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Pillared Clays and Related Catalysts pp 319–397Cite as

Heterogeneous Catalysis by Polyoxometalate-Intercalated Layered Double Hydroxides

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Abstract

The preparation, characterisation and catalytic performance of layered double hydroxides (LDH) with the hydrotalcite-type structure containing different polyoxometalates (POM) in the interlayer are studied. Special attention is paid to the preparation procedures, as they control the properties of the solids formed and thus their catalytic behaviour. The study is extended to solids prepared upon thermal decomposition of these POM–LDH systems. It is concluded that the LDH does not act as a simple support, but that its specific properties, such as nature of the cations in the brucite-like layers, specific surface area and the method followed for its preparation, have an outstanding effect on the final catalytic properties of the POM–LDH systems.

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Acknowledgements

Authors thank for financial support from Ministerio de Educación y Ciencia (grant MAT2009-08526) and ERDF. DC acknowledges a grant from Junta de Castilla y León.

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Authors and Affiliations

  1. GIR-QUESCAT, Departamento de Química Inorgánica, Universidad de Salamanca, Salamanca, 37008, Spain

    Vicente Rives & Cristina Martín

  2. Instituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC), Cantoblanco, 28049, Madrid, Spain

    Daniel Carriazo

Authors
  1. Vicente Rives
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  2. Daniel Carriazo
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  3. Cristina Martín
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Correspondence to Vicente Rives .

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Editors and Affiliations

  1. Department of Applied Chemistry, Public University of Navarra, Pamplona, 31006, Spain

    Antonio Gil

  2. Department of Applied Chemistry, Public University of Navarra, Pamplona, 31006, Spain

    Sophia A. Korili

  3. , Department of Inorganic Chemistry, University of Salamanca, Plaza de los Caídos s/n, Salamanca, 37008, Spain

    Raquel Trujillano

  4. , Department of Inorganic Cehmistry, University of Salamanca, Plaza de los Caídos s/n, Salamanca, 37008, Spain

    Miguel Angel Vicente

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Rives, V., Carriazo, D., Martín, C. (2010). Heterogeneous Catalysis by Polyoxometalate-Intercalated Layered Double Hydroxides. In: Gil, A., Korili, S., Trujillano, R., Vicente, M. (eds) Pillared Clays and Related Catalysts. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-6670-4_12

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