Skip to main content

Kinetics and Mechanisms of Metalloporphyrin Reactions

  • Chapter
Chemical Kinetics and Inorganic Reaction Mechanisms
  • 1478 Accesses

Abstract

Coordination chemistry of metalloporphyrins is a very large research field. The porphyrin macrocyclic ligand forms complexes with all transition metals, with many main group metals and many lanthanides. Metalloporphyrins easily bind various ligands in the axial positions above and below the porphyrin plane. The number of publications in the field amounts to several thousands a year. Fortunately, several review articles and monographs help manage this enormous research area.1–13

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. W. Kaim and B. Schwederski, Bioinorganic Chemistry: Inorganic Elements in the Chemistry of Life, Wiley, New York 1991, pp. 24, 66, 88-100, 117, 335.

    Google Scholar 

  2. D. Dolphin, Ed., The Porphyrins, Vol. I-VII, Academic Press, New York 1979.

    Google Scholar 

  3. J. O. Edwards, Inorganic Reaction Mechanisms, W. A. Benjamin, New York 1964, p. 53ff.

    Google Scholar 

  4. P. Hambright, in: K. M. Smith, Ed., Porphyrins and Metalloporphyrins, Elsevier, Amsterdam 1975, pp. 233–278.

    Google Scholar 

  5. D. K. Lavalle, Coord. Chem. Rev. 1985, 61, 55–96.

    Article  Google Scholar 

  6. M. Tsutsui and B. A. Taylor, in: K. Smith, Ed., Porphyrins and Metalloporphyrins, Elsevier, New York 1975, pp. 279–316.

    Google Scholar 

  7. K. Kasuga and M. Tsutsui, Coord. Chem. Rev. 1980, 32, 67–95.

    Article  CAS  Google Scholar 

  8. A. B. P. Lever and D. B. Gray, Iron Porphyrins, Parts 1 and 2, Addison-Wesley, Reading, MA 1983.

    Google Scholar 

  9. P. D. Smith, B. R. James, and D. H. Dolphin, Coord. Chem. Rev. 1981, 39, 31–75.

    Article  CAS  Google Scholar 

  10. E. Antonini and M. Brunori, Hemoglobins and Myoglobins in their Reactions with Ligands, North-Holland, Amsterdam 1971.

    Google Scholar 

  11. J. E. Falk, Porphyrins and Metalloporphyrins, Elsevier, Amsterdam 1971.

    Google Scholar 

  12. T. D. Smith, Cord. Chem. Rev. 1981, 39, 295–383.

    Google Scholar 

  13. R. Guilard and C. Lecomte, Cord. Chem. Rev. 1985, 65, 87–113.

    Article  CAS  Google Scholar 

  14. E. B. Fleischer and J. H. Wang. J. Am. Chem. Soc. 1960, 82, 3498.

    Article  CAS  Google Scholar 

  15. P. Hambright, J. Inorg. Nucl. Chem. 1970, 32, 2449.

    Article  CAS  Google Scholar 

  16. R. Pasternack, N. Sutin, and D. Turner, J. Am. Chem. Soc. 1976, 98, 1908.

    Article  CAS  Google Scholar 

  17. D. K. Lavalle and G. M. Onady, Inorg. Chem. 1981, 20, 907.

    Article  Google Scholar 

  18. S. Funahashi, Y Yamaguchi, and M. Tanaka, Bull Chem. Soc. Jpn. 1984, 57, 204.

    Google Scholar 

  19. W. Schneider, Struct. Bonding (Berlin), 1975, 23, 123.

    CAS  Google Scholar 

  20. A. Shamin and P. Hambright, Inorg. Chem. 1983, 22, 694.

    Article  Google Scholar 

  21. L. Stryer, Biochemistry, 2nd ed., W. H. Freeman, San Francisco 1981, pp. 49–85.

    Google Scholar 

  22. Ref. 1, p. 99.

    Google Scholar 

  23. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Wiley, New York 1988, p. 1345.

    Google Scholar 

  24. J. P. Coliman, R. R. Gagne, T. R. Halbert, J. C. Marchon, and C. A. Reed, J. Am. Chem. Soc. 1973, 95, 7868.

    Article  Google Scholar 

  25. J. P. Coliman, R. R. Gagne, H. B. Gray, and J. W. Hare, J. Am. Chem. Soc. 1974, 96, 6522.

    Article  Google Scholar 

  26. J. P. Coliman, Acc. Chem. Res. 1984, 17, 16; J. Coliman, J. I. Brauman, E. Rose, and K. S. Suslick, Proc. Natl Acad. Sci. USA, 1978, 75, 1053.

    Article  Google Scholar 

  27. K. S. Suslick and T. J. Reinert, J. Chem. Educ. 1985, 62, 974.

    Article  CAS  Google Scholar 

  28. J. Almog, J. E. Baldwin, R. L. Dyer, and M. Peters, J. Am. Chem. Soc. 1975, 97, 226; J. Almog, J. E. Baldwin, and J. Huff, ibid. 227.

    Article  CAS  Google Scholar 

  29. Ref. 21, Chap. 3, pp. 43-83.

    Google Scholar 

  30. M. F. Perutz, Nature, 1970, 228, 726.

    Article  CAS  Google Scholar 

  31. Ref. 23, pp. 1346-1348; F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Interscience, New York 1972, pp. 870-871.

    Google Scholar 

  32. N. M. Senozan, J. Chem. Educ. 1985, 62, 181.

    Article  CAS  Google Scholar 

  33. Ref. 21, p. 76.

    Google Scholar 

  34. S. Ašperger and B. Cetina-Čižmek, Inorg. Chem. 1996, 35, 5232.

    Article  Google Scholar 

  35. K. Yamamoto, Sci. Pap. Inst. Phys. Chem. Res. (Jpn), 1977, 77, 111.

    Google Scholar 

  36. Z. Dokuzović, Xh. Ahmeti, D. Pavlović, and I. Murati, Inorg. Chem. 1982, 21, 1576.

    Article  Google Scholar 

  37. F. A. Walker, J. Am. Chem. Soc. 1973, 95, 1150–1154.

    Article  CAS  Google Scholar 

  38. D. Pavlović, S. Ašperger, and B. Domi, J. Chem. Soc, Dalton Trans. 1986, 2535.

    Google Scholar 

  39. D. V. Stynes, H. C. Stynes, B. R. James, and J. A. Ibers, J. Am. Chem. Soc. 1973, 95, 1796.

    Article  CAS  Google Scholar 

  40. D. V. Stynes, H. C. Stynes, J. A. Ibers, and B. R. James, J. Am. Chem. Soc. 1973, 95, 1142; ibid. 1974, 96, 1358.

    Article  CAS  Google Scholar 

  41. F. A. Walker, D. Beroiz, and K. M. Kadish, J. Am. Chem. Soc. 1976, 98, 1484; ibid. 1970, 92, 4234.

    Google Scholar 

  42. F. Basolo, B. M. Hoffman, and J. A. Ibers, Acc. Chem. Res. 1975, 8, 384.

    Article  CAS  Google Scholar 

  43. R. S. Drago, T. Beugelsdijk, J. A. Breese, and J. P. Cannady, J. Am. Chem. Soc. 1978, 100, 5374.

    Article  CAS  Google Scholar 

  44. B. S. Tovrog, D. J. Kitko, and R. S. Drago, J. Am. Chem. Soc. 1976, 98, 5144.

    Article  CAS  Google Scholar 

  45. R. Dreos, G. Tauzher, G. Costa, and M. Green, J. Chem. Soc, Dalton Trans. 1975, 2329.

    Google Scholar 

  46. J. A. Cohen and W. S. Caughey, Biochemistry, 1968, 7, 636.

    Article  CAS  Google Scholar 

  47. P. Zanello, R. Cini, A. Cinquantini, and P. L. Orioli. J. Chem. Soc, Dalton Trans. 1983, 2159.

    Google Scholar 

  48. D. Pavlović, S. Ašperger, Z. Dokuzović, B. Jurišić, Xh. Ahmeti, M. Sertic, and I. Murati, J. Chem. Soc, Dalton Trans. 1985, 1095.

    Google Scholar 

  49. C. R. Johnson, C. M. Jones, S. A. Asher, and J. E. Abola, Inorg. Chem. 1988, 27, 2120.

    Article  Google Scholar 

  50. J. A. Winter, D. Caruso, and R. E. Shepherd, Inorg. Chem. 1988, 27, 1086.

    Article  CAS  Google Scholar 

  51. M. G. Elliot and R. E. Shepherd, Inorg. Chem. 1987, 26, 2067.

    Article  Google Scholar 

  52. E. M. Sabo, R. E. Shepherd, M. S. Rau, and M. G. Elliott, Inorg. Chem. 1987, 26, 2897.

    Article  CAS  Google Scholar 

  53. J. Rebek, J. Struct. Chem. 1990, 129.

    Google Scholar 

  54. M. Meot-Ner (Mautner), J. Am. Chem. Soc 1988, 110, 3075.

    Article  Google Scholar 

  55. C. A. Matuszak and A. J. Matuszak, J. Chem. Educ. 1976, 53, 280.

    Article  CAS  Google Scholar 

  56. H. C. Freeman, in: G. L. Eichorn, Ed., Inorganic Biochemistry, Elsevier, New York 1973, Chap. 4, pp. 43–152.

    Google Scholar 

  57. R. J. Sundberg and R. B. Martin, Chem. Rev. 1974, 74, 471.

    Article  CAS  Google Scholar 

  58. H. Siegel, B. E. Fisher, and B. Prijs, J. Am. Chem. Soc. 1977, 99, 4489.

    Article  Google Scholar 

  59. F. Ramirez and J. F. Marecek, Synthesis, 1979, 71.

    Google Scholar 

  60. R. Sarma, F. Ramirez, P. Narayanan, B. McKeever, and J. F. Marecek, J. Am. Chem. Soc 1979, 101, 5015.

    Article  CAS  Google Scholar 

  61. F. Ramirez, R. Sarma, Y. F Chaw, T. McCaffrey, J. F. Marecek B. McKeever, and D. Nierman, J. Am. Chem. Soc. 1977, 99, 5285.

    Article  CAS  Google Scholar 

  62. V. Mc.Kee, C. C. Ong, and G. A. Redley, Inorg. Chem. 1984, 23, 4242.

    Article  CAS  Google Scholar 

  63. F. Ramirez, K. K. Shukla, and H. M. Levy, J. Theor. Biol 1979, 76, 351.

    Article  CAS  Google Scholar 

  64. K. K. Shukla, F. Ramirez, J. F. Marecek, and H. M. Levy, J. Theor. Biol. 1979, 76, 351.

    Article  Google Scholar 

  65. C. R. Johnson and R. E. Shepherd, Inorg. Chem. 1983, 22, 3506.

    Article  CAS  Google Scholar 

  66. W. P. Schaefer, Inorg. Chem. 1987, 26, 1820.

    Article  CAS  Google Scholar 

  67. W. W. Henderson, R. E. Shepherd, and J. Abola, Inorg. Chem. 1986, 25, 3157.

    Article  CAS  Google Scholar 

  68. T. Uno, K. Hatano, T. Nawa, K. Nakamura, Y. Nishimura, and Y. Arata, Inorg. Chem. 1991, 30, 4322.

    Article  CAS  Google Scholar 

  69. S. Ašperger and C. K. Ingold, J. Chem. Soc. 1956, 2862.

    Google Scholar 

  70. S. Ašperger, G. Vrban, B. Cetina-Cizmek, and M. Orhanovic, J. Chem. Soc, Dalton Trans. 1991, 1847.

    Google Scholar 

  71. S. Ašperger, Croat. Chem. Acta, 1996, 69, 1305.

    Google Scholar 

  72. M. S. A. Hamza and J. M. Pratt, J. Chem. Soc, Dalton Trans. 1994, 1367.

    Google Scholar 

  73. M. S. A. Hamza and J. M. Pratt, J. Chem. Soc, Dalton Trans. 1994, 1373; ibid. 1377.

    Google Scholar 

  74. H. M. Marques, O. Q. Munro, B. M. Cumming, and C. de Nysschen, J. Chem. Soc, Dalton Trans. 1994, 297.

    Google Scholar 

  75. W. H. Brown, Organic Chemistry, Saunders College Publishing, New York 1995, p. 324.

    Google Scholar 

  76. A. Streitwieser, Jr. and C. H. Heathcock, Introduction to Organic Chemistry, Macmillan, New York 1976, pp. 214–215.

    Google Scholar 

  77. F. Basolo and R. G. Pearson, Mechanism of Inorganic Reaction, 2nd ed., Wiley, New York 1967, pp. 171–172.

    Google Scholar 

  78. H. M. Marques, J. C. Bradley, K. L. Brown, and H. J. Brooks, J. Chem. Soc, Dalton Trans. 1993, 3475.

    Google Scholar 

  79. D. A. Baldwin, E. A. Betterton, and J. M. Pratt, S. Afr. J. Chem. 1982, 35, 173.

    CAS  Google Scholar 

  80. Y. Aoyama, T. Fujisawa, T. Watanabe, H. Toi, and H. Ogoshi, J. Am. Chem. Soc. 1986, 108, 943.

    Article  CAS  Google Scholar 

  81. F. Kojima, T. Aida, and S. Inome, J. Am. Chem. Soc. 1986, 108, 391.

    Article  CAS  Google Scholar 

  82. I. Eide and T. L. M. Syversen, Acta Pharmacol. Toxicol. 1983, 52, 217.

    Article  CAS  Google Scholar 

  83. D. C. Wigfield and S. Tse, Can. J. Chem. 1985, 63, 2940.

    Article  CAS  Google Scholar 

  84. J. P. Coliman, M. Marroco. P. Denisevich, C. Koval, and F. C. Anson, J. Electroanal. Chem. Interfacial Electrochem. 1979, 101, 117; J. P. Coliman, P. Denisevich, Y Konai, M. Marrocco, C. Koval, and F. C. Anson, J. Am. Chem. Soc. 1980, 102, 6027; J. P. Coliman, F. C. Anson, S. Bencosme, A. Chang, T. Collins, P. Denisevich, E. Evitt, T. Geiger, J. Ibers, G. Jameson, Y. Konai, C. Koval, K. Meier, R. Oakley, R. Pettman, E Schmitten, and J. Sessler, in: B. M. Trost and C. R. Hutchinson, Eds., Organic Synthesis, Today and Tomorrow, Pergamon Press, New York 1981, pp. 29-45.

    Article  Google Scholar 

  85. R. R. Durand, Jr., C. S. Bencosme, J. P. Coliman, and F. C. Anson, J. Am. Chem. Soc. 1983, 105, 2710.

    Google Scholar 

  86. C. C. Leznoff, S. M. Marcuccio, S. Greenberg, A. B. P. Lever, and K. B. Tomer, Can. J. Chem. 1985, 63, 623.

    Article  CAS  Google Scholar 

  87. S. M. Marcuccio, P. I. Svirskaya, S. Greenberg, A. B. P. Lever, and C. C. Leznoff, Can. J. Chem. 1985, 63, 3057.

    Article  CAS  Google Scholar 

  88. C. K. Chang, H. Y. Lin, and I. Abdalmuhdi, J. Am. Chem. Soc. 1984, 106, 2725.

    Article  CAS  Google Scholar 

  89. E. Vogel, Chem. Eng. News, 1995 (June 26), 27.

    Google Scholar 

  90. L. Sessler, Angew. Chem., Int. Ed. Engl. 1994, 33, 1348.

    Article  Google Scholar 

  91. S. Borman, Chem. Eng. News, 1995 (June 26), 30.

    Google Scholar 

  92. G.-B. Yi, M. A. Khan, and G. B. Richter-Addo, J. Am. Chem. Soc. 1995, 117, 7850. (b) see also: L. Chen, G.-B. Yi, L.-S. Wang, U. R. Dharmawardana, A. C. Dart, M. A. Khan, and G. B. Richter-Addo, Inorg. Chem. 1998, 37, 4677; G. B. Richter-Addo, Acc. Chem. Res. 1999, 32, 529; J. Lee, L. Chen, A. H. West, and G. B. Richter-Addo, Chem. Rev. 2002, 102, 1019-1065 (619 refs.).

    Article  CAS  Google Scholar 

  93. J. S. Lindsey and R. W. Wagner, J. Am. Chem. Soc. 1994, 116, 9759.

    Article  Google Scholar 

  94. R. Dagani, Chem. Eng. News, 1994 (Oct. 31), 5.

    Google Scholar 

  95. N. R. Finsen, Phototherapy, transl, (from Danish) J. H. Sequeira, Arnold, London 1901.

    Google Scholar 

  96. R. Bonnett, Chem. Soc. Rev. 1995, 24, 19.

    Article  CAS  Google Scholar 

  97. L. Milgrom and S. MacRobert, Chem. Br. 1998 (May), p. 45.

    Google Scholar 

  98. Chem. Br. 1998 (May), p. 18.

    Google Scholar 

  99. P. W. Atkins, Physical Chemistry, 5th ed., Oxford University Press, Oxford 1994, p. 447; W. J. Moore, Physical Chemistry, 4th ed., Prentice-Hall, Englewood Cliffs, NJ 1972, p. 649.

    Google Scholar 

  100. H. Carmichael, Chem. Br. 1998 (August), p. 30.

    Google Scholar 

  101. J. L. Sessler, N. A. Tvermoes, D. M. Guldy, T. D. Mody, and W. A. Allen, J. Phys. Chem. A, 1999, 103, 787

    Article  CAS  Google Scholar 

  102. T. D. Mody and J. J. Sessler, Porphyrin and Expanded Porphyrin-based Diagnostic and Therapeutic Agents, in: D. N. Reinhoudt, Ed., Supramolecular Materials and Technologies, Wiley, New York 1999, pp. 245–294

    Google Scholar 

  103. D. M. Guidi, T. D. Mody, N. N. Gerasimchuk, D. Magda, and J. L. Sessler, J. Am. Chem. Soc. 2000, 122, 8289

    Article  Google Scholar 

  104. J. L. Sessler, N. A. Tvermoes, D. M. Guidi, G. L. Hug, T. D. Mody, and D. Magda, J. Phys. Chem. 2001, 105, 1452

    Article  CAS  Google Scholar 

  105. J. L. Sessler, Chem. Eng. News, 2001 (March 26), 223.

    Google Scholar 

  106. F. Böhm, G. Marston, T. G. Truscott, and R. P. Wayne, J. Chem. Soc, Faraday Trans. 1994, 90, 2453.

    Article  Google Scholar 

  107. J. Suk, Acc. Chem. Res. 1992, 25, 273.

    Article  Google Scholar 

  108. K. D. Karlin, Science, 1993, 26, 701.

    Article  Google Scholar 

  109. B. Valeur and E. Bardez, Chem. Br. 1995, 31, 216.

    CAS  Google Scholar 

  110. A. E. Erikson, T. A. Jones, and A. Liljas, Proteins: Struct. Funct. Genet. 1988, 4, 214.

    Google Scholar 

  111. R. Riepe and J. H. Wang, J. Am. Chem. Soc. 1967, 89, 4229.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2003 Springer Science+Business Media New York

About this chapter

Cite this chapter

Ašperger, S. (2003). Kinetics and Mechanisms of Metalloporphyrin Reactions. In: Chemical Kinetics and Inorganic Reaction Mechanisms. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-9276-5_9

Download citation

  • DOI: https://doi.org/10.1007/978-1-4419-9276-5_9

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-4871-9

  • Online ISBN: 978-1-4419-9276-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics