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Substitution Reactions on Metal Complexes

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Chemical Kinetics and Inorganic Reaction Mechanisms

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Abstract

A chemical bond, represented in terms of shared pairs of electrons, can be broken homolytically or heterolytically, as shown by the following equations:

$$ A: B \to A \cdot + \cdot B Homolysis $$
(2.1.1)
$$ A: B \to A^ + + :B^ - Heterolysis $$
(2.1.2)
$$ A: B \to A:^ - + B^ + Heterolysis $$
(2.1.3)

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  1. Croatian Academy of Sciences and Arts, University of Zagreb, Zagreb, Croatia

    Smiljko Ašperger (Professor of Chemistry)

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Ašperger, S. (2003). Substitution Reactions on Metal Complexes. In: Chemical Kinetics and Inorganic Reaction Mechanisms. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-9276-5_3

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  • DOI: https://doi.org/10.1007/978-1-4419-9276-5_3

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