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Theoretical Study of Oxygen Reduction Reaction Catalysts: From Pt to Non-precious Metal Catalysts

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Electrocatalysis in Fuel Cells

Part of the book series: Lecture Notes in Energy ((LNEN,volume 9))

Abstract

Fuel cells are regarded as one of the most promising candidates for stationary and mobile power generation due to their high energy yield and low environmental impact of hydrogen oxidation. The oxygen reduction reaction (ORR) at cathode is a very complex process and plays a crucial role during operation of the PEM fuel cells. However, its mechanism and the nature of intermediates involved remain vague. This chapter focuses on the recent theoretical modeling studies of ORR catalysts for PEMFC. Recent theoretical investigations on oxygen reduction electrocatalysts, such as Pt-based catalysts, non-Pt metal catalysts (Pd, Ir, CuCl), and non-precious metal catalysts (transitional metal macrocyclic complexes, conductive polymer materials, and carbon-based materials), are reviewed. The oxygen reduction mechanisms catalyzed by these catalysts are discussed based on the results.

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Authors and Affiliations

  1. College of Environmental and Energy Engineering, Beijing University of Technology, Xidawang Road, Chaoyang District, Beijing, 100124, P. R. China

    Xin Chen

  2. College of Engineering, Peking University, No.5 Yiheyuan Road, Haidian District, Beijing, 100871, P. R. China

    Dingguo Xia

  3. NRC-Institute for Fuel Cell Innovation, 4250 Wesbrook Mall, Vancouver, British Columbia, Canada

    Zheng Shi

  4. NRC Energy, Mining & Environment Portfolio, National Research Council Canada, 4250 Wesbrook Mall, Vancouver, BC, Canada, V6T 1W5

    Jiujun Zhang

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  1. Xin Chen
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    Minhua Shao

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Chen, X., Xia, D., Shi, Z., Zhang, J. (2013). Theoretical Study of Oxygen Reduction Reaction Catalysts: From Pt to Non-precious Metal Catalysts. In: Shao, M. (eds) Electrocatalysis in Fuel Cells. Lecture Notes in Energy, vol 9. Springer, London. https://doi.org/10.1007/978-1-4471-4911-8_11

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