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Comparison of Thermodynamic Data Obtained by Knudsen Vaporization Magnetic and Quadrupole Mass Spectrometric Techniques

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Materials Chemistry at High Temperatures

Part of the book series: Materials Chemistry at High Temperatures ((MCHT,volume 1))

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Abstract

The vaporization behavior of chromium silicides has been investigated by high temperature Knudsen effusion mass spectrometry in two laboratories, one employing a high resolution magnetic sector instrument, and the other a quadrupole instrument for mass analysis. The instrumentation differed also in cell design, furnace construction, temperature measurement and calibration, and experimental procedures. Chromium partial vapor pressures were based on calibrations with the pure element. The agreement of results from the two laboratories was found to be very good.

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© 1990 Springer Science+Business Media New York

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Murray, G.A., Kematick, R.J., Myers, C.E., Frisch, m.A. (1990). Comparison of Thermodynamic Data Obtained by Knudsen Vaporization Magnetic and Quadrupole Mass Spectrometric Techniques. In: Hastie, J.W. (eds) Materials Chemistry at High Temperatures. Materials Chemistry at High Temperatures, vol 1. Humana Press, Totowa, NJ. https://doi.org/10.1007/978-1-4612-0481-7_31

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  • DOI: https://doi.org/10.1007/978-1-4612-0481-7_31

  • Publisher Name: Humana Press, Totowa, NJ

  • Print ISBN: 978-1-4612-6781-2

  • Online ISBN: 978-1-4612-0481-7

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