Abstract
There are no simple or inexpensive tests for determining the fate of chemicals in the environment. Of numerous approaches, the three most often taken are: (1) measurement of the change in pesticide content in various field environmental compartments (i.e., soil, plant, water, or air) where all the interacting forces, processes, and pathways are at work; (2) measurement of environmental parameters and relating the measured changes in pesticide content to the parameters; or (3) measurement and relation of change in pesticide content in a small segment of the environment (e.g., as simulated in a laboratory flask) in order accurately to measure parameters and processes by minimizing interacting forces or multiple pathways for pesticide dissipation that exist in the field. tiWhen the laboratory approach is taken, the various segmented values have to be combined to describe the total chemical environmental system. Unfortunately, when a segment is iso- lated from interacting forces, processes, and pathways of the environment the value obtained may under- or overemphasize its importance. The best we can hope for is that the sum of the values, when combined, will offset each other and give us a realistic description of the chemical environmental system. When the field approach is taken, control and measurement of the various parameters usually are so limited it is often difficult to relate the results to any given parameter or situation.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Altom, J. D., and J. F. Stritzke: Degradation of dicamba, picloram, and four phenoxy herbicides in soils. Weed Sci. 21, 556 (1973).
Atallah, Y. H., D. M. Whitacre, and B. L. Hoo: Comparative volatility of liquid and granular formulations of chlordane and heptachlor from soil. Bull. Environ. Contam. Toxicol. 22, 570 (1979).
Baker, R. D., and H. G. Applegate: Effect of temperature and ultraviolet radiation on the persistence of methyl parathion and DDT in soils. Agron. J. 62, 509 (1973).
Bowery, T. G.: In G. Zweig (ed.): Analytical methods for pesticides, plant growth regulators, and food additives, vol. II, pp. 49, 245. New York: Academic Press (1964).
Decker, G. C., C. J. Weinman, and J. M. Bann: A preliminary report on the rate of insecticide residue loss from treated plants. J. Econ. Entomol. 43, 919 (1950).
Glotfelty, D. E.: Atmospheric dispersion of pesticides from treated fields. Ph.D. Thesis, pp. 94–187. Univ. of Maryland, College Park (1981).
Guckel, W., G. Synnatschke, and R. Rittig: A method for determining the volatility of active ingredients used in plant protection. Pest. Sci. 4, 137 (1973).
Guenzi, W. D., and W. E. Beard: Volatilization of lindane and DDT from soils. Soil Sci. Soc. Amer. Proc. 34, 443 (1970).
Harper, L. A., A. W. White, Jr., R. R. Bruce, A. W. Thomas, and R. A. Leonard. Soil and microclimate effects on trifluralin volatilization. J. Environ. Qual. 5, 236 (1976).
Hartley, G. S.: Evaporation of pesticides. In: Pesticidal formulations research, physical and colloidal chemical aspects. Adv. Chem. Ser. 86, 115 (1969).
Ketchersid, M. L., R. W. Bovey, and M. G. Merkle: The detection of trifluralin vapors in air. Weed Sci. 17, 484 (1969).
Lane, L. J., H. L. Morton, D. E. Wallace, R. E. Wilson, and R. D. Martin: Non-point source pollutants to determine runoff source areas. Hydrology and Water Resources in Arizona and the Southwest 7, 89 (1977).
Lichtenstein, E. P., and K. R. Schulz: Effect of soil cultivation, soil surface, and water on the persistence of insecticidal residues in soils. J. Econ. Entomol. 54, 517 (1961).
Mullison, W. R., R. W. Bovey, A. P. Burkhalter, T. D. Burkhalter, H. M. Hill, D. L. Sutton, and R. E. Talbert: Herbicide handbook of the Weed Science Society of America, 4th ed., p. 197. 09 West Clark St., Champaign, IL 61820 (1979).
Nash, R. G.: Uptake of ethylenebis(dithiocarbamate) fungicides and ethylene-thiourea by soybeans. J. Agr. Food Chem. 24, 596 (1976).
Nash, R. G., and M. L. Beall, Jr.: Fate of maneb and zineb fungicides in microagro-ecosystem chambers. J. Agr. Food Chem. 28, 322 (1980 a).
Nash, R. G., and M. L. Beall Jr.: Distribution of silvex, 2, 4-D, and TCDD applied to turf in chambers and field plots. J. Agr. Food Chem. 28, 614 (1980 b).
Nash, R. G., and M. L., Beall Jr. and W. G. Harris: Toxaphene and l, l, l-trichloro-2, 2-bis-(p-chlorophenyl) ethane (DDT) losses from cotton in an agroecosystem chamber. J. Agr. Food Chem. 25, 336 (1977).
Newsome, W. H.: Residues of four ethylenebis(dithiocarbamates) and their decomposition products on field-sprayed tomatoes. J. Agr. Food Chem. 24, 999 (1976).
Newsome, W. H. Residues of mancozeb, 2-imidazoline, and ethyleneurea in tomato and potato crops after field treatment with mancozeb. J. Agr. Food Chem. 27, 1188 (1979).
Newsome, W. H., J. B. Shields, and D. C. Villeneuve: Residues of maneb, ethylenethi-uram monosulfide, ethylenethiourea, and ethylenediamine on beans and tomatoes field treated with maneb. J. Agr. Food Chem. 23, 756 (1975).
Nigg, H. N., J. C. Allen, R. F. Brooks, G. J. Edwards, N. P. Thompson, R. W. King, and A. H. Blagg: Dislodgeable residues of ethion in Florida citrus and relationships to weather variable. Arch. Environ. Contam. Toxicol. 6, 257 (1977).
Orgill, M. M., G. A. Sehmel, and M. R. Petersen: Some initial measurements of airborne DDT over Pacific Northwest forests. Atmospheric Environ. 10, 827 (1976).
Rhodes, R. C: Studies with manganese [14C]ethylenebis(dithiocarbamate) ([14C] maneb) fungicide and [14C]ethylenethiourea ([14C]ETU) in plants, soil, and water. J. Agr. Food Chem. 25, 528 (1977).
Spencer, W. F., and M. M. Cliath: Volatility of DDT and related compounds. J. Agr. Food Chem. 20, 645 (1972).
Spencer, W. F., and M. M. Cliath: Factors affecting vapor loss of trifluralin from soil. J. Agr. Food Chem. 22, 987 (1974).
Spencer, W. F., and M. M. Cliath: The solid-air interface: Transfer of organic pollutants between the solid and air phases. In I. H. Suffet (ed.): Adv. Environ. Sci. Technol., p. 107. New York: Wiley (1976).
Spencer, W. F., and M. M. Cliath, W. J. Farmer, and M. M. Cliath: Pesticide volatilization. Residue Reviews 49, 1 (1973).
Stewart, D. K. R., and S. O. Gaul: Persistence of 2, 4-D dichlorophenoxyacetic acid, 2, 4, 5-T, and dicamba in a Dykeland soil. Bull. Environ. Contam. Toxicol. 18, 210 (1977).
Taylor, A. W., D. E. Glotfelty, B. C. Turner, R. E. Silver, H. P. Freeman, and A. Weiss: Volatilization of dieldrin and heptachlor residues from field vegetation. J. Agr. Food Chem. 25, 542 (1977).
Ware, G. W., W. P. Cahill, and B. J. Estesen: Volatilization of DDT and related materials from dry and irrigated soils. Bull. Environ. Contam. Toxicol. 14, 88 (1975).
Willis, G. H., and R. A. Hamilton: Agricultural chemicals in surface runoff, ground water, and soil: I. Endrin. J. Environ. Quality 2, 463 (1973).
Willis, G. H., L. L. McDowell, S. Smith, L. M. Southwick, and E. R. Lemon: Toxa-phene volatilization from a mature cotton canopy. Agron. J. 72, 627 (1980).
Willis, G. H., L. L. McDowell, J. F. Parr, and S. Smith: Volatilization of soil-applied DDT and DDD from flooded and nonflooded plots. Pest. Monit. J. 4, 204 (1971).
Wilson, R. G., Jr., and H. H. Cheng: Fate of 2, 4-D in a Naff silt loam soil. J. Environ. Qual. 7, 281 (1978).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1983 Springer-Verlag New York Inc.
About this paper
Cite this paper
Nash, R.G. (1983). Determining environmental fate of pesticides with microagroecosystems. In: Gunther, F.A., Gunther, J.D. (eds) Residue Reviews. Residue Reviews, vol 85. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-5462-1_15
Download citation
DOI: https://doi.org/10.1007/978-1-4612-5462-1_15
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4612-5464-5
Online ISBN: 978-1-4612-5462-1
eBook Packages: Springer Book Archive