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Experimental Investigation of Exchange Equilibria in the System Cordierite-Garnet-Biotite

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Kinetics and Equilibrium in Mineral Reactions

Part of the book series: Advances in Physical Geochemistry ((PHYSICAL GEOCHE,volume 3))

Abstract

Cordierite-garnet and biotite-garnet pairs are the most effective thermometers for estimating the equilibrium temperatures in metapelites. Both of these ther-mometers are based on the exchange equilibria with relatively large entropy change in the following reactions:

$${\rm{Co}}{{\rm{r}}_{{\rm{Fe}}}} + {\rm{G}}{{\rm{r}}_{{\rm{Mg}}}} = {\rm{G}}{{\rm{r}}_{{\rm{Fe}}}} + {\rm{Co}}{{\rm{r}}_{{\rm{Mg,}}}}$$
$${\rm{B}}{{\rm{i}}_{{\rm{Fe}}}} + {\rm{G}}{{\rm{r}}_{{\rm{Mg}}}} = {\rm{G}}{{\rm{r}}_{{\rm{Fe}}}} + {\rm{B}}{{\rm{i}}_{{\rm{Mg}}{\rm{.}}}}$$

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Perchuk, L.L., Lavrent’eva, I.V. (1983). Experimental Investigation of Exchange Equilibria in the System Cordierite-Garnet-Biotite. In: Saxena, S.K. (eds) Kinetics and Equilibrium in Mineral Reactions. Advances in Physical Geochemistry, vol 3. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-5587-1_7

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  • DOI: https://doi.org/10.1007/978-1-4612-5587-1_7

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4612-5589-5

  • Online ISBN: 978-1-4612-5587-1

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