Abstract
Biogas produced by the anaerobic digestion of biomass can be exploited directly as a fuel for small-to-medium-scale combined heat and power production, or as a renewable carbon source for the production of synthesis gas and/or hydrogen for industrial syntheses or energetic purposes. Since biogas contains CH4 and CO2 as two main components, it could be processed to a syngas according to a well-reported technological process called CO2 reforming of methane (dry reforming). We highlight the dry reforming of biogas as one area of activity where catalysts are already a significant focus of worldwide research efforts. Nickel catalysts are highly active for reforming reactions, and their cost is much lower compared with noble metals, which makes them suitable for a cost-effective commercial reforming process. For this reason, Ni-based catalysts are extensively studied, with emphasis on the effect of catalyst composition, preparation method, and pre-treatment. Unfortunately, nickel is more prone to carbon deposition. Improvement in the performance of Ni-based catalysts by incorporation of a second metal to catalyst composition and use of different Ni catalyst precursors is discussed in some detail. The challenges for catalysts applied to the dry reforming of biogas (activity, sulfur poisoning, carbon formation, and sintering) are also examined in order to reveal the specific needs and responses for the reforming process. A brief account of strategies and approaches adopted in the search for catalysts that respond to the above challenges is given here.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
Z. Jiang, T. Xiao, V.L. Kuznetsov, P.P. Edwards, Phil. Trans. R. Soc. A 368, 3343 (2010)
H. Arakawa, M. Aresta, J.N. Armor, M.A. Barteau, E.J. Beckman, A.T. Bell, J.E. Bercaw, C. Creutz, E. Dinjus, D.A. Dixon, K. Domen, D.L. DuBois, J. Eckert, E. Fujita, D.H. Gibson, W.A. Goddard, D.W. Goodman, J. Keller, G.J. Kubas, H.H. Kung, J.E. Lyons, L.E. Manzer, T.J. Marks, K. Morokuma, K.M. Nicholas, R. Periana, L. Que, J. Rostrup-Nielson, W.M. Sachtler, L.D. Schmidt, A. Sen, G.A. Somorjai, P.C. Stair, B.R. Stults, W. Tumas, Chem. Rev. 101(4), 953 (2001)
G.A. Olah, Angew. Chem.-Int. Ed. 44, 2636 (2005)
G. Centi, S. Perathoner, Catal. Today 148, 191 (2009)
R.J. Pearson, J.W.G. Turner, A.J. Peck, In Low Carbon Vehicles 2009 (Institution of Mechanical Engineers, London, May, 2009)
G. Centi, S. Perathoner, Stud. Surf. Sci. Catal. 153, 1 (2004)
M. Aresta, A. Dibenedetto, Dalton Trans. 28, 2975 (2007)
T. Sakakura, J.-C. Choi, H. Yasuda, Chem. Rev. 107(6), 2365 (2007)
C. Song, A.M. Gaffney, K. Fujimoto (eds.), CO 2 Conversion and Utilization (ACS Symposium Series) (American Chemical Society, Washington, DC, 2002)
Catal. Omae, Today 115(1–4), 33 (2006)
G. Centi, R.A. van Santen (eds.), Catalysis for Renewables (Wiley VCH Pub, Weinheim, Germany, 2007)
F. Cavani, G. Centi, S. Perathoner, F. Trifiro, Sustainable Industrial Chemistry Principles, in: Tools and Industrial Examples (Wiley VCH, Weinheim, Germany, 2009)
A.T Bell, B.C. Gates, D. Ray, Basic Research Needs: Catalysis for Energy (PNNL-17214), U.S. Department of Energy, Report from a Workshop held in August 6–8, 2007, Bethesda, Maryland, USA
N. Mota, C. Alvarez-Galvan, R.M. Navarro, J.L.G. Fierro, Biofuels 2(3), 325 (2011)
M. Mikkelsen, M. Jorgensen, F.C. Krebs, Energy Environ. Sci. 3, 43 (2010)
G.A. Olah, A. Goeppert, G.K.S. Prakash, J. Org. Chem. 74, 487 (2009)
J.R. Rostrup-Nielsen, In Catalysis Science and Technology, ed. by J.R. Anderson, M. Boudart (Springer, Berlin, 1984), Chap. 1
J.R. Rostrup-Nielsen, J.S. Sehested, J.K. Nørskov, Adv. Catal. 47, 65 (2002)
R.M. Navarro, M.A. Peña, J.L.G. Fierro, Chem. Rev. 107(10), 3952 (2007)
J.R.H. Ross, Catal. Today 100, 151 (2005)
M.S. Fan, A.Z. Abdullah, S. Bhatia, Chem. Cat. Chem. 1, 192 (2009)
M. Ojeda, T. Herranz, F.J. Perez, J.M. Gonzalez-Carballo, S. Rojas, J.L.G. Fierro, in Syngas: Production Methods, Post Treatment and Economics, ed. by A. Kurucz, I. Bencik (Nova Science Publishers, NY, USA, 2009)
M.C.J. Bradford, M.A. Vannice, Appl. Catal. A: Gen. 142, 73 (1996)
G.S. Gallego, C. Batiot-Dupeyrat, J. Barrault, E. Florez, F. Mondragón Appl, Catal. A: Gen. 334, 251 (2008)
U. Olsbye, T. Wurzel, L. Mleczko, Ind. Eng. Chem. Res. 36, 5180 (1997)
J.T. Richardson, S.A. Paripatyadar, Appl. Catal. 61, 293 (1990)
J. Zhang, H. Wang, A.K. Dalai, J. Catal. 249, 300 (2007)
G.C.D. Araujo, S.M. de Lima, J.M. Assaf, M.A. Pena, J.L.G. Fierro, M.C. Rangel, Catal. Today 133–135, 129 (2008)
R. Pereñíguez, V.M. González de la Cruz, J.P. Holgado, A. Caballero A., Appl. Catal. B Environ. 93, 346
G. Valderrama, A. Kiennemann, M.R. Goldwasser, J. Power Sources 195, 1765 (2010)
A.J. Brungs, A.P.E. York, J.B. Claridge, C. Marquez, M.L.H. Green, Catal. Lett. 70, 117 (2000)
A.T. Ashcroft, A.K. Cheetham, M.L.H. Green, P.D.F. Vernon, Nature 352, 225 (1991)
J. Guo, H. Lou, H. Zhao, D. Chai, X. Zheng, Appl. Catal. A: Gen. 273, 75 (2004)
J.M. Ginsburg, J. Pina, T. El Solh, H.I. de Lasa, Ind. Eng. Chem. Res. 44, 4846 (2005)
V.A. Tsipouriari, A.M. Efstathiou, X.E. Verykios, J. Catal. 161, 31 (1996)
J. Guo, H. Lou, X. Zheng, Carbon 45, 1314 (2007)
A.P.E. York, T. Xiao, M.L.H. Green, J.B. Claridge, Catal. Rev.-Sci. Eng. 49, 511 (2007)
E. Yamaguchi, J. Iglesia, Catal. 274, 52 (2010)
B.C. Enger, R. Lodeng, A. Holmen, Appl. Catal. A: Gen. 346, 1 (2008)
D.J. Trevor, D.M. Cox, A. Kaldor, J. Am. Chem. Soc. 112, 3742 (1990)
H.S. Bengaard, J.K. Nørskov, J. Sehested, B.S. Clausen, L.P. Nielsen, A.M. Molenbroek, J.R. Rostrup-Nielsen, J. Catal. 209, 365 (2002)
F. Abild-Pedersen, O. Lytken, J. Engbaek, G. Nielsen, I. Chorkendorff, J.K. Norskov, Surf. Sci. 590, 127 (2005)
M.C.J. Bradford, M.A. Vannice, Catal. Rev.-Sci. Eng. 41, 1 (1999)
T. Osaki, H. Masuda, T. Horiuchi, T. Mori, Catal. Lett. 34, 59 (1995)
V.A. Tsipouriari, X.E. Verykios, Catal. Today 64, 83 (2001)
H.J. Freund, R.P. Messmer, Surf. Sci. 172, 1 (1986)
J. Erdohelyi, E. Cserenyi, P.F. Solymosi, Appl. Catal. A: Gen. 108, 205 (1994)
S. Ozkara-Aydinoglu, E. Ozensoy, A.E. Aksoylu, Int. J. Hydrogen Energy 34, 9711 (2009)
C. de Leitenburg, A. Trovarelli, J.A. Kaspar, J. Catal. 166, 98 (1997)
Z.X. Cheng, X.G. Zhao, J.L. Li, Q.M. Zhu, Appl. Catal. A: Gen. 205, 31 (2001)
M.E. Dry, Catal. Today 6, 183 (1990)
A.M. O’Connor, F.C. Meunier, J.R.H. Ross, Stud. Surf. Sci. Catal. 119, 819 (1998)
M.A. Pena, J.P. Gomez, J.L.G. Fierro, Appl. Catal. A: Gen. 144, 7 (1996)
H.Y. Wang, E. Ruckenstein, Appl. Catal. A: Gen. 204, 143 (2000)
X.E. Verykios, Appl. Catal. A: Gen. 255, 101 (2003)
M.C.J. Bradford, M.A. Vannice, Appl. Catal. A: Gen. 142, 73 (1996)
J.R. Rostrup-Nielsen, J.H.B. Hansen, J. Catal. 144, 38 (1993)
M. Maestri, D.G. Vlachos, A. Beretta, G. Groppi, E. Tronconi, J. Catal. 259, 222 (2008)
J.F. Munera, S. Irusta, L.M. Cornaglia, E.A. Lombardo, D.S. Cesar, M. Schmal, J. Catal. 245, 25 (2007)
X.E. Verykios, Int. J. Hydrogen Energy 2003, 28 (1045)
J. Wei, E. Iglesia, J. Catal. 224, 370 (2004)
Z.X. Cheng, X.G. Zhao, J.L. Li, Q.M. Zhu, Appl. Catal. A Gen. 205, 31 (2001)
N. Sahli, C. Petit, A.C. Roger, A. Kiennemann, S. Libs, N. Bettahar, Catal. Today 113, 187 (2006)
A.P.E. York, T. Xiao, M.L.H. Green, J.B. Claridge, Catal. Rev.-Sci. Eng. 49, 511 (2007)
J. Guo, Z. Hou, J. Gao, X. Zheng, Fuel 87, 1348 (2008)
X.Y. Quek, D. Liu, W.N. Evelyn Cheo, H. Wang, Y. Chen, Y. Yang, Appl. Catal. B: Environ. 95, 374 (2010)
H. Kambolis, A. Matralis, C. Trovarelli, C.H. Papadopoulou, Appl. Catal. A: Gen. 377, 16 (2010)
J.L.G. Fierro, J. Soria, J. Sanz, J.M. Rojo, J. Solid State Chem. 66, 154 (1987)
A. Trovarelli, Catal. Rev.-Sci. Eng. 38, 439 (1996)
S. Damyanova, B. Pawelec, K. Arishtirova, M.V. Martinez-Huerta, J.L.G. Fierro, Appl. Catal. B: Environ. 89, 149 (2009)
J. Chen, Q. Wu, J. Zhang, J. Zhang, Fuel 87, 2901 (2008)
X.E. Verykios, Int. J. Hydrogen Energy 2003, 28 (1045)
E.S. Putna, B. Shereck, R.J. Gorte, Appl. Catal. B Environ. 17, 101 (1998)
K. Sutthiumporn, S. Kawi, Int. J. Hydrogen Energy 36, 14435 (2011)
T. Inui, K. Saigo, Y. Fujii, K. Fujioka, Catal. Today 26, 295 (1995)
K. Nagaoka, A. Jentys, J.A. Lercher, J. Catal. 229, 185 (2005)
S. Damyanova, B. Pawelec, K. Arishtirova, J.L.G. Fierro, C. Sener, T. Dogu, Appl. Catal. B: Environ. 92, 250 (2009)
J. Zhang, H. Wang, A.K. Dalai, J. Catal. 249, 300 (2007)
D. San Jose, J. Juan J, M.J. Illan, M.C. Roman-Martinez, Appl. Catal. A: Gen. 371, 54 (2009)
J. Zhang, H. Wang, A.K. Dalai, Appl. Catal. A: Gen. 339, 121 (2008)
S.M. Stagg, D.E. Resasco, Stud. Surf. Sci. Catal. 111, 543 (1997)
G. Valderrama, M.R. Goldwasser, C.U. Navarro, J.M. Tatibouet, J. Barrault, C. Batiot-Dupeyrat, F. Martinez, Catal. Today 107–108, 785 (2005)
G. Aldashukurova, A. Mironenko, Z. Mansurov, N. Shikina, S. Yashnik, Z Ismagilov. In ed. by J.J. Klemes; P.S. Varbanov; H.L. Lam, Chem. Eng. Trans. 25, 63 (2011)
V.M. Gonzalez de la Cruz, R. Pereniguez, F. Ternero, J.P. Holgado, A. Caballero, J. Phys. Chem. C 116, 2919 (2012)
A.J. Zhang, A.M. Zhu, B.B. Chen, S.H. Zhang, C.T. Au, C.A. Shi, Catal. Commun. 12, 803 (2011)
M.A. Pena, J.L.G. Fierro, Chem. Rev. 2001, 101 (1981)
R. Pereniguez, V.M. Gonzalez de la Cruz, H.P. Holgado, A. Caballero, Appl. Catal. B: Environ. 93, 346 (2010)
G.S. Gallego, J.G. Marın, C. Batiot-Dupeyrat, J. Barrault, F. Mondragón, Appl. Catal. A: Gen. 369, 97 (2008)
S.M. Lima, J.M. Assaf, M.A. Pena, J.L.G. Fierro, Appl. Catal. A Gen. 311, 94 (2006)
G. Valderrama, A. Kiennemann, M.R. Goldwasser, J. Power Sources 195, 1765 (2010)
S.M. de Lima, M.A. Pena, J.L.G. Fierro, J.M. Assaf, Catal. Lett. 124, 195 (2008)
J. Rynkovski, P. Samulkiewicz, A.K. Ladavos, P.J. Pomonis, Appl. Catal. A: Gen. 263, 1 (2004)
M.E. Rivas, J. Alvarez, E. Pietri, M.J. Pérez-Zurita, M.R. Goldwasser, Catal. Today, 149, 388
S. Gaur, D.J. Haynes, J.J. Spivey, Appl. Catal. A. Gen. 403, 142 (2011)
S. Gaur, D. Pakhare, H.Y. Wu, D.J. Haynes, J.J. Spivey, Energy Fuels 2012, 26 (1989)
N. Abatzoglou, S. Boivin, Biofuels Bioprod. Bioref. 3, 42 (2009)
R. Kothari, V.V. Tyagi, A. Pathak, Renew. Sust. Energy Rev. 14, 3164 (2010)
E. Martinot, C. Dienst, L. Weiliang, C. Qimin, Ann. Rev. Environ. Resour. 32, 205 (2007)
W. Rulkens, Energy Fuels 22, 9 (2008)
M. Harasimowicz, P. Orluk, G. Zakrzewska-Trznadel, A.G. Chmielewski, J. Hazard. Mater. 144, 698 (2007)
M. Haberbauer, in Biofuels for Fuel Cells, ed. by P. Lens, P. Westermann, M. Haberbauer, A. Moreno (IWA Publishing, London, UK, 2005)
Acknowledgments
This research was supported by the Ministry of Science and Innovation (Spain) and the Autonomous Government of Madrid, Madrid, Spain, under grants ENE2010-21198-C04-01 and S2009ENE-1743, respectively.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2013 Springer-Verlag London
About this paper
Cite this paper
Navarro, R., Pawelec, B., Alvarez-Galván, M.C., Guil-Lopez, R., Al-Sayari, S., Fierro, J.L.G. (2013). Renewable Syngas Production via Dry Reforming of Methane. In: Falco, M., Iaquaniello, G., Centi, G. (eds) CO2: A Valuable Source of Carbon. Green Energy and Technology. Springer, London. https://doi.org/10.1007/978-1-4471-5119-7_3
Download citation
DOI: https://doi.org/10.1007/978-1-4471-5119-7_3
Published:
Publisher Name: Springer, London
Print ISBN: 978-1-4471-5118-0
Online ISBN: 978-1-4471-5119-7
eBook Packages: EnergyEnergy (R0)