Abstract
Foaming in steel refining processes and in bath smelting reduction processes adversely impacts the quality and productivity of steel. Suppression of foaming is, therefore, one of the key processes in the steelmaking industry. Foaming is known to be caused through the effect of CO gas generation from decarburization and to be suppressed by adding coke or coal to the upper slag layer, decreasing the viscosity of the slag, or increasing the surface tension of the slag [1,2,3,4,5]. In addition, a low-frequency sonic wave is considered to be effective for suppression of slag foaming [6]. Based on X-ray fluoroscopic observations, Ogawa et al. [7] found that the attachment of CO bubbles to a solid body of poor wettability is extremely effective for suppressing foaming. The CO bubbles attached to the body become larger due to coalescence and are pulled to the bath surface as a result of the increased buoyancy force acting on the bubbles. This result suggests that the attachment of bubbles to solid bodies of poor wettability may be useful for removing fine bubbles contained in molten metals. For example, the method would be applicable to the removal of fine argon bubbles from continuous casting molds and thus aid the production of clean steel by suppressing bubble-induced defects such as pinhole and sliver.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ito K, Fruehan RJ (1989) Study on the foaming of CaO-SiO2-FeO Slags. Part II. Dimensional analysis and foaming in iron and steelmaking processes. Metall Trans B 20B:515
Ghag SS, Hayes PC, Lee H-G (1998) Model development of slag foaming. ISIJ Int 38:1208
Hing L, Hirasawa M, Sano M (1998) Behavior slags by of slag foaming with graphite. ISIJ Int 38:1339
Matsuo M, Hirata H, Katayama H, Ishikawa H, Kajioka H, Tokumitsu N (1986) Tetsu-to-Hagane 72:S970
Ito K, Fruehan RJ (1989) Study on the foaming of CaO-SiO2-FeO Slags: Part I. Foaming parameters and experimental results. Metall Trans B 20B:509
Komarov SV, Kuwabara M, Sano M (1990) Mechanism of acoustic defoaming by applying low frequency sound. CAMP ISIJ 12:721
Ogawa Y, Tokumitsu N (1990) Observation of slag foaming by X-ray fluoroscopy, In: Proceedings of the 6th international iron and steel congress. ISIJ, Tokyo, p 147
Mizuno Y, Shimizu T, Sonoyama N, Iguchi M (2000) Attachment of bubbles to a horizontal circular cylinder of poor wettability. Jpn J Multiphase Flow 14:166
Sonoyama N, Iguchi M, Sasaki Y, Ishii K (2000) Behavior of a single bubble colliding with a flat plate of poor wettability. Tetsu-to-Hagane 86:203
Lee C, Takahashi I, Miyata H (1995) Proposal on evaluation method of adhesion tension based on analytical estimation of configuration of sessile drops. Trans Jpn Soc Mech Eng (B) 61:4386
Fritz W (1935) Maximum volume of vapor bubbles, Physik Zeitschr 36:379
Bashforth F, Adams JC (1883) An attempt to test the theories of capillary action. Cambridge University Press, London
Murakami K, Sunada T, Ueki N (1998) Behavior of residual liquid on disk for mist flow injected between horizontal parallel disks. Trans Jpn Soc Mech Eng (B) 64:2071
Sano M, Mori K, Sato T (1977) Bubble formation at single nozzles immersed in molten iron. Tetsu-to-Hagane 63:2308
Mizuno Y, Inoue H, Sonoyama N, Iguchi M (2000) Size and shape of a bubble on the upper surface of a horizontal plate of poor wettability. Tetsu-to-Hagane 86:709–716
Ozawa Y, Mori K, Sano M (1981) Behavior of injected gas observed at the exit of a submerged orifice in liquid metal. Tetsu-to-Hagane 16:2655
Asai S (1984) 100th and 101st Nishiyama memorial lecture. ISIJ, Tokyo, pp 67
Sahai Y, St. Pierre GR (1992) Advances in transport phenomena in metallurgical systems. Elsevier, Amsterdam
The 140th Committee of Japan Society for Promotion of Science (1988) Handbook of physicochemical properties at high temperatures. ISIJ, Tokyo
Mori K, Sano M (1981) Process kinetics in injection metallurgy. Tetsu-to-Hagane 67:672
Iguchi M, Chihara T, Takanashi N, Ogawa Y, Tokumitsu N, Morita Z (1995) X-ray fluoroscopic observation ot bubble characteristics in a molten iron bath. ISIJ Int 35:1354
Irons GA, Guthrie RIL (1978) Bubble formation at nozzles in pig iron. Metall Trans 9B:101
Zhe W, Mukai K, Yamaguchi K, Lee J (1998) Influence of interfacial properties on the formation of bubble-related defects in slab. CAMP ISIJ 11:24
Kawakami M, Tomimoto, Itoh K (1982) Statistical analysis of gas bubbles dispersion in liquid phase. Tetsu-to-Hagane 68:774
Iguchi M, Ueda H, Uemura T (1995) Bubble and liquid flow characteristics in a vertical bubbling jet. Int J Multiphase Flow 21:861
Iida T, Guthrie RIL (1988) The physical properties of liquid metals. Oxford University Press, Oxford
Castillejos AH, Brimacombe JK (1987) Measurement of physical characteristics of bubbles in gas-liquid plumes. Part I1. Local properties of turbulent air-water plumes in vertically injected jets. Metall B 18B:659
Sano M, Makino H, Ozawa Y, Mori K (1986) Behavior of gas jet and plume in liquid metal. Trans Iron Steel Inst Jpn 26:298
Iguchi M, Nozawa K, Tomida H, Morita Z (1992) Bubble characteristics in the buoyancy region of a vertical bubbling jet. ISIJ Int 32:747
Mazumdar D, Guthrie RIL (1995) The physical and mathematical modelling of gas stirred ladle systems. ISIJ Int 32:747
Sugita K (1998) Various phenomena observed at refractory-iron melt interfaces: A condensed history of studies on their interactions. Bul ISIJ (Ferrum) 3:891
Sonoyama N, Iguchi M (1999) Wettability effects on bubble characteristics in a bubbling wall jet along a vertical flat plate. ISIJ Int 39:673–679
Rajaratnam N (1981) Turbulent jet (trans: Nomura Y). Morikita Publishing Co. Ltd., Tokyo
Rajaratnam N, Pani BS (1994) Three-dimensional turbulent wall jets, Trans ASCE 100(HY1):69
Verhoff A (1963) The two-dimensional turbulent wall jet with and without an external stream. Rep. 626, Princeton University, Princeton, NJ
Clift R, Grace JR, Weber ME (1978) Bubbles, drops, and particles. Academic, New York
Hetsroni G (1989) Particles-turbulence interaction. Int J Multiphase Flow 15:735
Iguchi M, Sonoyama N (2000) Wettability effects on liquid flow characteristics in a bubbling wall jet along a vertical flat plate. ISIJ Int 40:1–6
Shinozaki N, Echida N, Mukai K, Takahashi Y, Tanaka Y (1994) Wettability of Al2O3-MgO, ZrO2-CaO, Al2O3-CaO substrates with molten iron. Tetsu-to-Hagane 80:748–753
Takahira H, Fujikawa S, Akamatsu T (1989) Collapse motion of a single gas bubble near a plane or curved rigid wall. Trans Jpn Soc Mech Eng B 55:2720–2728
Shopov PJ, Minev PD, Bazhlekov IB, Zapryanov ZD (1990) Interaction of a deformable bubble with a rigid wall at moderate Reynolds numbers. J Fluid Mech 219:241–271
Maxworthy T (1991) Bubble rise under an inclined plate. J Fluid Mech 229:659–674
Tsao H, Koch DL (1997) Observations of high Reynolds number bubbles interacting with a rigid wall. Phys Fluids 9:44–56
Wang QX, Yeo KS, Khoo BC, Lam KY (1998) Toroidal bubbles near a rigid boundary. Theoret Comput Fluid Dyn 12:29–51
Tao Z, Mukai K, Takahashi T (1999) Mechanism of local corrosion of MgO-C refractory at slag-metal interface. CAMP ISIJ 12:208
Abbel G, Damen W, de Gendt G, Tiekink W (1996) Argon bubbles in slabs. ISIJ Int 36:S219–S222
Kasai N, Watanabe Y, Kajiwara T, Toyoda M (1997) Mechanism of fine bubbles entrapment beneath the surface of continuously cast slabs. Tetsu-to-Hagane 83:24–29
Iguchi M, Nakatani T, Ueda H (1997) Model study of turbulence structure in a bottom blown bath with top slag using conditional sampling. Metall Trans B 28:87–94
Zhe W, Mukai K, Matsuoka K (1997) Water model experiment for the behaviors of bubbles and liquid flow on the inside of the nozzle and mold of continuous casting process. CAMP ISIJ 10:68–71
MacDougall G, Ockrent C (1942) Surface energy relations in liquid/solid systems. I. The adhesion of liquids to solids and a new method of determining the surface tension of liquids. Proc R Soc Lond Ser A 180:151–173
Shoji M, Zhang XY (1992) Study of contact angle hysteresis: In relation to boiling surface wettability. Trans Jpn Soc Mech Eng B 58:1853–1859
Fukai J, Shibata Y, Yamamoto T, Miyatake O, Poulikakos D, Megaridis CM, Zhao Z (1995) Wetting effects on the spreading of a liquid droplet colliding with a flat surface: Experiment and modeling. Phys Fluids 7:236–247
Wenzel RN (1936) Resistance of solid surfaces to wetting by water. Ind Eng Chem 28:988–994
Fujita M, Madarame H (1983) Bubble dynamics in a horizontal rectangular pipe with rough wall. Trans Jpn Soc Mech Eng B 49:1676–1684
Murakami K, Sunada T, Ueki N (1998) Behavior of residual liquid on disk for mist flow injected between horizontal parallel disks. Trans Jpn Soc Mech Eng B 64:2071–2078
Kawasaki K (1960) Study of wettability of polymers by sliding of water drop. J Colloid Sci 15:402–407
Furmidge CGL (1962) Studies at phase interfaces. I. The sliding of liquid drops on solid surfaces and a theory for spray retention. J Colloid Sci 17:309–324
Larkin BK (1967) Numerical solution of the equation of capillarity. J Colloid Interface Sci 23:305–312
Ogawa Y, Huin D, Gaye H, Tokumitsu N (1993) Physical model of slag foaming. ISIJ Int 33(1):224–232
Sano N, Fruehan RJ, Cramb AW (1991) Computer aided interfacial measurements, US-Japan joint seminar, fundamental of bath smelting and clean steel production. Myrtle Beach, 7–9 Oct
Fukui K (1996) A study on the new iron ore smelting reduction processes. Tetsu-to-Hagane 82(1):1–7
Iguchi M, Kondoh T, Uemura T (1994) Simultaneous measurement of liquid and bubble velocities in a cylindrical bath subject to centric bottom gas injection. Int J Multiphase Flow 20:753–762
Anagbo PE, Brimacombe JK (1990) Plume characteristics and liquid circulation in gas injection through a porous plug. Metall Mater Trans B 21B:637–648
Iguchi M, Kaji M, Morita Z (1998) Effects of pore diameter, bath surface pressure, and nozzle diameter on the bubble formation from a porous nozzle. Metall Mater Trans B 29B:1209–1218
Davidson L, Amick EH Jr (1956) Formation of gas bubbles at horizontal orifices. AIChE J 2:337–342
Castello-Branco MASC, Schwerdtfeger K (1994) Large-scale measurements of the physical characteristics of round vertical bubble plumes in liquids. Metall Mater Trans B 25B:359–371
Akagawa K (1980) Gas–liquid two-phase flow. Corona Publishing Co. Ltd, Tokyo
Hetsroni G (1982) Handbook of multiphase systems. Hemisphere Publishing Corporation, Washington
Ueda T (1989) Gas–liquid two-phase flow (Fluid flow and heat transfer). Yokendo Publishing Co. Ltd, Tokyo
The Japan Society of Mechanical Engineers (1989) Handbook of gas–liquid two-phase flow technology. Corona Publishing Co. Ltd., Tokyo
Barajas AM, Panton RL (1993) The effects of contact angle on two-phase flow in capillary tubes. Int J Multiphase Flow 19:337–346
Terauchi Y, Iguchi M, Kosaka H, Yokoya S, Hara S (1999) Wettability effect on the flow pattern of air–water two-phase flows in a vertical circular pipe. Tetsu-to-Hagane 85(9):645–651 (in Japanese)
Taitel Y, Barnea D, Dukler AE (1980) Modelling flow pattern transitions for steady upward gas-liquid flow in vertical tubes. AIChE J 26(3):345–354
Weisman J, Kang SY (1981) Flow pattern transitions in vertical and upwardly inclined lines. Int J Multiphase Flow 7:271–291
Mishima K, Ishii M (1984) Flow regime transition criteria for upward two-phase flow in vertical tubes. Int J Heat Mass Transfer 27:723–737
Iguchi M, Terauchi Y (2001) Boundaries among bubbly and slug flow regimes in air–water two-phase flows in vertical pipe of poor wettability. Int J Multiphase Flow 27:729–735
Nicklin DJ, Wilke JO, Davidson JF (1962) Two-phase flow in vertical tubes. Trans Inst Chem Eng 40(1):61
Kariyasaki A, Fukano T, Outsuka A, Kagawa M (1992) Isothermal air-water two-phase up-and downward flows in a vertical capillary tube (1st report, flow pattern and void fraction). Trans Jpn Soc Mech Eng 58(553):2684–2690
Akagawa K, Sakaguchi T (1965) Fluctuation of void ratio in a two-phase flow : 3rd report, absolute velocities of slugs and small bubbles. Trans Jpn Soc Mech Eng 31(224):601–607
Street JR, Tek MR (1965) Dynamics of bullet shaped bubbles encountered in vertical gas liquid slug flow. AIChE J 11(4):644–650
Iguchi M, Terauchi Y (2000) Rising behavior of air–water two-phase flows in vertical pipe of poor wettability. ISIJ Int 40:567–571
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2011 Springer New York
About this chapter
Cite this chapter
Iguchi, M., Ilegbusi, O.J. (2011). Interfacial Phenomena. In: Modeling Multiphase Materials Processes. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-7479-2_4
Download citation
DOI: https://doi.org/10.1007/978-1-4419-7479-2_4
Published:
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4419-7478-5
Online ISBN: 978-1-4419-7479-2
eBook Packages: EngineeringEngineering (R0)