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Nanoparticles Dispersion and the Effect of Related Parameters in the EPD Kinetics

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Electrophoretic Deposition of Nanomaterials

Part of the book series: Nanostructure Science and Technology ((NST))

Abstract

In this chapter, the stabilization of nanoparticles in liquid media is studied on the basis of the colloid science foundations. The most common dispersing mechanisms, i.e. electrostatic and steric, are reviewed. After the stabilization of the particles, an additional step is the deposition process, whose kinetics depends on a number of parameters related to both the suspension and the applied conditions. This chapter reviews the quantitative models existing in the literature to explain and predict the deposit formation kinetics.

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Abbreviations

a:

Particle radius

A:

Hamaker constant

B:

London constant

Cd :

Deposit concentration

Cs :

Solid content of the suspension

Cs,0 :

Initial solid content of the suspension

D:

Particle diameter

E:

Electric field

Eef :

Effective electric field

f:

Efficiency factor or sticking parameter

I:

Electric Current

I+ :

Electric current transported by the cations

I− :

Electric current transported by the anions

Ip :

Electric current transported by the particles

i0 :

Initial current density

i:

Current density

K:

Kinetics parameter

L:

Electrode distance

m:

Deposited mass

m0 :

Initial mass of powder in suspension

R:

Roughness

S:

Deposition surface area

SWE :

Conduction surface area

t:

Deposition time

V:

Volume of the suspension

Vd :

Volume of the deposit

1/κ :

Debye length

ε d :

Dielectric constants of the deposit

ε s :

Dielectric constants of the suspension

ε r,l :

Dielectric constant of the solvent

ε r,p :

Dielectric constant of the particles

ε 0 :

Vacuum dielectric constant

φ d :

Volumetric fraction of the deposit

φ s :

Volumetric fraction of the suspension

φ s, 0 :

Initial volumetric fraction of the suspension

η :

Solvent viscosity

µ :

Electrophoretic mobility

v:

Electrophoresis rate

ρ s :

Resistivity of the suspension

ρ s, ∞ :

Resistivity of the suspension at infinite time

ρ d :

Resistivity of the deposit

ρ + :

Resistivity associated to the cations

ρ − :

Resistivity associated to the anions

ρ p :

Resistivity associated to the particles

ρ s,0 :

Initial resistivity of the suspension

Δ :

Deposit thickness

σ s :

Conductivity of the suspension

ρ s, ∞ :

Conductivity of the liquid medium

τ :

Characteristic deposition time

τ 0 :

Characteristic deposition time for initial conditions

τ ∞ :

The characteristic deposition time for final conditions

∆ψ :

Potential drop and surface potential

∆ψ a :

Potential drop at the anode

∆ψ c :

Potential drop at the cathode

ζ :

Zeta potential

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  1. Instituto de Cerámica y Vidrio, CSIC, Kelsen 5, 28049, Madrid, Spain

    Rodrigo Moreno & Begoña Ferrari

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  1. Rodrigo Moreno
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  2. Begoña Ferrari
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Correspondence to Rodrigo Moreno .

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  1. Dept. Physics & Astronomy, Vanderbilt University Dept. Physics & Astronomy, Nashville, Tennessee, USA

    James H. Dickerson

  2. Department of Materials Science and Engi, University of Erlangen-Nuremberg, Erlangen, Germany

    Aldo R. Boccaccini

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Moreno, R., Ferrari, B. (2012). Nanoparticles Dispersion and the Effect of Related Parameters in the EPD Kinetics. In: Dickerson, J., Boccaccini, A. (eds) Electrophoretic Deposition of Nanomaterials. Nanostructure Science and Technology. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-9730-2_2

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