Skip to main content

Plastics and Composites from Soybean Oil

  • Chapter
Natural Fibers, Plastics and Composites

Abstract

Useful composite matrix materials have been prepared from a series of soybean oils. Their properties are primarily affected by crosslink density. The utility of these resins was demonstrated on two series of laminates prepared from two types of polyols and several types of reinforcements: glass fabric, carbon fiber, polyester, and cotton and jute fabrics. Polyurethane matrix resins are a viable alternative to epoxy and polyester matrix resins and they are already being used commercially in selected farm combine and automotive applications.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Miekel, J. American plastics: a cultural history, Rutgers University Press, 1995.

    Google Scholar 

  2. Mo, X., Hu, J., Sun, X.S. and Ratto, J.A. Compression and tensile strength of lowdensity straw protein particleboard. Industrial Crops and Products 2001; 14: 1–9.

    Article  CAS  Google Scholar 

  3. Zhong, Z., Sun, X.S., Fang, X. and Ratto, J.A. Adhesion properties of soy protein with fiber cardboard. J. Am. Oil Chem. Soc. 2001; 78:37–41.

    Article  CAS  Google Scholar 

  4. Sun, X. and Bian, K. “Novel materials from agroproteins: Adhesives from modified soy protein polymers.” In: Biopolymers from Polysacharides and Agroproteins, R.A. Gross and C. Scholz, eds. Washington, DC: American Chemical Society, 1999.

    Google Scholar 

  5. Petrovic, Z.S., Guo, A., Fuller, R. and Javni, I. Thermosetting resins from vegetable oils. SPE Technical Papers 1999; 45(ANTEC99): 888–891.

    Google Scholar 

  6. Crivello, J.V., Sternstein, S.S. and Narayan, R. Mechanical characterization of glass fiber reinforced/UV cured resins from epoxidized linseed oil. Proc. 1995 ASME Int. Mech. Eng. Congress and Expo 1995; Part 1, 69–1: 175-180.

    Google Scholar 

  7. American Institute of Chemical Engineers. Composite created from soybean oil. Chem. Eng. Prog. 1997; 93: 19–20.

    Google Scholar 

  8. Crivello, J.V., Narayan, R. and Sternstein, S.S. Fabrication and mechanical characterization of glass fiber reinforced UV-cured composites from epoxidized vegetable oils. J. Appl. Polym. Sci. 1997; 64: 2073–2087.

    Article  CAS  Google Scholar 

  9. Dahlke, B., Poltrock, R., Larbig, H. and Scherzer, H.D. Natural fibre reinforced foams based on renewable resources for automotive interior applications. J. Cell. Plast. 1998; 34: 361–379.

    CAS  Google Scholar 

  10. Materials Research Society. Chemically modified soy oil replaces conventional resins in composite manufacturing processes. MRS Bulletin 1998; 23: 6.

    Google Scholar 

  11. United Soybean Board. Deere testing reinforced soy plastics. Feedstocks 1998; 2: 2–2.

    Google Scholar 

  12. Warth, H., Muelhaupt, R., Hoffmann, B. and Lawson, S. Polyester networks based upon epoxidized and maleinated natural oils. Angew. Makromol. Chem. 1997; 249: 79–92.

    Article  CAS  Google Scholar 

  13. I. Ray Publishing. Expanding applications reinforce the value of composites. High Performance Composites 1997; 5: 10–25.

    Google Scholar 

  14. Larock, R. APUF (Agricultural Products Utilization Forum). Kansas City, 2002.

    Google Scholar 

  15. Larock, R. Preparation of industrially promising conjugated and metathesized soybean oil. Abstr. of the 89th AOCS Annual Meeting and Expo 39, 1998.

    Google Scholar 

  16. Larock, R.C., Refvik, M.D. and Poon, K.W.C. 92nd AOCS Annual Meeting and Expo Abstracts. Minneapolis, Minnesota, 2001.

    Google Scholar 

  17. Juangvanich, N. and Stoffer, J. Reactions of amines with epoxidized soybean oil. Polym. Prepr. 2002; 43: 922–923.

    CAS  Google Scholar 

  18. Abdel-Bary, E.M., Badran, B.M. and Ghanem, N.A. The modification of epoxidized oils with amines. I. The modification of epoxidized dehydrated castor oil with diamines. Eur. Polym. J. 1975; 11: 399–402.

    Article  CAS  Google Scholar 

  19. Dirlikov, S., Frischinger, I. and Chen, Z. Phase-separation of 2-phase epoxy thermosets that contain epoxidized triglycéride oils. Adv. Chem. Ser. 1996; 252: 95–109.

    Article  CAS  Google Scholar 

  20. Frischinger, I. and Dirlikov, S. Toughening of epoxy-resins by epoxidized vegetableoils. Polym. Commun. 1991; 32: 536–537.

    CAS  Google Scholar 

  21. Petrovic, Z.S., Zhang, W., Miller, R. and Javni, I. ANTEC 2002, San Francisco: SPE, 2002.

    Google Scholar 

  22. Muelhaupt, R. The use of renewable resources — possibilities and limitations. Chimia 1996; 50: 191–198.

    CAS  Google Scholar 

  23. Roesch, J. and Muelhaupt, R. Polymers from renewable resources: polyester resins and blends based upon anhydride-cured epoxidized soybean oil. Polym. Bull. (Berlin) 1993; 31:679–685.

    Article  CAS  Google Scholar 

  24. Gerbase, A.E., Petzhold, C.L. and Costa, A.P.O. Dynamic mechanical and thermal behavior of epoxy resins based on soybean oil. J. Am. Oil Chem. Soc. 2002; 79: 797–802.

    Article  CAS  Google Scholar 

  25. Wool, R., Kusefoglu, S., Palmese, G., Khot, S. and Zhao, R. U.S. Patent 6,121,398.

    Google Scholar 

  26. Lu, J. and Wool, R.P. 223rd ACS National Meeting; 2002 April 7-11; Orlando, FL, United States.

    Google Scholar 

  27. Williams, G.I. and Wool, R.P. Composites from natural fibers and soy oil resins. Applied Composite Materials 2000; 7: 421–432.

    Article  CAS  Google Scholar 

  28. Khot, S.N., Lascala, J.J., Can, E., Morye, S.S., Williams, G.I, Palmese, G.R, Kusefoglu, S.H. and Wool, R.P. Development and application of triglyceride-based polymers and composites. J. Appl. Polym. Sci. 2001; 82: 703–723.

    Article  CAS  Google Scholar 

  29. Wool, R.P, Kusefoglu, S.H, Khot, S.N, Zhao, R, Palmese, G, Boyd,A,Fisher, C, Bandypadhyay, S, Paesano, A, Dhurjati, P, LaScala, J, Williams, G, Gibbons, K, Bryner, M, Rhinehart, J, Robison, A, Wang, C. and Soultoukis, C. Affordable composites from renewable sources (ACRES). Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 1998; 39: 90.

    CAS  Google Scholar 

  30. Wool, R.P, Khot, S.H, LaScala, J.J, Williams, G.I, Bunker, S.P. and Morye, S.S. “Composites in the transportation industry.” In Proceedings of the ACUN-2: International Composites Conference, 2nd, Sydney, Australia: University of New South Wales, 2000, pp 619–627.

    Google Scholar 

  31. Wool, R.P. 223rd ACS National Meeting United States; 2002 April 7-11; Orlando, FL.

    Google Scholar 

  32. Daute, P, Gruetzmacher, R, Hoefer, R. and Westfechtel, A. Saponification resistant polyols for polyurethane applications based on oleochemical raw materials. Fett Wiss. Technol. 1993; 95: 91–94.

    CAS  Google Scholar 

  33. Guo, A, Cho, Y.-J. and Petrovic, Z.S. Structure and properties of halogenated and non-halogenated soy-based polyols. J. Polym. Sci. Part A: Polym. Chem. 2000; 38: 3900–3910.

    Article  CAS  Google Scholar 

  34. Gruber, B, Hoefer, R, Kluth, H. and Meffert, A. Polyols on the basis of oleochemical raw materials. Fett Wiss. Technol. 1987; 89: 147–151.

    CAS  Google Scholar 

  35. Nagakura, M. Fat and oil products in urethane polymers. Prog. Org. Coatings 1977; 5: 35–78.

    Article  CAS  Google Scholar 

  36. Petrovic, Z.S, Javni, I. and Guo, A. “Electroinsulating polyurethane casting resins based on soy oil and castor oil.” In Proceedings of the Polyurethanes ExPO′98. 1998, pp. 559–562.

    Google Scholar 

  37. Guo, A, Javni, I. and Petrovic, Z. Rigid polyurethane foams based on soybean oil. ACS PMSE Preprints 1999; 80: 503–504.

    CAS  Google Scholar 

  38. Javni, I, Petrovic, Z, Zhang, W. and Guo, A. Optimization of composition of soy-based polyols for rigid polyurethane foams. SPE Technical Papers (ANTEC 2000); 2000, vol. 46.

    Google Scholar 

  39. Petrovic, Z, Guo, A. and Javni, I. U. S. Patent 6,107,433.

    Google Scholar 

  40. Zlatanic, A, Petrovic, Z.S. and Dušek, K. Structure and properties of triolein — based polyurethane networks. Biomacromolecules 2002; 3: 1048–1056.

    Article  CAS  Google Scholar 

  41. Dušek, K, Dušková-Smrcková, M, Zlatanic, A. and Petrovic, Z. Polymeric materials from renewable resources. ACS; 2002; Orlando, FL.

    Google Scholar 

  42. Petrovic, Z.S. and Zlatanic, A. Proc. Polyurethanes Expo2001. Columbus, OH: CRC, 2001, pp 597–600.

    Google Scholar 

  43. Zlatanic, A, Lava, C, Zhang, W. and Petrovic, Z.S. Effect of structure on properties of polyols and polyurethanes based on different vegetable oils. Submitted to J. Polymer Science, part B 2003.

    Google Scholar 

  44. Javni, I, Zhang, W. and Petrovic, Z.S. Effect of different isocyanates on properties of soy-based polyurethanes. Submitted to J. Appl. Polym. Sci, 2003.

    Google Scholar 

  45. Mapleston, P. Automakers work on sustainable platforms (biopolymers). Modern Plastics 2003; 80(3): 45.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2004 Springer Science+Business Media New York

About this chapter

Cite this chapter

Petrović, Z.S., Guo, A., Javni, I., Zhang, W. (2004). Plastics and Composites from Soybean Oil. In: Wallenberger, F.T., Weston, N.E. (eds) Natural Fibers, Plastics and Composites. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-9050-1_11

Download citation

  • DOI: https://doi.org/10.1007/978-1-4419-9050-1_11

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-4774-3

  • Online ISBN: 978-1-4419-9050-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics