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Charge Exchange Between Localized Sites

  • J. Jortner
  • M. Bixon
Part of the Proceedings in Life Sciences book series (LIFE SCIENCES)

Abstract

We examine two distinct classes of quantum mechanical effects on the dynamics of electron transfer (ET) processes between a spatially fixed donor-acceptor pair. First, we review the conventional ET processes, which occur from a thermally equilibrated initial vibrational manifold and consider the nature of the electronic coupling, i.e., direct exchange and superexchange, as well as nuclear overlap contributions. Conventional ET with some quantitative modifications is applicable for the description of the later charge separation events in bacterial photosynthesis, which occur on the time scale t > 10 psec. Second, we consider the implications of the competition between ET and medium-induced vibrational relaxation.

Such a modified ET theory may be applicable for the description of the primary charge separation in bacterial photosynthesis, which occurs on the psec (or subpsec) time scale.

Keywords

Electron Transfer Photosynthetic Bacterium Electronic Coupling Vibrational Relaxation Charge Transfer State 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1987

Authors and Affiliations

  • J. Jortner
    • 1
  • M. Bixon
    • 1
  1. 1.Department of ChemistryTel Aviv UniversityTel AvivIsrael

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