Abstract
A Schottky junction is not only an important heterostructure for electronic and optical devices, but is also an ideal system for studying fundamental interface physical phenomena such as band-offsets, band bending, and interface states. In this chapter, we focus our attention on the complex oxides with the perovskite structure. This family of materials exhibit unique physical properties including ferroelectricity, magnetism and high temperature superconductivity. We will describe how to incorporate the strong interaction between charge, lattice and spins, absent in conventional semiconductors, in describing oxide Schottky junctions, and present new oxide specific functionalities. After a brief overview of the history of complex oxide Schottky junctions (Sect. 5.1), the basics of Schottky junctions are reviewed (Sect. 5.2). The specific features of oxide Schottky junctions will be introduced focusing on band bending and band alignment mechanisms (Sect. 5.3) followed by examples of novel functionalities achievable in oxide Schottky junctions (Sect. 5.4). This Chapter will close with a summary and a future outlook (Sect. 5.5).
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References
Goodenough JB (1971) Prog Solid Stat Chem 5:145
Tsuda N, Nasu K, Fujimori A, Siratori K (2000) Electronic conduction in oxides, 2nd rev. Springer, Berlin
Imada M, Fujimori A, Tokura Y (1998) Rev Mod Phys 70:1039
Galasso FS (1970) Structure and properties of inorganic solids. Pergamon, Oxford
Chrisey DB, Hubler GK (1994) Pulsed laser deposition of thin films. Wiley, New York
Kawasaki M, Takahashi K, Maeda T, Tsuchiya R, Shinohara M, Ishiyama O, Yonezawa T, Yoshimoto M, Koinuma H (1994) Science 266:1540
Koster G, Kropman BL, Rijnders GJHM, Blank DHA, Rogalla H (1998) Appl Phys Lett 73:2920
Mukunoki Y, Nakagawa N, Susaki T, Hwang HY (2005) Appl Phys Lett 86:171908
Ohtomo A, Muller DA, Grazul JL, Hwang HY (2002) Nature 419:378
Ohtomo A, Hwang HY (2004) Nature 427:423
Okamoto S, Millis AJ (2004) Nature 428:630
Nakagawa N, Hwang HY, Muller DA (2006) Nature Mater 5:204
Hamann DR, Muller DA, Hwang HY (2006) Phys Rev B 73:195403
Huijben M, Rijnders G, Blank DHA, Bals S, van Aert S, Verbeeck J, van Tendeloo G, Brinkman A, Hilgenkamp H (2006) Nature Mater 5:556
Yunoki S, Moreo A, Dagotto E, Okamoto S, Kancharla SS, Fujimori A (2007) Phys Rev B 76:064532
Smadici S, Abbamonte P, Bhattacharya A, Zhai X, Jiang B, Rusydi A, Eckstein JN, Bader SD, Zuo J-M (2007) Phys Rev Lett 99:196404
Chakhalian J, Freeland JW, Habermeier H-U, Cristiani G, Khaliullin G, van Veenendaal M, Keimer B (2007) Science 318:1114
Hotta Y, Susaki T, Hwang HY (2007) Phys Rev Lett 99:236805
Cen C, Thiel S, Hammerl G, Schneider CW, Andersen KE, Hellberg CS, Mannhart J, Levy J (2008) Nature Mater 7:298
Okamoto S, Maier ThA (2008) Phys Rev Lett 101:156401
Gozar A, Logvenov G, Fitting Kourkoutis L, Bollinger AT, Giannuzzi LA, Muller DA, Bozovic I (2008) Nature 455:782
Pentcheva R, Pickett W (2008) Phys Rev B 78:205106
Caviglia AD, Gariglio S, Reyren N, Jaccard D, Schneider T, Gabay M, Thiel S, Hammerl G, Mannhart J, Triscone J-M (2008) Nature 456:624
Popovic ZS, Satpathy S, Martin RM (2008) Phys Rev Lett 101:256801
Levy A, Falck JP, Kastner MA, Gallagher WJ, Gupta A, Kleinsasser AW (1991) J Appl Phys 69:4439
Mannhart J, Schlom DG, Bednorz JG, Muller KA (1991) Phys Rev Lett 67:2099
Xi XX, Doughty C, Walkenhorst A, Kwon C, Li Q, Venkatesan T (1992) Phys Rev Lett 68:1240
Atalla MM, Soshea RW (1963) Solid-State Electron 6:245
Suzuki H, Yamamoto T, Suzuki S, Iyori M, Takahashi K, Usuki T, Yoshisato Y, Nakano S (1993) Jpn J Appl Phys 32:783
Toda F, Abe H, Ogiwara M (1993) IEEE Electron Device Lett 14:100
Yamamoto T, Suzuki S, Suzuki H, Kawaugchi K, Takahashi K, Yoshisato Y (1997) Jpn J Appl Phys 36:L390
Yamamoto T, Suzuki S, Kawaguchi K, Takahashi K (1998) Jpn J Appl Phys 37:4737
Tamura H, Yoshida A, Gotoh K, Hasuo S, Van Duzer T (1991) IEEE Trans Magn 27:2594
Yoshida A, Tamura H, Gotoh K, Takauchi H, Hasuo S (1991) J Appl Phys 70:4976
Blom PWM, Wolf RM, Cillessen JFM, Krijn MPCM (1994) Phys Rev Lett 73:2107
Watanabe Y (1998) Phys Rev B 57:R5563; (1999) Phys Rev B 59:11257
Watanabe Y, Okano M (2001) Appl Phys Lett 78:1906
Sze SM (1981) Physics of semiconductor devices, 2nd edn. Wiley, New York
Brillson LJ (1982) Surf Sci Rep 2:123
Rhoderick EH, Williams RH (1988) Metal–semiconductor contacts, 2nd edn. Clarendon, Oxford
Tung R (2001) Mater Sci Eng R 35:1
Kurtin S, McGill TC, Mead CA (1969) Phys Rev Lett 22:1433
Bardeen J (1947) Phys Rev 71:717
Heine V (1965) Phys Rev 138:A1689
Spicer WE, Chye PW, Skeath PR, Su CY, Lindau I (1979) J Vac Sci Technol 16:1422
Hasegawa H, Ohno H (1986) J Vac Sci Technol B 4:1068
Tung R (2000) Phys Rev Lett 84:6078
Padovani FA, Stratton R (1966) Solid-State Electron 9:695
Fonash SJ (1983) J Appl Phys 54:1966
Margaritondo G, Rowe JE, Christman SB (1976) Phys Rev B 14:5396
Hecht MH (1990) Phys Rev B 41:7918
Fowler RH (1931) Phys Rev 38:45
Crowell CR, Sze SM, Spitzer WG (1964) Appl Phys Lett 4:91
Sze SM, Moll JL, Sugano T (1964) Solid-State Electron 7:509
Dalal VL (1971) J App Phys 42:2274
Noland JA (1954) Phys Rev 94:724
Tufte ON, Chapman PW (1967) Phys Rev 155:796
Frederikse HPR, Hosler WR (1967) Phys Rev 161:822
Lee C, Yahia J, Brebner JL (1971) Phys Rev B 3:2525
Müller KA, Burkard H (1979) Phys Rev B 19:3593
Sawaguchi E, Kikuchi A, Kodera Y (1962) J Phys Soc Jpn 17:1666
Saifi MA, Cross LE (1970) Phys Rev B 2:677
Carnes JE, Goodman AM (1967) J Appl Phys 38:3091
Hasegawa H, Nishino T (1991) J Appl Phys 69:1501
Naito M, Sato H (1994) Physica C 229:1
Yoshimoto M, Maeda T, Shimozono K, Koinuma H, Shinohara M, Ishiyama O, Ohtani F (1994) Appl Phys Lett 65:3197
Shimizu T, Okushi H (1999) J Appl Phys 85:7244
Inoue A, Izumisawa K, Uwe H (2001) Jpn J Appl Phys 40:3153
Barrett JH (1952) Phys Rev 86:118
Susaki T, Kozuka Y, Tateyama Y, Hwang HY (2007) Phys Rev B 76:155110
Eom CB, Cava RJ, Fleming RM, Phillips JM, van Dover RB, Marshall JH, Hsu JWP, Krajewski JJ, Peck WF, Jr. (1992) Science 258:1766
Hikita Y, Kozuka Y, Susaki T, Takagi H, Hwang HY (2007) Appl Phys Lett 90:143507
Fujii T, Kawasaki M, Sawa A, Kawazoe Y, Akoh H, Tokura Y (2007) Phys Rev B 75:165101
Goodman AM, Perkins DM (1964) J Appl Phys 35:3351
Stoecky B (1980) Appl Phys Lett 36:384
Sroubek Z (1970) Phys Rev B 2:3170
Fang X, Kobayashi T (1999) Appl Phys A 69:S587
Robertson J, Chen CW (1999) Appl Phys Lett 74:1168
Minohara M, Ohkubo I, Kumigashira H, Oshima M (2007) Appl Phys Lett 90:132123
Katsufuji T, Tokura Y (1994) Phys Rev B 50:2704
Miyasaka S, Okuda T, Tokura Y (2000) Phys Rev Lett 85:5388
Urushibara A, Moritomo Y, Arima T, Asamitsu A, Kido G, Tokura Y (1995) Phys Rev B 51:14103
Sawa A, Yamamoto A, Yamada H, Fujii T, Kawasaki M, Matsuno J, Tokura Y (2007) Appl Phys Lett 90:252102
A. Fujimori, A. Ino, J. Matsuno, T. Yoshida, K. Tanaka, T. Mizokawa (2002) J Electron Spectrosc. Relat. Phenom. 124:127
Matsuno J, Fujimori A, Takeda Y, Takano M (2002) Europhys Lett 59:252
Wadati H, Kobayashi D, Kumigashira H, Okazaki K, Mizokawa T, Fujimori A, Horiba K, Oshima M, Hamada N, Lippmaa M, Kawasaki M, Koinuma H (2005) Phys Rev B 71:035108
Hikita Y, Nishikawa M, Yajima T, Hwang HY (2009) Phys Rev B 79:073101
Kozuka Y, Susaki T, Hwang HY (2006) Appl Phys Lett 88:142111
Lee WC, MacDonald AH (2006) Phys Rev B 74:075106
Ruegg A, Pilgram S, Sigrist M (2007) Phys Rev B 75:195117
Tokura Y (ed) (2000) Colossal magnetoresistive oxides Gordon and Breach, New York
Haghiri-Gosnet A-M, Renard J-P (2003) J Phys D: Appl Phys 36:R127
Sugiura M, Uragou K, Noda M, Tachiki M, Kobayashi T (1999) Jpn J Appl Phys 38:2675
Tanaka H, Zhang J, Kawai T (2001) Phys Rev Lett 88:027204
Sun JR, Xiong CM, Zhao TY, Zhang SY, Chen YF, Shen BG (2004) Appl Phys Lett 84:1528
Wang DJ, Xie YW, Xiong CM, Shen BG, Sun JR (2006) Europhys Lett 73:401
Sheng ZG, Song WH, Sun YP, Sun JR, Shen BG (2005) Appl Phys Lett 87:032501
Jin KJ, Lu HB, Zhou QL, Zhao K, Cheng BL, Chen ZH, Zhou YL, Yang GZ (2005) Phys Rev B 71:184428
Matsuno J, Sawa A, Kawasaki M, Tokura Y (2008) Appl Phys Lett 92:122104
Postma FM, Ramaneti R, Banerjee T, Gokcan H, Haq E, Blank DHA, Jansen R, Lodder CJ (2004) J Appl Phys 95:7324
Sawa A, Fujii T, Kawasaki M, Tokura Y (2005) Appl Phys Lett 86:112508
Nakagawa N, Asai M, Mukunoki Y, Susaki T, Hwang HY (2005) Appl Phys Lett 86:082504
Susaki T, Nakagawa N, Hwang HY (2007) Phys Rev B 75:104409
Wang DJ, Sun JR, Lu WM, Xie YW, Liang S, Shen BG (2007) J Phys D: Appl Phys 40:5075
Wang DJ, Sun JR, Xie YW, Lu WM, Liang S, Zhao TY, Shen BG (2007) Appl Phys Lett 91:062503
Chen YF, Ziese M, Esquinazi P (2007) J Appl Phys 101:123906
Ahn CH, Bhattacharya A, Di Ventra M, Eckstein JN, Frisbie CD, Gershenson ME, Goldman AM, Inoue IH, Mannhart J, Millis AJ, Morpurgo AF, Natelson D, Triscone J-M (2006) Rev Mod Phys 78:1185
Katsu H, Tanaka H, Kawai T (2001) J Appl Phys 90:4578
Muraoka Y, Hiroi Z (2003) J Phys Soc Jpn 72:781
Muraoka Y, Yamauchi T, Muramatsu T, Yamaura J, Hiroi Z (2004) J Magn Magn Mater 272–276:448
Muraoka Y, Muramatsu T, Hiroi Z (2005) Thin Solid Films 486:82
Eguchi R, Tsuda S, Kiss T, Chainani A, Muraoka Y, Hiroi Z, Shin S (2007) Phys Rev B 75:073102
Muramatsu T, Muraoka Y, Yamauchi T, Yamaura J, Hiroi Z (2004) J Magn Magn Mater 272–276:e787
Hikita Y, Fitting Kourkoutis L, Susaki T, Muller DA, Takagi H, Hwang HY (2008) Phys Rev B 77:205330
Cao G, Chikara S, Lin XN, Elhami E, Durairaj V, Shlottmann P (2005) Phys Rev B 71:035104
Tsu R, Esaki L (1973) Appl Phys Lett 22:562
Dearnaley G, Steoneham AM, Morgan DV (1970) Rep Prog Phys 33:1129
Pgnia H, Sotnik N (1988) Phys Status Solidi a108:11
Liu SQ, Wu NJ, Ignatiev A (2000) Appl Phys Lett 76:2749
Beck A, Bednorz JG, Gerber Ch, Rossel C, Widmer D (2000) Appl Phys Lett 77:139
Sawa A (2008) Mater Today 11:28
Kato H, Kudo A (2003) Catal Today 78:561
Diamant Y, Chappel S, Chen SG, Melamed O, Zaban A (2004) Coord Chem Rev 248:1271
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Hikita, Y., Hwang, H.Y. (2010). Complex Oxide Schottky Junctions. In: Ramanathan, S. (eds) Thin Film Metal-Oxides. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-0664-9_5
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