Abstract
Highly porous titania is attractive because of various applications such as photocatalysts. Mesoporous titania gels can be prepared by the sol–gel method with templating. The incorporated surfactant micelles or polymer aggregates in wet gels prevent the shrinkage while drying under ambient pressure. The specific surface area, porosity, and pore size, depending on the preparation conditions, for example, species of templating materials, are much larger than those of xerogels but not larger than those of aerogels. The performance of porous titania, for example, the photocatalytic activity, can be improved with suitable pore structure for specific applications.
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References
Fricke J (1986) Aerogels – a fascinating class of high-performance porous solids. in “Aerogels” Ed. Fricke J, Springer, Berlin: 2–19
Huesing N, Shubert U (1998) Aerogels – airy materials. Angew Chem Int Ed 37:22–45
Teichner S J (1986) Aerogels of inorganic oxides. in in “Aerogels” Ed. Fricke J, Springer, Berlin: 22–30
Matthews R W (1987) Photooxidation of organic impurities in water using thin films of titanium dioxide. J Phys Chem 91: 3328–3333
Matthews L R, Avnir D, Modestov A D, Sampath S, Lev O (1997) The incorporation of titanium into modified silicates for solar photodegradation of aqueous species. J Sol-Gel Sci Tech 8:619–623
O’Regan B, Graetzel M (1991) A low-cost, high-efficiency solar cell base on dye-sensitized colloidal TiO2 films. Nature 353:737–740
Traversa E, Di Vona M L, Licoccia S, Sacerdoti M (2000) Sol-gel nanosized semiconducting titania-based powders for thick-film gas sensors. J.Sol-Gel Sci Tech 19:193–196
Wang R, Hashimoto k, Fijishima A, Chikuni M, Kojima E, Kitamura A, Shimohigishi M, Watanabe T (1997) Light-induced amphiphilic surfaces. Nature 388:431–432
Hirashima H, Kojima C, Kohama K, Imai H (1997) Application of alumina aerogels as catalysts. J Sol-Gel Sci Techn 8:843–846
Hirashima H, Imai H, Balek V (1998) Characterization of alumina gel catalysts by emanation thermal analysis (ETA). J Sol-Gel Sci Techn 19:399–402
Willey R J, Wang C-T, Peri J B (1995) Vanadium-titanium oxide aerogel catalysts. J Non-Cryst Solids 186:408–414
Hong-Van C, Zegaoui O, Pichat P (1998) Vanadia-titania aerogel deNOx catalysts. J Non-Cryst Solids 225:157–162
Beghi M, Chiurlo P, Costa L, Plladino M, Pirini M F (1992) Structural investigation of the silica-titania gel/glass transition. J Non-Cryst Solids 145:175–179
Yoda S, Tasaka Y, Uchida K, Kawai A, Oshima S, Ikazaki F (1998) TiO2-impregnated SiO2 aerogels by alcohol supercritical drying with zeolite. J Non-Cryst Solids 225:105–110
Yoda S, Otake K, Takabayashi Y, Sugeta T, Sato T (2001) Effects of supercritical impregnation conditions on the properties of silica-titania aerogels. J Non-Cryst Solids 285:8–12
Pietron J J, Rolison D R (2001) Electrochemically induced surface modification of titanols in a ‘nanoglued’ titania aerogel composite film. J Non-Cryst Solids 285:13–21
Pietron J J, Rolison D R (2004) Improving the efficiency of titania aerogel-based photovoltaic electrodes by electrochemically grafting isopropyl moieties on the titania surface. J Non-Cryst Solids 350:107–112
Tursiloadi S, Imai H, Hirashima H (2004) Preparation and characterization of mesoporous titania-alumina ceramic by modified sol-gel method. J Non-Cryst Solids 350:271–276
Shimizu K, Imai H, Hirashima H, Tsukuma K (1999) Low-temperature synthesis of anatase thin films on glass and organic substrates by direct deposition from aqueous solutions. Thin Solid Films 351:220–224
Imai H, Takei Y, Shimizu K, Matsuda M, Hirashima H (1999) Direct preparation of anatase TiO2 nanotubes in porous alumina membranes. J Mater Chem. 9:2971–2972
Smith D.M, Stein D, Anderson J M, Ackerman W (1995) Preparation of low-density xerogels at ambient pressure. J Non-Cryst Solids 186:104–112
Prakash S S, Brinker C J, Hurd A.J (1995) Silica aerogel films at ambient pressure. J Non-Cryst Solids 190:264-275
Land V, Harris T.M, Teeters D C (2001) Processing of low-density silica gel by critical point drying or ambient pressure drying. J Non-Cryst Solids 283:11–17
Kajihara K, Nakanishi K, Tanaka K, Hirano K, Soga N (1998) Preparation of macroporous titania films by a sol-gel dip-coating method from the system containing poly(ethylene glycol). J Am Ceram Soc 81:2670–2676
Negishi N, Takeuchi K, Ibusuki T (1997) The surface structure of titanium dioxide thin film photocatalyst. Appl Surf Sci 121/122:417–420
Takahashi R, Nakanishi K, Soga N, (1995) Effects of aging and solvent exchange on pore structure of silica gels with interconnected macropores. J Non-Cryst Solids 189:66–76
Yusuf M M, Imai H, Hirashima H (2003) Preparation of mesoporous titania by templating with polymer and surfactant and its characterization. J Sol-Gel Sci Technol 28:97–104
Hirashima H, Imai H, Balek V (2001) Preparation of mesoporous TiO2 gels and their characterization. J Non-Cryst Solids 285:96–100
Yusuf M M, Chimoto Y, Imai H, Hirashima H (2003) Preparation and characterization of porous titania by modified sol-gel method. J Sol-Gel Sci Technol 26:635–640
Yusuf M M, Imai H, Hirashima H (2001) Preparation of mesoporous TiO2 thin films by surfactant templating. J Non-Cryst Solids 285:90–95
Yusuf M M, Imai H, Hirashima H (2002) Preparation of porous titania film by modified sol-gel method and its application to photocatalyst. J Sol-Gel Sci Technol 25:65–74
Hirashima H, Imai H, Miah M Y, Bountseva I M, Beckman I N, Balek V (2004) Preparation of mesoporous titania gel films and their characterization. J Non-Cryst Solids (2004) 350: 266–270
Miah M Y (2002) Preparation, characterization and application of porous titania by sol-gel method. PhD Thesis, Keio University, Japan pp.79–101
Tursiloadi S, Yamanaka Y, Hirashima H (2006) Thermal evolution of mesoporous titania prepared by CO2 supercritical extraction. J Sol-Gel Sci Technol 38:5–12
Negishi N, Takeuchi, K, Ibusuki T (1997) The surface structure of titanium dioxide thin film photocatalyst. Appl Surface Sci 121/122:417–420
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Hirashima, H. (2011). Preparation of TiO2 Aerogels-Like Materials Under Ambient Pressure. In: Aegerter, M., Leventis, N., Koebel, M. (eds) Aerogels Handbook. Advances in Sol-Gel Derived Materials and Technologies. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-7589-8_7
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DOI: https://doi.org/10.1007/978-1-4419-7589-8_7
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