Abstract
The Chapter focuses on the role of inelastic and second-kind (superelastic) collisions in shaping the electron energy distribution function (eedf). Particularly important are the second-kind collisions, which create structures on the eedf, such as peaks and plateaux, also experimentally observed. This non-equilibrium behavior is reflected on the rate coefficients of electron induced processes, in particular dissociation and ionization.
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Notes
- 1.
This principle assure the existence of the equilibrium distribution.
- 2.
We should note that \( S_{sup}^{2}(\varepsilon ) = -S_{sup}^{1}(\varepsilon -\varepsilon ^{\star }) \) and \( S_{in}^{2}(\varepsilon ) = -S_{in}^{1}(\varepsilon +\varepsilon ^{\star }) \).
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Capitelli, M. et al. (2016). Superelastic Collisions and Electron Energy Distribution Function. In: Fundamental Aspects of Plasma Chemical Physics. Springer Series on Atomic, Optical, and Plasma Physics, vol 85. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-8185-1_5
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