. Analyst 94, 1075 (1969).
Riva, M., and A. Carisano: Compact dual-channel flame ionization-cum-thermionic detector for high specificity chromatographic analysis. J. Chromatog. 36, 269 (1968).
Riva, M., and A. Carisano: Direct gas chromatographic determination of carbaryl. J. Chromatog. 42, 464 (1969).
Ruyle, C., W. A. Aue, C. W. Gehrke, D. L. Stalling, and R. C. Tindle: Presented Fifth Nat. Meeting, Soc. Applied Spectroscopy, Chicago, Ill. (June 1966).
Strother, A.: Gas chromatography of various phenyl N-methylcarbamates. J. Gas Chromatog. 6, 110 (1968).
Sullivan, L. J., J. M. Eldridge, and J. B. Knaak: Determination of carbaryl and some other carbamates by gas chromatography. J. Agr. Food Chem. 15, 927 (1967).
Tilden, R. L., and C. H. Van Mmdelem: Determination of carbaryl as an amide derivative by electron-capture gas chromatography. J. Agr. Food Chem. 18, 154 (1970).
Van Middelem, G. H., T. L. Norwood, and R. E. Wastes: Electron affinity G.L.C. residue determination of Sevin and other carbamates following hydrolysis and bromination. J. Gas Chromatog. 3, 310 (1965).
Zielinski, W. L., Jr., and L. Fishbein: Gas chromatography of carbamate derivatives. I. Simple carbamates. J. Gas Chromatog. 3, 142 (1965a).
Zielinski, W. L., Jr., and L. Fishbein: Gas chromatography of carbamate derivatives. II. N-substituted carbamates. J. Gas Chromatog. 3, 333 (1965b).
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Williams, I.H. (1971). Carbamate insecticide residues in plant material: Determination by gas chromatography. In: Gunther, F.A., Gunther, J.D. (eds) Residue Reviews / Rückstands-Berichte. Residue Reviews, vol 38. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-9818-2_1
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DOI: https://doi.org/10.1007/978-1-4612-9818-2_1
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