Skip to main content

Factors Affecting Atrazine Fate in North Central U.S. Soils

  • Chapter
Reviews of Environmental Contamination and Toxicology

Part of the book series: Reviews of Environmental Contamination and Toxicology ((RECT,volume 151))

Abstract

Atrazine (6-chloro-N-ethyl-N′-(l-methylethyl)-l,3,5-triazine-2,4-diamine) is a herbicide of the triazine family used for controlling broadleaf and some grassy weeds in corn and sorghum. Since its introduction in the late 1950s, atrazine has been a popular herbicide because it is relatively inexpensive and, in most cases, gives good season-long weed control. It can be applied pre-or postemergence and is often tank mixed with grass herbicides, such as alachlor (2-chloro-N-(2,6-diethylphenyl-N-(methoxymethyl)acetamide), metolachlor(2-chloro-N-(2-2ethyl-6-methylphenyl)-N-(2-methoxy-l-methylethyl) acetamide), butylate (S-ethyl bis(2-methylpropyl)carbamothioate), or EPTC (S-ethyl dipropylcarbamothioate), or with other broadleaf herbicides, such as dicamba (3,6-dichloro-2-methoxybenzoic acid), to obtain broad-spectrum weed control. Atrazine mixed with nicosulfuron {2-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-N,N-dimethyl-3-pyridinecarboxamide} or bromoxynil (3,5-dibromo-4-hydro-xybenzonitrile) is commonly used across the northern Corn Belt; when mixed with cyanazine {2-[[4-chloro-6-(ethylamino)-l,3,5-triazin-2-yl]amino]-2-methylpropanenitrile}, it is commonly used in total weed control programs in southern Iowa, Illinois, Indiana, and Ohio.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Adams CD, Thurman EM (1991) Formation and transport of deethylatrazine in the soil and vadose zone. J Environ Qual 20:540–547.

    Article  CAS  Google Scholar 

  • Alhajjar BJ, Simsiman GV, Chesters G (1990) Fate and transport of alachlor, metolachlor, and atrazine in large columns. Water Sci Technol 22:87–94.

    CAS  Google Scholar 

  • Anderson JR, Stephenson GR, Corke CT (1980) Atrazine and cyanazine activity in Ontario and Manitoba soils. Can J Soil Sci 60:773–781.

    Article  CAS  Google Scholar 

  • Anderson TA, Kruger EL, Coats JR (1994) Enhanced degradation of a mixture of three herbicides in the rhizosphere of a herbicide-tolerant plant. Chemosphere 28:1551–1557.

    Article  CAS  Google Scholar 

  • Armstrong DE, Chesters G, Harris RF (1967) Atrazine hydrolysis in soil. Soil Sci Soc Am Proc 31:61–66.

    Article  CAS  Google Scholar 

  • Armstrong DE, Chesters G (1968) Adsorption catalyzed chemical hydrolysis of atrazine. Environ Sci Technol 9:683–689.

    Article  Google Scholar 

  • Aspelin AL (1996) Pesticides industry sales and usage, 1994 and 1995 market estimates. 733-K96-001, June 1996. U.S. Environmental Protection Agency, Office of Pesticide Programs, Biological and Economic Analysis Division, Washington, DC.

    Google Scholar 

  • Assaf NA, Turco RF (1994) Influence of carbon and nitrogen application on the mineralization of atrazine and its metabolites in soil. Pestic Sci 41:41–47.

    Article  CAS  Google Scholar 

  • Baker JL, Mickelson SK (1994) Application technology and best management practices for minimizing herbicide runoff. Weed Technol 8:862–869.

    Google Scholar 

  • Baluch HU, Somasundaram L, Kanwar RS, Coats JR (1993) Fate of major degradation products of atrazine in Iowa soils. J Environ Sci Health B 28:127–149.

    Article  Google Scholar 

  • Bandeen JD, Stephenson GR, Cowett ER (1982) Discovery and distribution of herbicide-resistant weeds in North America. In: Le Baron HM, Gressel J (eds) Herbicide Resistance in Plants. Wiley, New York, pp 9–30.

    Google Scholar 

  • Barley KP (1954) Effects of root growth and decay on the permeability of synthetic sandy loam. Soil Sci 78:205–210.

    Article  Google Scholar 

  • Barrett MR (1996) The environmental impact of pesticide degradates in groundwater. In: Meyer MT, Thurman EM (eds) Herbicide Metabolites in Surface Water and Groundwater. ACS Symp Ser 630. American Chemical Society, Washington, DC, pp 200–225.

    Chapter  Google Scholar 

  • Barriuso E, Koskinen WC (1996) Incorporating nonextractable atrazine residues into soil size fractions as a function of time. Soil Sci Soc Am J 60:150–157.

    Article  CAS  Google Scholar 

  • Barriuso E, Koskinen WC, Sorenson B (1992) Modification of atrazine desorption during field incubation experiments. Sci Total Environ 123/124:333–344.

    Article  Google Scholar 

  • Barriuso E, Laird DA, Koskinen WC, Dowdy RH (1994) Atrazine desorption from smectites. Soil Sci Soc Am J 58:1632–1638.

    Article  CAS  Google Scholar 

  • Behki R, Topp E, Dick W, Germon P (1993) Metabolism of the herbicide atrazine by Rhodococcus strains. Appl Environ Microbiol 59:1955–1959.

    PubMed  CAS  Google Scholar 

  • Behki RM, Khan SU (1986) Degradation of atrazine by Pseudomonas: N-dealkylation and dehalogenation of atrazine and its metabolites. J Agric Food Chem 34:746–749.

    Article  CAS  Google Scholar 

  • Behki RM, Khan SU (1994) Degradation of atrazine, propazione, simazine by Rhodococcus strain B-30. J Agric Food Chem 42:1237–1241.

    Article  CAS  Google Scholar 

  • Blevins RL, Frye WW, Baldwin PL, Robertson SD (1990) Tillage effects on sediment and soluble nutrient losses from a Maury silt loam soil. J Environ Qual 19:683–686.

    Article  Google Scholar 

  • Bowman BT (1989) Mobility and persistence of the herbicides atrazine, metolachlor and terbuthylazine in Plainfield sand determined using field lysimeters. Environ Toxicol Chem 8:485–491.

    Article  CAS  Google Scholar 

  • Bowman BT (1990) Mobility and persistence of alachlor, atrazine and metolachlor in Plainfield sand, and atrazine and isazofos in Honeywood silt loam, using field lysimeters. Environ Toxicol Chem 9:453–461.

    Article  CAS  Google Scholar 

  • Bowman BT (1991) Mobility and dissipation studies of metribuzin, atrazine and their metabolites in Plainfield sand using field lysimeters. Environ Toxicol Chem 10:573–579.

    Article  CAS  Google Scholar 

  • Bowman BT (1993) Effect of formulation upon movement and dissipation of 14C-metolachlor and atrazine in field lysimeters. Can J Soil Sci 73:309–316.

    Article  CAS  Google Scholar 

  • Brady JF, LeMasters GS, Williams RK, Pittman JH, Daubert JP, Cheung MW, Skinner DH, Turner J, Rowland MA, Lange J, Sobek SM (1995) Immunoassay analysis and gas chromatography confirmation of atrazine residues in water samples from a field study conducted in the state of Wisconsin. J Agric Food Chem 43:268–274.

    Article  CAS  Google Scholar 

  • Brejda JJ, Shea PJ, Moser LE, Waller SS (1988) Atrazine dissipation and off-plot movement in a Nebraska sandhills subirrigated meadow. J Range Manage 41:416–420.

    Article  CAS  Google Scholar 

  • Brouwer WWM, Boesten JJTI, Siegers WG (1990) Adsorption of transformation products of atrazine by soil. Weed Res 30:123–128.

    Article  CAS  Google Scholar 

  • Brown CB, White JL (1969) Reactions of 12 s-triazines with soil clays. Soil Sci Soc Am Proc 33:863–867.

    Article  CAS  Google Scholar 

  • Buhler DD, Randall GW, Koskinen WC, Wyse DL (1993) Atrazine and alachlor losses from subsurface tile drainage of a clay loam soil. J Environ Qual 22:583–588.

    Article  CAS  Google Scholar 

  • Buhler DD, Koskinen WC, Schreiber MM, Gan J (1994) Dissipation of alachlor, metolachlor, and atrazine from starch encapsulated formulations in a sandy loam soil. Weed Sci 42:411–417.

    CAS  Google Scholar 

  • Burnside OC, Wicks GA (1980) Atrazine carryover in soil in a reduced tillage crop production system. J Weed Sci 28:661–666.

    CAS  Google Scholar 

  • Calvert R (1980) Adsorption-desorption phenomena. In: Hance RJ (ed) Interactions between Herbicides and the Soil. Academic Press, London, pp. 1–30.

    Google Scholar 

  • Capriel P, Haisch A, Khan SU (1985) Distribution and nature of bound (nonextractable) residues of atrazine in a mineral soil nine years after the herbicide application. J Agric Food Chem 33:567–569.

    Article  CAS  Google Scholar 

  • Ciba-Geigy (1992a) A review of historical surface water monitoring for atrazine in eleven states in the central United States (1975–1991). Tech Rep 11-92. Environmental and Public Affairs Department, Ciba-Geigy Corporation, Greensboro, NC.

    Google Scholar 

  • Ciba-Geigy (1992b) A review of historical surface water monitoring for atrazine in the Mississippi, Missouri, and Ohio rivers, 1975–1991. Tech Rep 6-92. Environmental and Public Affairs Department, Ciba-Geigy Corporation, Greensboro, NC.

    Google Scholar 

  • Ciba-Geigy (1993) Biological assessment of atrazine and metolachlor in rainfall. Tech Rep 1-1993. Environmental and Public Affairs Department, Ciba-Geigy Corporation, Greensboro, NC.

    Google Scholar 

  • Clay SA, Allmaras RR, Koskinen WC, Wyse DL (1988a) Desorption of atrazine and cyanazine from soil. J Environ Qual 17:719–723.

    Article  CAS  Google Scholar 

  • Clay SA, Koskinen WC, Allmaras RR, Dowdy RH (1988b) Differences in herbicide adsorption on soil using several soil pH modification techniques. J Environ Sci Health B 23:559–573.

    Google Scholar 

  • Clay SA, Koskinen WC (1990a) Characterization of alachlor and atrazine desorption from soils. Weed Sci 38:74–80.

    CAS  Google Scholar 

  • Clay SA, Koskinen WC (1990b) Adsorption and desorption of atrazine, hydroxya-trazine and S-gluthathione atrazine on two soils. Weed Sci 38:262–266.

    CAS  Google Scholar 

  • Clay SA, Scholes KA, Clay DE (1994) Fertilizer shank placement impact on atrazine movement in a ridge tillage system. Weed Sci 42:86–91.

    CAS  Google Scholar 

  • Clay SA, Clay DE, Liu Z, Harper SS (1996) The effect of ammonia on atrazine sorption and transport. In: Meyer MT, Thurman EM (eds) Herbicide Metabolites in Surface Water and Groundwater. ACS Symp Ser 630. American Chemical Society, Washington, DC, pp 117–124.

    Chapter  Google Scholar 

  • Cook AM, Hutter R (1981) s-triazines as nitrogen sources for bacteria. J Agric Food Chem 29:1135–1143.

    Article  CAS  Google Scholar 

  • Dao TH, Lavy TL, Sorensen RC (1979) Atrazine degradation and residue distribution in soil. Soil Sci Soc Am J 43:1129–1134.

    Article  CAS  Google Scholar 

  • Davidson JM, Rao PSC, Ou LT, Wheeler WB, Rothwell DF (1980) Adsorption, movement, and biodegradation of large concentrations of selected pesticides in soil. EPA-600/2-80-124. U.S. Environmental Protection Agency, Cincinnati, OH.

    Google Scholar 

  • de Souza ML, Wackett LP, Boundy-Mills KL, Mandelbaum RT, Sadowsky MJ (1995) Cloning, characterization, and expression of a gene region from Pseudomonas sp. strain ADP involved in the dechlorination of atrazine. Appl Environ Microbiol 61:3373–3378.

    PubMed  Google Scholar 

  • DeSutter TM, Clay SA, Clay DE (1995) Agrichemical movement with wind-eroded sediment. Proc North Central Weed Sci Soc 50:26.

    Google Scholar 

  • Dowdy RH, Lamb JA, Anderson JL, Reicosky DC, Alessi RS (1995) Atrazine and alachlor leaching under corn/soybean canopies. In: Clean Water-Clean Environment—21st Century, Vol. 1, Conference Proceedings. American Society of Agricultural Engineers, March 5–8, Kansas City, MO, pp 65–68.

    Google Scholar 

  • Edwards WM, Shipitalo MJ, Dick WA, Owens LB (1992a) Rainfall intensity affects transport of water and chemicals through macropores in no-till soil. Soil Sci Soc Am J 56:52–58.

    Article  Google Scholar 

  • Edwards WM, Shipitalo MJ, Traina SJ, Edwards SA, Owens LB (1992b) Role of Lumbricus terrestris (L.) burrows on quality of infiltrating water. Soil Biol Biochem 24:1555–1561.

    Article  Google Scholar 

  • Edwards WM, Shipitalo MJ, Owens LB, Dick WA (1993) Factors affecting preferential flow of water and atrazine through earthworm burrows under continuous no-till corn. J Environ Qual 22:453–457.

    Article  CAS  Google Scholar 

  • Ellis L (1996) Atrazine. In: Biocatalysis/Biodegradation Database, University of Minnesota. Available at http://dragon.labmed.umn.edu/~lynda/index.html.

  • Fausey N, Dowdy R, Steinheimer T, Spalding R, Blanchard P, Lowery B, Albus W, Clay SA (1995) Where’s the atrazine—a regional ground water synopsis. In: Clean Water-Clean Environment-21st Century Vol. 1, Conference Proceedings. American Society of Agricultural Engineers, March 5–8,1995, Kansas City, MO, pp 69–72.

    Google Scholar 

  • Fleming GF, Simmons FW, Wax LM, Wing RE, Carr ME (1992) Atrazine movement in soil columns as influenced by starch-encapsulation and acrylic polymer additives. Weed Sci 40:465–470.

    CAS  Google Scholar 

  • Frank R, Sirons GJ (1985) Dissipation of atrazine residues from soils. Bull Environ Contam Toxicol 34:541–548.

    Article  PubMed  CAS  Google Scholar 

  • Frank R, Clegg BS, Ripley BD, Braun HE (1987) Investigations of pesticide contaminations in rural wells, 1979–1984, Ontario, Canada. Arch Environ Contam Toxicol 16:9–22.

    Article  CAS  Google Scholar 

  • Frank R, Braun HE, Clegg BS, Ripley BD, Johnson R (1990a) Survey of farm wells for pesticides, Ontario, Canada, 1986 and 1987. Bull Environ Contam Toxicol 44:410–419.

    Article  PubMed  CAS  Google Scholar 

  • Frank R, Clegg BS, Sherman C, Chapman ND (1990b) Triazine and chloroacetamide herbicides in Sydenham river water and municipal drinking water, Dresden, Ontario, Canada, 1981–1987. Arch Environ Contam Toxicol 19:319–324.

    Article  PubMed  CAS  Google Scholar 

  • Frank R, Clegg BS, Patni NK (1991) Dissipation of atrazine on a clay loam soil, Ontario, Canada, 1986–90. Arch Environ Contam Toxicol 21:41–50.

    Article  CAS  Google Scholar 

  • Gaber HM, Inskeep WP, Comfort SD, Wraith JM (1995) Nonequilibrium transport of atrazine through large intact soil cores. Soil Sci Soc Am J 59:60–67.

    Article  CAS  Google Scholar 

  • Gamble DS, Haniff MI, Zienius RH (1986) Solution phase complexing of atrazine by fulvic acid: A batch ultrafiltration technique. Anal Chem 54:727–731.

    Article  Google Scholar 

  • Gamble DS, Khan SU (1985) Atrazine hydrolysis in soils: Catalysis by the acidic functional groups of fulvic acid. Can J Soil Sci 65:435–443.

    Article  CAS  Google Scholar 

  • Gamble DS, Khan SU (1990) Atrazine in organic soil: chemical speciation during heterogeneous catalysis. J Agric Food Chem 38:297–308.

    Article  CAS  Google Scholar 

  • Gamerdinger AP, Lemley AT, Wagenet RJ (1991) Nonequilibrium sorption and degradation of three 2-chloro-s-triazine herbicides in soil water systems. J Environ Qual 20:815–822.

    Article  CAS  Google Scholar 

  • Gan J, Becker RL, Koskinen WC, Buhler DD (1996) Degradation of atrazine as a function of concentration. J Environ Qual 25:1064–1072.

    Article  CAS  Google Scholar 

  • Gaynor JD, Stone JA, Vyn TJ (1987) Tillage systems and atrazine and alachlor residues on a poorly drained soil. Can J Soil Sci 67:959–963.

    Article  CAS  Google Scholar 

  • Gaynor JD, MacTavish DC, Findlay WI (1992) Surface and subsurface transport of atrazine and alachlor from a Brookston clay loam under continuous corn production. Arch Environ Contam Toxicol 23:240–245.

    Article  CAS  Google Scholar 

  • Gaynor JD, MacTavish DC, Findlay WI (1995) Atrazine and metolachlor loss in surface and subsurface runoff from three tillage treatments in corn. J Environ Qual 24:246–256.

    Article  CAS  Google Scholar 

  • Gaynor JD, van Wesenbeeck IJ (1995) Effects of band widths on atrazine, metri-buzin, and metolachlor runoff. Weed Technol 9:107–112.

    CAS  Google Scholar 

  • Ghadiri H, Shea PJ, Wicks GA, Haderlie LC (1984) Atrazine dissipation in conven-tional-till and no-till sorghum. J Environ Qual 13:549–552.

    Article  Google Scholar 

  • Gianessi LP, Puffer C (1991) Herbicide use in the United States: national summary report. Resources for the Future, Washington, DC.

    Google Scholar 

  • Giardi MT, Giardina MC, Filacchioni G (1985) Chemical and biological degradation of primary metabolites of atrazine by a Nocardia strain. Agric Biol Chem 49:1551–1558.

    Article  CAS  Google Scholar 

  • Giardina MC, Giardi MT, Filacchioni G (1980) 4-Amino-2-chloro-l,3,5-triazine: A new metabolite of atrazine by soil bacterium. Agric Biol Chem 44:2067-2072.

    Google Scholar 

  • Giardina MC, Giardi MT, Filacchioni G (1982) Atrazine metabolism by Nocardia: elucidation of initial pathway and synthesis of potential metabolites. Agric Biol Chem 46:1439–1445.

    Article  CAS  Google Scholar 

  • Gish TG, Shirmohammadi A, Wienhold BJ (1994) Field-scale mobility and persistence of commercial and starch-encapsulated atrazine and alachlor. J Environ Qual 23:355–359.

    Article  CAS  Google Scholar 

  • Gish TJ, Sadeghi A, Weinhold BJ (1995a) Volatilization of alachlor and atrazine asin fluenced by surface litter. Chemosphere 31:2971–2982.

    Article  CAS  Google Scholar 

  • Gish TG, Shirmohammadi A, Vyravipillai R, Wienhold B J (1995b) Herbicide leaching under tilled and no-tillage fields. Soil Sci Soc Am J 59:895–901.

    Article  CAS  Google Scholar 

  • Glotfelty DE, Leech MM, Jersey J, Taylor AW (1989) Volatilization and winderosion of soil surface applied atrazine, simazine, alachlor, and toxaphene. J Agric Food Chem 37:546–551.

    Article  CAS  Google Scholar 

  • Goetz AJ, Walker RH, Wehtje G, Hajek BF (1988) Sorption and mobility of chlorimuron in Alabama soils. Weed Sci 37:428–433.

    Google Scholar 

  • Goolsby DA, Battaglia WA (1995) Occurrence and distribution of pesticides in rivers of the Midwestern United States. In: Leng ML, Leovey EMK, Zubkoff PLZ (eds) Agrochemical Environmental Fate: State of the Art. CRC Press, Boca Raton, FL, pp 159–173.

    Google Scholar 

  • Green JD, Horton R, Baker JL (1995) Crop residue effects on the leaching of surface-applied chemicals. J Environ Qual 24:343–351.

    Article  CAS  Google Scholar 

  • Guo L, Bicki TJ, Felsot AS, Hinesly TD (1991a) Phytotoxicity of atrazine and alachlor in soil amended with sludge, manure and activated carbon. J Environ Sci Health B 26:513–527.

    Article  Google Scholar 

  • Guo L, Bicki TJ, Hinesly TD, Felsot AS (1991b) Effect of carbon-rich waste materials on movement and sorption of atrazine in a sandy, coarse-textured soil. Environ Toxicol Chem 10:1273–1282.

    Article  CAS  Google Scholar 

  • Hall JK, Hartwig NL (1978) Atrazine mobility in two soils under conventional tillage. J Environ Qual 7:63–68.

    Article  CAS  Google Scholar 

  • Hall JK, Hartwig NL, Hoffman LK (1983) Application mode and alternative cropping effects on atrazine losses from a hillside. J Environ Qual 12:336–340.

    Article  Google Scholar 

  • Hall JK, Murray MR, Hartwig NL (1989) Herbicide leaching and distribution in tilled and untilled soil. J Environ Qual 18:439–445.

    Article  CAS  Google Scholar 

  • Hall JK, Mumma RO, Watts DW (1991) Leaching and runoff losses of herbicides in a tilled and untilled field. Agric Ecosyst Environ 37:303–314.

    Article  CAS  Google Scholar 

  • Hamaker JW, Thompson JM (1972) Adsorption. In: Goring CAI, Hamaker JW (eds) Organic Chemicals in the Soil Environment. Marcel Dekker, New York, NY, pp. 49–143.

    Google Scholar 

  • Haniff MI, Zienius RH, Langford CH, Gamble DS (1985) The solution phase complexing of atrazine by fulvic acid: Equilibria at 25°C. J. Environ Sci Health 820:215–262.

    Google Scholar 

  • Hatfield JL, Wesley CK, Prueger JH, Pfeiffer RL (1996) Herbicide and nitrate distribution in Central Iowa rainfall. J Environ Qual 25:259–264.

    Article  CAS  Google Scholar 

  • Helling CS (1968) Pesticide mobility in soils. I. Parameters of thin-layer chromatog-raphy. Soil Sci Soc Am Proc 35:732–737.

    Google Scholar 

  • Helling CS, Turner BC (1968) Pesticide mobility: determination by soil thin-layer chromatography. Science 162:562–563.

    Article  PubMed  CAS  Google Scholar 

  • Helling CS, Zhuang W, Gish TJ, Coffman CB, Isensee AR, Kearney PC, Hoagland DR, Woodward MD (1988) Persistence and leaching of atrazine, alachlor, and cyanazine under no-tillage practices. Chemosphere 17:175–187.

    Article  CAS  Google Scholar 

  • Hickey WJ, Fuster DJ, Lamar RT (1994) Transformation of atrazine in soil by Phanerochaete chrososporium. Soil Biol Biochem 26:1665–1671.

    Article  CAS  Google Scholar 

  • Isensee AR, Helling CS, Gish TJ, Kearney PC, Coffman CB, Zhuang W (1988) Chemosphere 17:165–174.

    Article  CAS  Google Scholar 

  • Isensee AR, Nash RG, Helling CS (1990) Effect of conventional vs. no-tillage on pesticide leaching to shallow groundwater. J Environ Qual 19:434–440.

    Article  CAS  Google Scholar 

  • Isensee AR, Sadeghi AM (1994) Effects of tillage and rainfall on atrazine residue levels in soil. Weed Sci 42:462–467.

    CAS  Google Scholar 

  • Jayachandran K, Steinheimer TR, Somasundaram L, Moorman TB, Kanwar RS, Coats JR (1994) Occurrence of atrazine and degradates as contaminants of sub surface drainage and shallow groundwater. J Environ Qual 23:311–319.

    Article  CAS  Google Scholar 

  • Junk GA, Spalding RF, Richard JJ (1980) Areal, vertical, and temporal differences in ground water chemistry: II. Organic consituents. J Environ Qual 9:479–483.

    Article  CAS  Google Scholar 

  • Kalkhoff SJ, Detroy MG, Cherryholmes KL, Kuzniar RL (1992) Herbicide and nitrate variation in alluvium underlying a corn field at a site in Iowa County, Iowa. Water Resour Bull 28:1001–1011.

    Article  Google Scholar 

  • Kaufman DD, Blake J (1970) Degradation of atrazine by soil fungi. Soil Biol Bio chem 2:73–80.

    Article  CAS  Google Scholar 

  • Khakural BR, Robert PC, Koskinen WC, Sorenson BA, Buhler DD, Wyse DL (1995) Test of the leaching estimation and chemistry model for predicting atra-zine movement in three Minnesota soils. J Environ Qual 24:644–655.

    Article  CAS  Google Scholar 

  • Khan SU, Marriage PB (1977) Residues of atrazine and its metabolites in an orchard soil and their uptake by oat plants. J Agric Food Chem 25:1408–1413.

    Article  PubMed  CAS  Google Scholar 

  • Khan SU (1978) Kinetics of hydrolysis of atrazine in aqueous fulvic acid solution. Pestic Sci 9:39–43.

    Article  CAS  Google Scholar 

  • Khan SU (1982) Bound pesticide residues in soil and plants. Residue Rev 84:1–25.

    Article  PubMed  CAS  Google Scholar 

  • Khan SU, Behki RM (1990) Effects of Pseudomonas species on the release of bound 14C residues from soil treated with [14C]atrazine. J Agric Food Chem 38:2090–2093.

    Article  CAS  Google Scholar 

  • Kladivko EJ, Van Scoyoc GE, Monke EJ, Oates KM, Pask W (1991) Pesticide and nutrient movement into subsurface tile drains on a silt loam soil in Indiana. J Environ Qual 20:264–270.

    Article  CAS  Google Scholar 

  • Kolpin DW, Kalkhoff SJ (1993) Atrazine degradation in a small stream in Iowa. Environ Sci Technol 27:134–139.

    Article  CAS  Google Scholar 

  • Kolpin DW, Thurman EM, Goolsby DA (1996) Occurrence of selected pesticides and their metabolites in near surface aquifers of the Midwestern United States. Environ Sci Technol 30:335–340.

    Article  CAS  Google Scholar 

  • Konopka A, Turco R (1991) Biodegradation of organic compounds in vadose zone and aquifer sediments. Appl Environ Microbiol 57:2260–2268

    PubMed  CAS  Google Scholar 

  • Koskinen WC, Moorman EE (1985) Factors affecting triazine and substituted-urea adsorption in soil. Abstracts, February, 1985, St. Louis MO, Weed Science Society of America, Champaign, IL, p 96.

    Google Scholar 

  • Koskinen WC, Harper SS (1990) The retention process: mechanisms. In: Cheng HH (ed) Pesticides in the Soil Environment. Soil Science Society of America, Madison, WI, pp 51–77.

    Google Scholar 

  • Koskinen WC, Reynolds KM, Buhler DD, Wyse DL, Barber BL, Jarvis LJ (1993) Persistence and movement of sethoxydim residues in three Minnesota soils. Weed Sci 41:634–640.

    CAS  Google Scholar 

  • Koskinen WC, Sellung KE, Baker JM, Barber BL, Dowdy RH (1994) Ultrasonic decom position of atrazine and alachlor in water. J Environ Sci Health B 29:581–590.

    Article  Google Scholar 

  • Koskinen WC, Cheng HH, Jarvis LJ, Sorenson BA (1995) Characterization of mechanisms of pesticide retention in soils using the supercritical fluid extraction technique. Int J Environ Anal Chem 58:379–385.

    Article  CAS  Google Scholar 

  • Koskinen WC, Rochette EA (1996) Atrazine sorption-desorption in field-moist soils. Int J Environ Anal Chem 65:223–230.

    Article  CAS  Google Scholar 

  • Kruger EL, Somasundaram L, Kan war RS, Coats JR (1993 a) Persistence and degradation of [14C]atrazine and [14C]deisopropylatrazine as affected by soil depth and moisture conditions. Environ Toxicol Chem 12:1959–1967.

    CAS  Google Scholar 

  • Kruger EL, Somasundaram L, Kanwar RS, Coats JR (1993b) Movement and degradation of [14C] atrazine in undisturbed soil columns. Environ Toxicol Chem 12:1969–1975.

    CAS  Google Scholar 

  • Kruger EL, Rice PJ, Anhalt JC, Anderson TA, Coats JR (1996a) Use of undisturbed soil columns under controlled conditions to study the fate of [14C]deethy-latrazine. J Agric Food Chem 44:1144–1149.

    Article  CAS  Google Scholar 

  • Kruger EL, Zhu B, Coats JR (1996b) Relative mobilities of atrazine, five atrazine degradates, metolachlor, and simazine in soils of Iowa. Environ Toxicol Chem 15:691–695.

    Article  CAS  Google Scholar 

  • Laird DA, Barriuso E, Dowdy RH, Koskinen WC (1992) Adsorption of atrazine on smectites. Soil Sci Soc Am J 56:62–67.

    Article  CAS  Google Scholar 

  • Laird DA, Yen PY, Koskinen WC, Steinheimer TR, Dowdy RH (1994) Sorption of atrazine on soil clay components. Environ Sci Technol 28:1054–1061

    Article  PubMed  CAS  Google Scholar 

  • Laird DA (1996) Interactions between atrazine and smectite surfaces. In: Meyer MT, Thurman EM (eds) Herbicide Metabolites in Surface Water and Groundwater. ACS Symp Ser 630. American Chemical Society, Washington, DC, pp 86–100.

    Chapter  Google Scholar 

  • Lamoureux GL, Stafford LE, Shimabukuro RH (1972) Conjugation of 2-chloro-4,6-bis(alkylamino)-s-triazines in plants. J Agric Food Chem 20:1004–1010.

    Article  CAS  Google Scholar 

  • Lavy TL, Roeth FW, Fenster CR (1973) Degradation of 2,4-D and atrazine at three soil depths in the field. J Environ Qual 2:132–137.

    Article  CAS  Google Scholar 

  • Leavitt RA, Kells JJ, Bunkelmann JR, Hollingworth RM (1991) Assessing atrazine persistence in soil following a severe drought. Bull Environ Contam Toxicol 46:22–29.

    Article  PubMed  CAS  Google Scholar 

  • Lee RF, Weber JB (1993) Influence of polymers on the mobility, loss, and bioactivity of 14C from 14C-labeled atrazine, metolachlor and primisulfuron. J Agric Food Chem 41:988–995.

    Article  CAS  Google Scholar 

  • Lerch RN, Donald WW, Li YX, Alberts EE (1995) Hydroxylated atrazine degradation products in a small Missouri stream. Environ Sci Technol 29:2759–2768

    Article  PubMed  CAS  Google Scholar 

  • Levanon D, Codling EE, Meisinger JJ, Starr JL (1993) Mobility of agrochemicals through soil from two tillage systems. J Environ Qual 22:155–161

    Article  CAS  Google Scholar 

  • Levanon D, Meisinger JJ, Codling EE, Starr JL (1994) Impact of tillage on microbial activity and the fate of pesticides in the upper soil. Water Air Soil Pollut 72:179–189.

    Article  CAS  Google Scholar 

  • Levy J, Chesters G (1995) Simulation of atrazine and metabolite transport and fate in a sandy-till aquifer. J Contam Hydrol 20:67–88

    Article  CAS  Google Scholar 

  • Liu Z, Clay SA, Clay DE, Harper SS (1995a) Ammonia impacts on atrazine leaching through undisturbed soil columns. J Environ Qual 24:1170–1173.

    Article  CAS  Google Scholar 

  • Liu Z, Clay SA, Clay DE, Harper SS (1995b) Ammonia fertilizer influences atrazine adsorption-desorption characteristics. J Agric Food Chem 43:815–819

    Article  CAS  Google Scholar 

  • Logan TJ, Eckert DJ, Beak DG (1994) Tillage, crop and climatic effects on runoff and tile drainage losses of nitrate and four herbicides. Soil Tillage Res 30:75–103.

    Article  Google Scholar 

  • Mandelbaum RT, Wackett LP, Allan DL (1993a) Rapid hydrolysis of atrazine to hydroxyatrazine by soil bacteria. Environ Sci Technol 27:1943–1946.

    Article  CAS  Google Scholar 

  • Mandelbaum RT, Wackett LP, Allan DL (1993b) Mineralization of the s-triazine ring of atrazine by stable bacterial mixed cultures. Appl Environ Microbiol 59:1695–1701.

    PubMed  CAS  Google Scholar 

  • Masaphy S, Levanon D, Vaya J, Henis Y (1993) Isolation and characterization of a novel atrazine metabolite produced by the fungus Pleurotus pulmonarius, 2-chloro-4-ethylamino-6-(l-hydroxyisopropyl)amino-l,3,5-trizaine. Appl Environ Microbiol 59:4342–4346.

    PubMed  CAS  Google Scholar 

  • Masse L, Prasher SO, Khan SU, Arjoon DS, Barrington S (1994) Leaching of metolachlor, atrazine, and atrazine metobolites into groundwater. Trans Am Soc Agric Eng 37:801–806.

    CAS  Google Scholar 

  • McGlamery MD, Slife FW (1966) The adsorption and desorption of atrazine as affected by pH, temperature, and concentration. Weeds 14:237–239.

    Article  CAS  Google Scholar 

  • Mervosh TL, Stoller EW, Simmons FW, Ellsworth TR, Sims GK (1995) Effects of starch encapsulation on clomazone and atrazine movement in soil and clomazone volatilization. Weed Sci 43:445–453.

    CAS  Google Scholar 

  • Milburn P, Leger DA, O’Neill H, MacQuarrie K, Richards JE (1995) Point and nonpoint-source leaching of atrazine from a corn field—effects on tile drainage water quality. Can Agric Eng 37:269–277.

    Google Scholar 

  • Mills MS, Thurman EM (1994) Preferential dealkylation reactions of s-triazine herbicides in the unsaturated zone. Environ Sci Technol 28:600–605.

    Article  PubMed  CAS  Google Scholar 

  • Mougin G, Laugero C, Asther M, Duboca J, Frasse P, Asther M (1994) Biotransformation of the herbicide atrazine by the white rot fungus Phanerochaete chryso-sporium. Appl Environ Microbiol 60:705–708.

    PubMed  CAS  Google Scholar 

  • Muir DC, Baker BE (1976) Detection of triazine herbicides and their degradation products in tile-drain water from fields under intensive corn (maize) production. J Agric Food Chem 24:122–125.

    Article  PubMed  CAS  Google Scholar 

  • Muir DCG, Baker BE (1978) The disappearance and movement of three triazine herbicides and several of their degradation products in soil under field conditions. Weed Res 18:111–120.

    Article  CAS  Google Scholar 

  • Nagy I, Compernolle F, Ghys K, Vanderleyden J, de Mot R (1995) A single cyto-chrome P-450 system is involved in degradation of the herbicides EPTC (S-ethyl dipropylthiocarbamate) and atrazine by Rhodococcus sp. strain NI86/21. Appl Environ Microbiol 61:2056–2060.

    PubMed  CAS  Google Scholar 

  • Nair DR, Schnoor JL (1994) Effect of soil conditions on model parameters and atrazine mineralization rates. Water Res 5:1199–1205.

    Article  Google Scholar 

  • Nations BK, Hallberg GR (1992) Pesticides in Iowa precipitation. J Environ Qual 21:486–492.

    Article  CAS  Google Scholar 

  • Nelson H, Jones RD (1994) Potential regulatory problems associated with atrazine, cyanazine, and alachlor in surface water source drinking water. Weed Technol 8:852–861.

    CAS  Google Scholar 

  • Pantone DJ, Young RA, Buhler DD, Eberlein CV, Koskinen WC, Forcella F (1992) Water quality impacts associated with pre-and postemergence applications of atrazine in maize. J Environ Qual 21:567–573.

    Article  CAS  Google Scholar 

  • Paterson KG, Schnoor JL (1992) Fate of alachlor and atrazine in a riparian zone field site. Water Environ Res 64:274–283.

    Article  CAS  Google Scholar 

  • Pignatello JJ, Huang LQ (1991) Sorptive reversibility of atrazine and metolachlor residues in field soil samples. J Environ Qual 20:222–228.

    Article  CAS  Google Scholar 

  • Pignatello JJ, Ferrandino FJ, Huang LQ (1993) Elution of aged and freshly added herbicides from a soil. Environ Sci Technol 27:1563–1571.

    Article  CAS  Google Scholar 

  • Pionke HB, Glotfelty DW (1990) Contamination of groundwater by atrazine and selected metabolites. Chemosphere 6:813–822.

    Article  Google Scholar 

  • Quisenberry VL, Phillips RE (1976) Percolation of surface applied water in the field. Soil Sci Soc Am J 40:484–489.

    Article  CAS  Google Scholar 

  • Radosevich MS, Traina SJ, Hao YL, Tuovinen O (1995) Degradation and mineralization of atrazine by a soil bacterial isolate. Appl Environ Microbiol 61:297–302.

    PubMed  CAS  Google Scholar 

  • Raju GS, Millette JA, Khan SU (1993) Pollution potential of selected pesticides in soils. Chemosphere 26:1429–1442.

    Article  CAS  Google Scholar 

  • Rao PSC, Davidson JM (1980) Estimation of pesticide retention and transformation parameters required in nonpoint source pollution models. In: Overcash MR, Davidson JM (eds) Environmental Impact of Nonpoint Source Pollution. Ann Arbor Science, Ann Arbor, MI, pp 23–67.

    Google Scholar 

  • Richards RD, Baker DB, Creamer NL, Kramer JW, Ewing DE, Merryfield BJ, Wallrabenstein LK (1996) Well water quality, well vulnerability, and agricultural contamination in the Midwestern United States. J Environ Qual 25:389–402.

    Article  CAS  Google Scholar 

  • Richards RP, Kramer JW, Baker DB, Krieger KA (1987) Pesticides in rainwater in the northeastern United States. Nature 327:129–131.

    Article  Google Scholar 

  • Ritter WF (1990) Pesticide contamination of groundwater in the United States—a review. J Environ Sci Health B25:l–29.

    Google Scholar 

  • Rochette EA, Koskinen WC (1996) Supercritical carbon dioxide for determining atrazine sorption by field-moist soils. Soil Sci Soc Am J 60:453–460.

    Article  CAS  Google Scholar 

  • Rouchaud J, Gustin F, Cappelen O, Mouraux ND (1994) Pig slurry and cow manure effect on atrazine and metolachlor soil biodegradation in maize. Bull Environ Contam Toxicol 52:568–573.

    Article  PubMed  CAS  Google Scholar 

  • Roy WR, Krapac IG (1994) Adsorption and desorption of atrazine and deethy-latrrazine by low organic carbon geologic materials. J Environ Qual 23:549–556.

    Article  CAS  Google Scholar 

  • Ryan GF (1970) Resistance of common groundsel to simazine and atrazine. Weed Sci 18:614–616.

    CAS  Google Scholar 

  • Sadeghi AM, Isensee AR (1992) Effect of tillage systems and rainfall patterns on atrazine distribution in soil. J Environ Qual 21:464–469.

    Article  CAS  Google Scholar 

  • Sadeghi AM, Isensee AR (1994) Spatial distribution of atrazine residues in soil and shallow groundwater: effect of tillage and rainfall timing. Agric Ecosyst Environ 48:67–76.

    Article  CAS  Google Scholar 

  • Sauer TJ, Daniel TC (1987) Effect of tillage system on runoff losses of surface-applied pesticides. Soil Sci Soc Am J 51:410–415

    Article  CAS  Google Scholar 

  • Sauer TJ, Fermanich KJ, Daniel TC (1990) Comparison of the pesticide root zone model simulated and measured pesticide mobility under two tillage systems. J Environ Qual 19:727–734.

    Article  CAS  Google Scholar 

  • Schiavon M (1988a) Studies of movement and the formation of bound residues of atrazine, of its chlorinated derivatives, and of hydroxyatrazine in soil using 14C ring-labeled compounds under outdoor conditions. Ecotoxicol Environ Saf 15:55–61.

    Article  PubMed  CAS  Google Scholar 

  • Schiavon M (1988b) Studies of the leaching of atrazine, of its chlorinated derivatives, and of hydroxyatrazine from soil using 14C ring-labeled compounds underoutdoor conditions. Ecotoxicol Environ Saf 15:46–54.

    Article  PubMed  CAS  Google Scholar 

  • Schottler SP, Eisenreich SJ, Capei PD (1994) Atrazine, alachlor, and cyanazine in a large agricultural river system. Environ Sci Technol 28:1079–1089.

    Article  PubMed  CAS  Google Scholar 

  • Seybold CA, McSweeney K, Lowery B (1994) Atrazine adsorption in sandy soils of Wisconsin. J Environ Qual 23:1291–1297.

    Article  Google Scholar 

  • Shelton, DR, Sadeghi AM, Karns JS, Hapeman CJ (1995) Effect of wetting and drying of soil on sorption and biodegradation of atrazine. Weed Sci 43:298–305.

    CAS  Google Scholar 

  • Shipitalo MJ, Edwards WM, Dick WA, Owens LB (1990) Initial storm effects on macropore transport of surface-applied chemicals in no-till soil. Soil Sci Soc Am J 54:1530–1536.

    Article  CAS  Google Scholar 

  • Sigua GC, Isensee AR, Sadeghi AM (1993) Influence of rainfall intensity and crop residue on leaching of atrazine through intact no-till soil cores. Soil Sci 156:225–232.

    Article  CAS  Google Scholar 

  • Sigua GC, Isensee AR, Sadeghi AM, Im GJ (1995) Distribution and transport of atrazine as influenced by surface cultivation, earthworm population and rainfall pattern. Chemosphere 31:4237–4242

    Article  CAS  Google Scholar 

  • Sirons GJ, Frank R, Sawyer T (1973) Residues of atrazine, cyanazine, and their phytotoxic metabolites in a clay loam. J Agric Food Chem 21:1016–1020.

    Article  PubMed  CAS  Google Scholar 

  • Skipper HD, Gilmour CM, Furtick WR (1967) Microbial versus chemical degrada tion of atrazine in soils. Soil Sci Soc Am Proc 31:653–656.

    Article  CAS  Google Scholar 

  • Skipper HD, Volk VV (1972) Biological and chemical degradation of atrazine in three Oregon soils. Weed Sci 20:344–347.

    CAS  Google Scholar 

  • Smith AE (1981) Comparison of solvent systems for the extractions of atrazine, benzoylprop, flamprop, and trifluralin from weathered field soils. J Agric Food Chem 29:111–115.

    Article  CAS  Google Scholar 

  • Smith AE, Walker A (1989) Prediction of the persistence of the triazine herbicides atrazine, cyanazine, and metribuzin in Regina heavy clay. Can J Soil Sci 69:587–595.

    Article  CAS  Google Scholar 

  • Sonon LS, Schwab AP (1995) Adsorption characteristics of atrazine and alachlor in Kansas soils. Weed Sci 43:461–466.

    CAS  Google Scholar 

  • Sorenson BA, Wyse DL, Koskinen WC, Buhler DD, Lueschen WE, Jorgenson MD (1993) Formation and movement of 14C-atrazine degradation products in a sandy loam soil under field conditions. Weed Sci 41:239–245.

    CAS  Google Scholar 

  • Sorenson BA, Koskinen WC, Buhler DD, Wyse DL, Lueschen WE, Jorgenson MD (1994) Formation and movement of 14C-atrazine degradation products in a clay loam soil in the field. Weed Sci 42:618–624.

    CAS  Google Scholar 

  • Sorenson BA, Koskinen WC, Buhler DD, Wyse DL, Lueschen WE, Jorgenson MD (1995) Fate of 14C-atrazine in a silt loam soil. Int J Environ Anal Chem 61:1–10.

    Article  CAS  Google Scholar 

  • Spalding RF, Junk GA, Richard JJ (1980) Pesticides in ground water beneath irrigated farmland in Nebraska, August 1978. Pestic Monk J 14:70–73.

    CAS  Google Scholar 

  • Spalding RF, Snow DD, Cassada DA, Burbach ME (1994) Study of pesticide occurrence in two closely spaced lakes in northeastern Nebraska. J Environ Qual 23:571–578.

    Article  CAS  Google Scholar 

  • Starr JL, Glotfelty DE (1990) Atrazine and bromide movement through a silt loam soil. J Environ Qual 19:552–558.

    Article  CAS  Google Scholar 

  • Stehouwer RC, Dick WA, Traina SJ (1993) Characteristics of earthworm burrow lining affecting atrazine sorption. J Environ Qual 22:181–185.

    Article  CAS  Google Scholar 

  • Stehouwer RC, Dick WA, Traina SJ (1994) Sorption and retention of herbicides in vertically oriented earthworm and artificial burrows. J Environ Qual 23:286–292.

    Article  CAS  Google Scholar 

  • Stolpe NB, Shea PJ (1995) Alachlor and atrazine degradation in a Nebraska soil and underlying sediment. Soil Sci 160:359–370.

    Article  CAS  Google Scholar 

  • Talbert RE, Fletchall OH (1965) The adsorption of some s-triazines in soils. Weeds 13:46–53.

    Article  CAS  Google Scholar 

  • Thomas GW, Phillips RE (1979) Consequences of water movement in macropores. J Environ Qual 8:149–152.

    Article  Google Scholar 

  • Thurman EM, Goolsby DA, Meyer MT, Kolpin DW (1991) Herbicides in surface waters of the Midwestern United States: effect of spring flush. Environ Sci Technol 25:1794–1796.

    Article  CAS  Google Scholar 

  • Thurman EM, Goolsby DA, Meyer MT, Kolpin DW (1992) A reconnaissance study of herbicides and their metabolites in surface water of the Midwestern United States using immunoassay and gas chromatography/mass spectrometry. Environ Sci Technol 26:2440–2447.

    Article  CAS  Google Scholar 

  • Tomlin C (1994) Atrazine. In: The Pesticide Manual, 10th Ed. Crop Protection Publications, Surrey, UK, pp 35–37.

    Google Scholar 

  • Topp E, Smith WN, Reynolds WD, Khan SU (1994) Atrazine and metolachlor dissipation in soils incubated in undisturbed cores, repacked cores, and flasks. J Environ Qual 23:693–700.

    Article  CAS  Google Scholar 

  • Topp E, Gutzman DW, Bourgoin B, Millette J, Gamble DS (1995) Rapid mineralization of the herbicide atrazine in alluvial sediments and enrichment cultures. Environ Toxicol Chem 14:743–747.

    Article  CAS  Google Scholar 

  • Triplett GB Jr, Conner BJ, Edwards WM (1978) Transport of atrazine and simazine in runoff from conventional and no-tillage corn. J Environ Qual 7:77–84.

    Article  CAS  Google Scholar 

  • USEPA (1995) Drinking water regulations and health advisories. U.S. Environmental Protection Agency, Office of Water, Washington, DC.

    Google Scholar 

  • Verstraeten IM, Lewis DT, McCallister DL, Parkhurst A, Thurman EM (1995) Relation of landscape position and irrigation to concentrations of alachlor, atrazine, and selected degradates in regolith in northeastern Nebraska. In: Meyer M, Thurman EM (eds) Herbicide Metabolites in Surface Water and Groundwa-ter. ACS Symp Ser 630. American Chemical Society, Washington, DC, pp 178–197.

    Google Scholar 

  • Wagenet RJ, Hutson JL (1989) LEACHM: leaching estimation model-a process-based model for water and solute movement, transformation, plant uptake and chemical reactions in the unsaturated zone. Continuum Vol. 2. Water Resources Institute, Cornell University, Ithaca, NY.

    Google Scholar 

  • Wang Z, Gamble DS, Langford CH (1990) Interaction of atrazine with Laurentian fulvic acid: binding and hydrolysis. Anal Chim Acta 232:181–188.

    Article  CAS  Google Scholar 

  • Wang Z, Gamble DS, Langford CH (1991) Interaction of atrazine with Laurentian humic acid. Anal Chim Acta 244:135–143.

    Article  CAS  Google Scholar 

  • Wang Z, Gamble DS, Langford CH (1992) Interaction of atrazine with Laurentian soil. Environ Sci Technol 26:560–565.

    Article  CAS  Google Scholar 

  • Weed DAJ, Kanwar RS, Stoltenberg DE, Pfeiffer RL (1995) Dissipation and distribution of herbicides in the soil profile. J Environ Qual 24:68–79.

    Article  CAS  Google Scholar 

  • Wehtje GR, Spalding RF, Burnside OC, Lowry SR, Leavitt JRC (1983) Biological significance and fate of atrazine under aquifer conditions. Weed Sci 31:610–618.

    CAS  Google Scholar 

  • Wehtje G, Mielke LN, Leavitt JRC, Schepers JS (1984) Leaching of atrazine in the root zone of an alluvial soil in Nebraska. J Environ Qual 13:507–513.

    Article  CAS  Google Scholar 

  • Welhouse GJ, Bleam WF (1993a) Atrazine hydrogen-bonding potentials. Environ Sci Technol 27:494–500.

    Article  CAS  Google Scholar 

  • Welhouse GJ, Bleam WF (1993b) Cooperative hydrogen bonding of atrazine. Environ Sci Technol 27:500–505.

    Article  CAS  Google Scholar 

  • Whang JM, Schomburg CJ, Glotfelty DE, Taylor AW (1993) Volatilization of fonofos, chlorpyrifos, and atrazine from conventional and no-till surface soils in the field. J Environ Qual 22:173–180.

    Article  CAS  Google Scholar 

  • Widmer SK, Olson JM, Koskinen WC (1993) Kinetics of atrazine hydrolysis in water. J Environ Sci Health B 28:19–28.

    Article  Google Scholar 

  • Widmer SK, Spalding RF (1995) A natural gradient transport study of selected herbicides. J Environ Qual 24:445–453.

    Article  CAS  Google Scholar 

  • Wienhold BJ, Sadeghi AM, Gish TJ (1993) Effect of starch encapsulation and temperature on volatilization of atrazine and alachlor. J Environ Qual 22:162–166.

    Article  CAS  Google Scholar 

  • Wienhold BJ, Gish TJ (1994) Effect of formulation and tillage practice on volatil of atrazine and alachlor. J Environ Qual 22:162–166.

    Article  Google Scholar 

  • Wietersen RC, Daniel TC, Fermanich KJ, Girard BD, McSweeney K, Lowery B (1993a) Atrazine, alachlor, and metolachlor mobility through two sandy Wisconsin soils. J Environ Qual 22:811–818.

    Article  CAS  Google Scholar 

  • Wietersen RC, Daniel TC, Fermanich KJ, Lowery B, McSweeney K (1993b) Irrigation and polymer effects on herbicide transport through the unsaturated zone of a Sparta sand. J Environ Qual 22:819–824.

    Article  CAS  Google Scholar 

  • Winkelmann, DA, Klaine SJ (1991) Degradation and bound residue formation of four atrazine metabolites, deethylatrazine, deisopropylatrazine, dealkylatrazine and hydroxyatrazine, in a western Tennessee soil. Environ Toxicol Chem 10:347–354.

    Article  CAS  Google Scholar 

  • Wolf DC, Martin JP (1975) Microbial decomposition of ring 14C atrazine, cyanuric acid and 2-chloro-4,6-diamino-,s-triazine. J Environ Qual 4:134–139.

    Article  CAS  Google Scholar 

  • Wolf SA, Nowak PJ (1996) A regulatory approach to atrazine mangement: evaluation of Wisconsin groundwater protection strategy. J Soil Water Conserv 51:94–100.

    Google Scholar 

  • Workman SR, Ward AD, Fausey NR, Nokes SE (1995) Atrazine and alachlor dissipation rates from field experiments. Trans Am Soc Agric Eng 38:1421–1425.

    CAS  Google Scholar 

  • Wu TL (1980) Dissipation of the herbicides atrazine and alachlor in a Maryland corn field. J Environ Qual 9:459–465.

    Article  CAS  Google Scholar 

  • Wu TL, Corell DL, Remenapp HEH (1983) Herbicide runoff from experimental watersheds. J Environ Qual 12:330–336.

    Article  CAS  Google Scholar 

  • Zins AB, Wyse DL, Koskinen WC (1991) Effect of alfalfa roots on movements of atrazine and alachlor through soil. Weed Sci 39:262–269.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1997 Springer Science+Business Media New York

About this chapter

Cite this chapter

Koskinen, W.C., Clay, S.A. (1997). Factors Affecting Atrazine Fate in North Central U.S. Soils. In: Ware, G.W. (eds) Reviews of Environmental Contamination and Toxicology. Reviews of Environmental Contamination and Toxicology, vol 151. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-1958-3_4

Download citation

  • DOI: https://doi.org/10.1007/978-1-4612-1958-3_4

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4612-7355-4

  • Online ISBN: 978-1-4612-1958-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics