Abstract
The use of lipases as biocatalysts in interesterification reactions has been the object of growing interest, owing to the importance of esters as emulsifiers, intermediates to produce oleochemicals, and fuel alternatives. We consider in this article a kinetic study of lipase-catalyzed alcoholysis of palm kernel oil, using n-hexane as the solvent. In a first step the ester production was maximized by using a Taguchi design, and then an empirical model was built to determine the influence of the process variables. Taking into account the results obtained in the first step, we performed a kinetic study and developed a simple model for this system.
Author to whom all correspondence and reprint requests should be addressed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
Mukherjee, K. D. (1990), Biocatalysis 3, 277–281.
Goh, S. H., Yeong, S. K., and Wang, C. W. (1993), J. Am. Oil Chem. Soc. 70, 567–572.
Qinlan, P. and Moore, S. (1993), Inform 4, 580–582.
Chulalaksananukul, W., Condoret, J. S., and Combes D. (1992), Ibid. 14, 293–296.
Santaniello, E., Ferraboschi, E. P., and Grisenti, P. (1993), Enzyme Microb. 15, 367–369.
Kurashige, J., Matsuzaki, N., and Takahashi, H. (1993) J. Am. Oil Chem. Soc. 70, 849–855.
Peterson, C. L. (1986), Trans. ASAE 29, 1413–1418.
Mittelbach, M. (1990), J. Am. Oil Chemists Soc. 67, 3–7.
Oliveira, D. and Alves, T. L. M. (1999), Appl. Biochem. Biotechnol. 77-79, 835–842.
Stahl, E. (1969), in Thin-Layer Chromatography, Springer Verlag, New York.
Coks, L. V. and van Rede, C. (1966), in Laboratory Handbook for Oils and Fats Analysis, 1st ed., Academic, London.
Monaco, L. C. (1985), Produção de Combustíveis Líquidos a partir de Óleos Vegetais, MIC/STI, 277, Brasília (in Portuguese).
Yamane, T. (1988), Biocatalysis 2, 1–9.
Himmelblau, D. M. (1970), in Process Analysis by Statistical Methods, John Wiley & Sons, New York.
Pinto, J. C., Noronha, F. B., Monteiro, J. L., Lobão, M. W., and Santos, T. J. (1987), ESTIMA: Um Pacote Computacional para Estimação de Parâmetros e Projeto de Experimentos, PEQ/COPPE/UFRJ (in Portuguese).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2000 Springer Science+Business Media New York
About this chapter
Cite this chapter
de Oliveira, D., Alves, T.L.M. (2000). A Kinetic Study of Lipase-Catalyzed Alcoholysis of Palm Kernel Oil. In: Finkelstein, M., Davison, B.H. (eds) Twenty-First Symposium on Biotechnology for Fuels and Chemicals. Applied Biochemistry and Biotechnology. Humana Press, Totowa, NJ. https://doi.org/10.1007/978-1-4612-1392-5_4
Download citation
DOI: https://doi.org/10.1007/978-1-4612-1392-5_4
Publisher Name: Humana Press, Totowa, NJ
Print ISBN: 978-1-4612-7128-4
Online ISBN: 978-1-4612-1392-5
eBook Packages: Springer Book Archive