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Physical Chemistry of Magmas pp 152–191Cite as

The Role of High Field Strength Cations in Silicate Melts

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Part of the book series: Advances in Physical Geochemistry ((PHYSICAL GEOCHE,volume 9))

Abstract

Early models of melt structure focused almost exclusively on the role of the polymerized aluminosilicate tetrahedral framework. Solubility relations, trace element partitioning patterns, redox equilibria and the occurrence of liquid immiscibility among other properties were explained in the following way. A highly polymerized melt is a relatively inflexible structure with few non-bridging oxygen. High field strength cations cannot substitute into the tetrahedrally coordinated structure (TO), and have difficulty in achieving coordination polyhedra of oxygen within the network. This difficulty limits the solubility of the cations whose addition leads eventually to crystallization or to silicate liquid immiscibility.

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Authors
  1. Paul C. Hess
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Editors and Affiliations

  1. Institute of Experimental Mineralogy, USSR Academy of Sciences, Moscow District, Chernogolovka, 142432, Russia

    Leonid L. Perchuk

  2. Geological Institute, Faculty of Science, University of Tokyo, Tokyo, 113, Japan

    Ikuo Kushiro

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Hess, P.C. (1991). The Role of High Field Strength Cations in Silicate Melts. In: Perchuk, L.L., Kushiro, I. (eds) Physical Chemistry of Magmas. Advances in Physical Geochemistry, vol 9. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-3128-8_5

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  • DOI: https://doi.org/10.1007/978-1-4612-3128-8_5

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