Abstract
Polylactic acid (PLA) is a thermoplastic polyester that has been commercialized for use in biodegradable plastic bags and planting cups. Recent research and development efforts show that it is also a superior composite matrix material. Flax reinforced PLA composites, which are readily extrusion and compression molded, were found to have 50% higher strength than other flax reinforced thermoplastic composites which are already being used in automotive panels.
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References
Hornsby, P.R., Hinrichsen, E. and Tarverdi, K. Preparation and properties of polypropylene composites reinforced with wheat and flax straw fibers. Part II. Analysis of composite microstructure and mechanical properties. J. Mat. Sci. 1997; 32: 1009–1015.
Heijenrath, R. and Peijs, T. Natural-fibre-mat-reinforced thermoplastic composites based on flax fibres and polypropylene. Advanced Composites Letters 1996; 5(3): 81–85.
Oksman, K. Mechanical properties of natural fibre mat reinforced thermoplastics. Appl. Comp. Mat. 2000; 7: 403–414.
Mieck, K.-P., Nechwatal, A. and Knobeldorf, C. Potential applications of natural fibres in composite materials. Melliand Textilberichte (English) 1994; 11: 228–230.
Bledzki, A.K., Reihmane, S. and Gassan, J. Properties and modification methods for vegetable fibers for natural fiber composites. J. Appl. Polymer Sci. 1996; 5: 1329–1336.
Li, Y., Mai, Y.-W. and Lin,Y. Sisal fibre and its composites: a review of recent developments. Composites Science and Technology 2000; 60: 2037–2055.
Bürger, H., Koine, A., Maron, R. and Mieck, K.-P. Use of natural fibres and environmental aspects. International Polymer Science and Technology 1995; 22: 25–34.
Sanadi, A.R., Prasad, S.V. and Rohatgi, P.K. Natural fibres and agro-wastes as fillers and reinforcements in polymer composites. J. Sci. Ind. Res. 1985; 44: 437–442.
Oksman, K. High quality flax fibre composites manufactured by the resin transfer moulding process. J. Reinforced Plastics and Composites 2001; 20(7): 621–627.
Plackett, D.V. and Andersen, T.L Biocomposites from natural fibres and biodegradable polymers; Processing, properties and futures prospects. Proceedings of the 23rd Rise International Symposium on Materials Science: Sustainable Natural and and Polymeric Composites-Science and Technology; 2002; Ris0 National Laboratory, Roskilde, Denmark.
Cyras, V.P., Innace, S., Kenny, J.M. and Vazques, A. Relationship between processing and properties of biodegradable composites based on PCL/starch matrix and sisal fibres. Polymer Composites 2001; 22(1): 104–110.
Riedel, U. and Nickel, J. Natural fibre-reinforced biopolymers as construction materials-new discoveries. Angew. Macromol. Chemie 1999; 272: 34–40.
Herrmann, A.S., Nickel, J. and Riedel, U. Construction materials based upon biologically renewable resources-from components to finished parts. Polymer Degradation and Stability 1998; 59: 251–261.
Mishra, S., Tripathy, S.S., Misra, M., Mohanty, A.K. and Nayak, S.K. Novel ecofriendly biocomposites: biofiber reinforced biodegradable polyester amide compositesfabrication and properties evaluation. J. Reinforced Plastics and Composites 2002; 21(1): 5570.
Williams, G.I. and Wool, R.P. Composites from natural fibres and soy oil resin. Appl. Comp. Mat. 2000; 7: 421–432.
Meinander. K., Niemi, M., Hakola, J.S. and Selin, J.-F. Polylactides-degradable polymers for fibres and films. Macromol. Symp. 1997; 123: 147–154.
Holten, C.H., Muller, A. and Rehbinder, D. Lactic Acid. Copenhagen: Verlag Chemie, International Research Association, 1971, Chapter xVII.
Salminen, S. and Wright, A., eds. Lactic Acid Bacteria. New York: Marcel Dekker 1993, pp. 65–95.
Carothers. W.H., Dorough, G.L. and Van Natta, F.J. Studies of polymerization and ring formation. x. The reversible polymerizationof six-membered cyclic esters. J. Am. Chem. Soc. 1932; 54: 761–772.
Jacobsen, S., Fritz, H.-G., Degée, P., Dubois, P. and Jérôme, R. New developments on the ring opening polymerisation of polylactide. Industrial Crops and Products 2000; 11: 265–275.
Drumright, R.E., Gruber, P.R. and Henton, D.E. Polylactic acid technology. Adv. Mater. 2000; 12(23): 1841–1846.
Ajioka, M., Enomoto, K., Suzuki, K. and Yamaguchi, A. The basic properties of poly(lactic acid) produced by the direct condensation polymerization of lactic acid. J. Environ. Polym. Degrad. 1995; 3: 225–234.
Mukherejee, P.S. and Satyanarayana, K.G. Structure and properties of some vegetable fibres. Part 1. Sisal fibre. J. Mat. Sci. Tech. 1984; 19: 3925–3934.
Ilvessalo-Pläffi, M.-S. Fiber Atlas, Identification of Papermaking Fibers. Berlin, Heidelberg: Springer-Verlag, 1995.
Bledzki, A.K., Reihmane, S. and Gassan, J. Properties and modification methods for vegetable fibers for natural fiber composites. J. Appl. Poly.Sci. 1996; 5: 1329–1336.
Södergard, A., Niemi, M., Selin, J.-F. and Näsman, J.H. Changes in peroxide meltmodified poly(L-lactide). I&EC Research 1995; 34:1203–1207.
Chartoff, R.P. “Thermoplastic polymers.” In: Thermal Characterization of Polymeric Materials, E.A. Turi ed. Academic Press, 2nd ed., 1997; vol. 1: chap. 3.
Mapleston, P. Automakers work on sustainable platforms (Biopolymers). Modern Plastics 2003; 80(3): 45.
Best, J.R. Biodegradable polymers could replace 0.2% of conventional global plastics production. Injection Molding, Extrusion and Blow Molding Newsletter 2003; 27(14, April 14): 2.
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Oksman, K., Selin, JF. (2004). Plastics and Composites from Polylactic Acid. In: Wallenberger, F.T., Weston, N.E. (eds) Natural Fibers, Plastics and Composites. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-9050-1_10
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DOI: https://doi.org/10.1007/978-1-4419-9050-1_10
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