Skip to main content

The Binary Cycles

  • Chapter
  • First Online:

Part of the book series: Lecture Notes in Energy ((LNEN,volume 11))

Abstract

Today, the term “binary cycle” commonly refers to the organic fluid Rankine engines in geothermal systems, where a mass flow of geothermal brine is cooled in a recovery heat exchanger and the heat recovered is converted into electricity by means of an organic fluid engine (see Chap. 3, Sect. 3.6, and DiPippo [1]).

In general, though, the term “binary cycle” can cover any thermodynamic conversion system of heat into electricity with two different fluids involved in the process.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Notes

  1. 1.

    A good indicator of the thermodynamic quality of a cycle is the second-law efficiency, discussed in Exercise 1.2; see (1.22).

  2. 2.

    The mercury vapours are extremely toxic, and the mercury does not wet the metal surfaces, creating major problems of heat exchange. The first mercury boilers were subject to tube plugging and failures, with massive corrosion of the tubes, made in low carbon steel, [2]. Water and air infiltration into the mercury circuits created further problems.

  3. 3.

    A heterocyclic organic compound, also called dibenzofuran, \(\mathrm{C_{12}H_{8}O}\). With T cr = 550.85  ∘  C, P cr = 36.34  bar. With boiling temperature of 285.16  ∘  C and a melting point at 81–85  ∘  C.

  4. 4.

    The power \(\dot{W}\) of the last stage of a turbine is, approximately, if calculating on a preset number of Mach, like \(\dot{W} =\dot{ m}\Delta H \propto \rho {D}^{2}v_{s}v_{s}^{2} \propto \left (P/T\right )\mathrm{M}{D}^{2}v_{s}^{3} \propto {D}^{2}\left (P/T\right )\mathrm{M}{\left (T/\mathrm{M}\right )}^{3/2}\), with D average diameter, ρ density of vapour, v s speed of sound, \(\Delta H\) enthalpy drop and M molecular weight. For the same average diameter and the same condensation temperature, the power is, therefore, approximately proportional to the ratio \(P/\sqrt{\mathrm{M}}\). For example, assuming T = 500  ∘  C, the power of the stage with rubidium would be approximately 1.7–1.8 times greater than that of the stage with potassium.

  5. 5.

    In the case of steam turbines, stages have been designed with a tip diameter of 4.32  m at 3,000 rpm and stages with a tip diameter of 6.7  m at 1,500 rpm with h ∕ D ratios, height of blade with respect to average diameter, of 0.39 and 0.37, respectively.

References

  1. DiPippo R (2008) Geothermal power plants: principles, applications, case Studies, and environmental impact, 2nd edn. Butterworth-Heinemann, Oxford UK

    Google Scholar 

  2. Gutstein M, Furman ER, Kaplan GM (1975) Liquid-metal binary cycles for stationary power. NASA Technical Note, NASA TN D-7955

    Google Scholar 

  3. Gaffert GA (1952) Steam power stations, 4th edn. McGraw-Hill and Kōgakusha Company, New York and Tokyo

    Google Scholar 

  4. Fraas AP (October 1966) A potassium-steam binary vapor cycle for a molten-salt reactor power plant. J Eng Power Trans ASME, 355–366

    Google Scholar 

  5. Goldstein S, Vrillon B (1982) Confirmation of the advantages of a thermodynamic cycle using sulfur with the help of an experimental facility. In: Energy conservation in industry: combustion, heat recovery, and Rankine cycle machines. Proceedings of the contractors’ meetings, Brussels. D.Reidel Publishing Company, Dordrecht, pp. 213–222

    Google Scholar 

  6. Fraas AP (1973) A potassium-steam binary vapor cycle for better fuel economy and reduced thermal pollution. J Eng Power Trans ASME 95(1):53–63

    Article  Google Scholar 

  7. Dow HH (1926) Diphenyl oxide bi-fluid power plants. J Am Soc Nav Eng 38(4):940–950

    Article  Google Scholar 

  8. Killeffer DH (1935) Stable organic compounds in power generation. Diphenyl-Diphenyl oxide mixtures in an efficient boiler plant of unique design. Ind Eng Chem 27(1):10–15

    Google Scholar 

  9. d’Amelio L (1936) The steam turbine and the binary cycles with fluids other than water between the lower isotherms. L’elettrotecnica 23(9):250–257 (in Italian)

    Google Scholar 

  10. Fleury J, Bellot Ch (1984) Ammonia bottoming cycle development at Electricité de France for nuclear power plants. In: ORC-HP-Technology. Working Fluid Problems. Proceedings of the International VDI-Seminar, Zürich. VDI-Verlag GmbH, Düsseldorf, pp. 221–241

    Google Scholar 

  11. Angelino G, Invernizzi C, Molteni G (1999) The potential role of organic bottoming Rankine cycles in steam power stations. Proc IME J Power Energ 213:75–81

    Article  Google Scholar 

  12. Angelino G, Invernizzi C (2006) Binary and ternary liquid metal-steam cycles for high-efficiency coal power stations. Proc IME J Power Energ 220:195–205

    Article  Google Scholar 

  13. Fraas AP, Brooks RD (1974) Topping and bottoming cycles. Paper prepared for presentation at the 9th World Energy Conference, Detroit, Michigan, 22–27 September

    Google Scholar 

  14. Fraas AP (1976) Application of the fluidized bed coal combustion system to the production of electric power and process heat. Paper prepared for presentation at the American Institute of Chemical Engineers. Kansas City, Missouri, 11–14 April

    Google Scholar 

  15. Angelino G, Invernizzi C (2008) Binary conversion cycles for concentrating solar power technology. Sol Energ 82:637–647

    Article  Google Scholar 

  16. Manson SV (1968) A review of the alkali metal Rankine technology program. J Spacecraft Rockets 5(11):1249–1259

    Article  Google Scholar 

  17. Fraas AP, Burton DW, LaVerne ME, Wilson LV (1969) Design comparison of cesium and potassium vapor turbine-generator units for space power plants. Oak Ridge National Laboratory, Oak Ridge, Tennessee. ORNL-TM-2024

    Google Scholar 

  18. Fraas AP (1975) A cesium vapor cycle for an advanced LMFBR. Paper submitted for presentation at the ASME Winter Annual Meeting. Houston, Texas, 30 November–5 December

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2013 Springer-Verlag London

About this chapter

Cite this chapter

Invernizzi, C.M. (2013). The Binary Cycles. In: Closed Power Cycles. Lecture Notes in Energy, vol 11. Springer, London. https://doi.org/10.1007/978-1-4471-5140-1_5

Download citation

  • DOI: https://doi.org/10.1007/978-1-4471-5140-1_5

  • Published:

  • Publisher Name: Springer, London

  • Print ISBN: 978-1-4471-5139-5

  • Online ISBN: 978-1-4471-5140-1

  • eBook Packages: EnergyEnergy (R0)

Publish with us

Policies and ethics