Skip to main content

Crevice Corrosion and Pitting

  • Chapter
  • First Online:
Introduction to Corrosion Science

Abstract

Passive films, which were studied in the previous chapter, are remarkable in their ability to provide corrosion protection to a wide variety of metals and alloys. However, passive films are not perfect and often suffer localized breakdown at certain specific areas. Although the remainder of the passive film may remain intact and continue to offer protection against general corrosion, the occurrence of localized corrosion is dangerous because it is concentrated at a fixed area and can lead to catastrophic failure of the metal piece. In addition, the presence of localized corrosion is usually more difficult to detect than general corrosion.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 109.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 139.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. F. J. Martin, K. E. Lucas, and E. A. Hogan, Rev. Sci. Instruments, 73, 1273 (2002).

    Article  CAS  Google Scholar 

  2. I. L. Rosenfeld and I. K. Marshakov, Corrosion, 20, 115t (1964).

    Google Scholar 

  3. I. B. Ulanovski and Y. M. Korovin, J. Appl. Chem. USSR, 35, 1683 (1962).

    Google Scholar 

  4. E. McCafferty, J. Electrochem. Soc., 121, 1007 (1974).

    Article  CAS  Google Scholar 

  5. M. H. Peterson, T. J. Lennox, Jr., and R. E. Groover, Mater. Protect. Perform., 9 (1), 23 (1970).

    CAS  Google Scholar 

  6. A. Turnbull, Corros. Sci., 23, 833 (1983).

    Article  CAS  Google Scholar 

  7. F. D. Bogar and C. T. Fujii, Solution Chemistry in Crevices on Fe-Cr Binary Alloys, NRL Report 7690, Naval Research Laboratory, Washington, DC, March 21, 1974

    Google Scholar 

  8. I. L. Rosenfeld in Localized Corrosion, R. W. Staehle, B. F. Brown, J. Kruger, and A. Agrawal, Eds., p. 373, National Association of Corrosion Engineers, Houston, TX (1974).

    Google Scholar 

  9. T. Suzuki, M. Yamabe, and Y. Kitamura, Corrosion, 29, 18 (1973).

    CAS  Google Scholar 

  10. J. Mankowski and Z. Szkarlarska-Smialowska, Corros. Sci., 15, 493 (1975).

    Article  CAS  Google Scholar 

  11. M. G. Fontana and N. D. Greene, Corrosion Engineering, p. 43, McGraw-Hill, New York (1978).

    Google Scholar 

  12. R. M. Kain, J. Testing Evaluation, 18, 309 (1990).

    Article  CAS  Google Scholar 

  13. E. McCafferty, J. Electrochem. Soc., 126, 385 (1979).

    Article  CAS  Google Scholar 

  14. Standard Test Method G-48-97, 1998 Annual Book of ASTM Standards”, ASTM, West Conshohocken, PA (1998).

    Google Scholar 

  15. K. Sotoudeh, T. H. Nguyen, R. T. Foley, and B. F. Brown, Corrosion, 37, 358 (1981).

    Article  CAS  Google Scholar 

  16. E. McCafferty, F. D. Bogar, E. D. Thomas, C. A. Creegan, K. E. Lucas, and A. I. Kaznoff, Corrosion, 53, 755 (1997).

    Article  CAS  Google Scholar 

  17. R. S. Lillard, M. P. Jurinski, and J. R. Scully, Corrosion, 50, 251 (1994).

    Article  CAS  Google Scholar 

  18. O. B. Ellis and F. L. LaQue, Corrosion, 7, 362 (1951).

    CAS  Google Scholar 

  19. T. J. Lennox, Jr. and M. H. Peterson in “Localized Corrosion”, R. W. Staehle et al., Eds., p. 173, National Association of Corrosion Engineers, Houston, TX (1974).

    Google Scholar 

  20. V. R. Pludek, “Design and Corrosion Control”, p. 173, John Wiley and Sons, New York, NY (1977).

    Google Scholar 

  21. A. J. Sedriks, “Corrosion of Stainless Steels”, p. 201, Wiley-Interscience, New York (1996).

    Google Scholar 

  22. E. McCafferty, P. P. Trazskoma, and P. M. Natishan in “Advances in Localized Corrosion”, H. S. Isaacs, U. Bertocci, J. Kruger, and S. Smialowska, Eds., p. 181, National Association of Corrosion Engineers, Houston, TX (1990).

    Google Scholar 

  23. J. R. Galvele in “Passivity of Metals”, R. P. Frankenthal and J. Kruger, Eds., p. 285, The Electrochemical Society, Princeton, NJ (1978).

    Google Scholar 

  24. H. P. Leckie and H. H. Uhlig, J. Electrochem. Soc., 113, 1262 (1966).

    Article  CAS  Google Scholar 

  25. R. E. Groover, T. J. Lennox, Jr., and M. H. Peterson, Mater. Protect., 8 (11), 25 (1969).

    Google Scholar 

  26. Z. A. Foroulis and M. J. Thubrikar, J. Electrochem. Soc., 122, 1296 (1975).

    Article  CAS  Google Scholar 

  27. H. Böhni and H. H. Uhlig, J. Electrochem. Soc., 116, 906 (1969).

    Article  Google Scholar 

  28. S. Szklarska-Smialowski in “Advances in Localized Corrosion”, H. S. Isaacs, U. Bertocci, J. Kruger, and S. Smialowska, Eds., p. 41, National Association of Corrosion Engineers, Houston, TX (1990).

    Google Scholar 

  29. H.-H. Strehblow, Werkstoffe u. Korros., 27, 792 (1976).

    Article  CAS  Google Scholar 

  30. G. S. Frankel, J. Electrochem. Soc., 145, 2186 (1998).

    Article  CAS  Google Scholar 

  31. P. M. Natishan, W. E. O'Grady, E. McCafferty, D. E. Ramaker, K. Pandya, and A. Russell, J. Electrochem. Soc., 146, 1737 (1999).

    Article  CAS  Google Scholar 

  32. L. A. Krebs and J. Kruger in “Passivity of Metals and Semiconductors”, M. B. Ives, J. L. Luo, and J. R. Rodda, Eds., p. 561, The Electrochemical Society, Pennington, NJ (2001).

    Google Scholar 

  33. D. D. Macdonald, J. Electrochem. Soc., 139, 3434 (1992).

    Article  CAS  Google Scholar 

  34. J. O'M. Bockris and L. V. Minevski, J. Electroanal. Chem., 349, 375 (1993).

    Article  CAS  Google Scholar 

  35. J. O'M. Bockris and Y. K. Kang, J. Solid State Electrochem., 1, 17 (1997).

    Article  CAS  Google Scholar 

  36. T. H. Nguyen and R. T. Foley, J. Electrochem. Soc., 127, 2563 (1980).

    Article  CAS  Google Scholar 

  37. S. Yu, W. E. O'Grady, D. E. Ramaker, and P. M. Natishan, J. Electrochem. Soc., 147, 2952 (2000).

    Article  CAS  Google Scholar 

  38. W. Khalil, S. Haupt, and H.-H. Strehblow, Werkstoffe u. Korros., 36, 16 (1985)

    Article  CAS  Google Scholar 

  39. N. Sato, Electrochim. Acta, 16, 1683 (1971).

    Article  CAS  Google Scholar 

  40. W. A. Badawy, M. M. Ibrahim, M. M. Abou-Romia, and M. S. El-Bosiouny, Corrosion, 42, 324 (1986).

    Article  CAS  Google Scholar 

  41. I. L. Rosenfeld in “Proceedings of the Fifth International Congress on Metallic Corrosion”, p. 53, NACE, Houston, TX (1974).

    Google Scholar 

  42. G. Butler, P. Stretton, and J. G. Beynon, Br. Corros. J., 7, 168 (1972).

    Article  CAS  Google Scholar 

  43. B. E. Wilde and E. Williams, Electrochim. Acta., 16, 1971 (1971).

    Article  CAS  Google Scholar 

  44. N. Pessall and C. Liu, Electrochim. Acta, 16, 1987 (1971).

    Article  Google Scholar 

  45. G. S. Frankel, L. Stockert, F. Hunkeler, and H. Boehni, Corrosion, 43, 429 (1987).

    Article  CAS  Google Scholar 

  46. I. L. Rosenfeld, I. S. Danilov, and R. N. Oranskaya, J. Electrochem. Soc., 125, 1729 (1978).

    Article  CAS  Google Scholar 

  47. D. A. Jones and B. E. Wilde, Corros. Sci., 18, 631 (1978)

    Article  CAS  Google Scholar 

  48. T. Hakkarainen in Proceedings of the Eighth International Congress on Metallic Corrosion, Vol. 1, p. 157, DECHEMA, Frankfurt am Main, (1981).

    Google Scholar 

  49. R. C. Newman and H. S. Isaacs in “Passivity of Metals and Semiconductors”, M. Froment, Ed., p. 269, Amsterdam (1983).

    Google Scholar 

  50. E. McCafferty and N. Hackerman, J. Electrochem. Soc. 119, 999 (1972).

    Article  CAS  Google Scholar 

  51. M. Pourbaix, Corros. Sci., 12, 161 (1970).

    Article  Google Scholar 

  52. M. Pourbaix in “Localized Corrosion”, R. W. Staehle, B. F. Brown, J. Kruger, and A. Agrawal, Eds., p. 12, National Association of Corrosion Engineers, Houston, TX (1974).

    Google Scholar 

  53. R. A. Bonewitz and E. D. Verinck, Jr., Mater. Perform., 14 (8), 16 (1975).

    CAS  Google Scholar 

  54. K. K. Starr, E. D. Verinck, Jr., and M. Pourbaix, Corrosion, 32, 47 (1976).

    CAS  Google Scholar 

  55. E. D. Verinck, Jr., and M. Pourbaix, Corrosion, 27, 495 (1971).

    Google Scholar 

  56. E. D. Verinck, Jr., K. K. Starr, and J. M. Bowers, Corrosion, 32, 60 (1976).

    Google Scholar 

  57. A. J. Sedriks in “Corrosion of Stainless Steels”, p. 123, Wiley-Interscience, New York (1996).

    Google Scholar 

  58. C. R. Clayton and I. Olejford in “Corrosion Mechanisms in Theory and Practice”, P. Marcus and J. Oudar, Eds, p. 175, Marcel Dekker, New York, NY (1995).

    Google Scholar 

  59. Z. Szklarska-Smialowska and E. Lunarska, Werkstoffe u. Korros., 32, 478 (1981).

    Article  CAS  Google Scholar 

  60. A. J. Sedriks, Intl. Met. Rev., 28, 295 (1983).

    Article  CAS  Google Scholar 

  61. A. J. Sedriks in A. J. Sedriks, “Corrosion of Stainless Steels”, p. 24, Wiley-Interscience, New York (1996).

    Google Scholar 

  62. E. McCafferty and P. G. Moore, J. Electrochem. Soc., 133, 1090 (1986).

    Article  CAS  Google Scholar 

  63. B. Vuillemin, X. Phillipe, R. Oltra, V. Vignal, L. Coudreuse, L. C. Dufour, and E. Finot, Corros. Sci., 45, 1143 (2003).

    Article  CAS  Google Scholar 

  64. M. P. Ryan, D. E. Williams, R. J. Chater, B. M. Hutton, and D. S. McPhail, Nature, 415, 770 (2002).

    Article  CAS  Google Scholar 

  65. K. D. Efird and G. E. Moller, Mater. Perform., 18 (7), 34 (1979).

    CAS  Google Scholar 

  66. R. J. Brigham, Corrosion, 30, 396 (1974).

    CAS  Google Scholar 

  67. E. McCafferty, Corros. Sci., 45, 1421 (2003).

    Article  CAS  Google Scholar 

  68. P. M. Natishan and E. McCafferty, J. Electrochem. Soc., 136, 53 (1989).

    Article  CAS  Google Scholar 

  69. C. J. Lin, R. G. Du, and T. Nguyen, Corrosion, 56, 41 (2000).

    Article  CAS  Google Scholar 

  70. L. Tomcsanyi, K. Varga, I. Bartik, G. Horanyi, and E. Maleczki, Electrochim. Acta, 34, 855 (1989).

    Article  CAS  Google Scholar 

  71. C. B. Bargeron and R. B. Givens, J. Electrochem. Soc., 124, 1845 (1977).

    Article  CAS  Google Scholar 

  72. C. B. Bargeron and R. B. Givens, Corrosion, 36, 618 (1980).

    CAS  Google Scholar 

  73. J. Perkins, J. R. Cummings, and K. J. Graham, J. Electrochem. Soc., 129, 137 (1982).

    Article  CAS  Google Scholar 

  74. W. Hübner and G. Wranglen in “Current Corrosion Research in Scandinavia”, p. 60, Kemian Keskusliitto, Helsinki, Finland (1965).

    Google Scholar 

  75. C. B. Bargeron and R. B. Givens, J. Electrochem. Soc., 127, 2528 (1980).

    Article  CAS  Google Scholar 

  76. B. F. Brown, Corrosion, 26, 249 (1970).

    CAS  Google Scholar 

  77. R. C. Newman, Corros. Sci., 25, 341 (1985).

    Article  CAS  Google Scholar 

  78. M. Pourbaix in “The Theory of Stress Corrosion Cracking in Alloys”, J. C. Scully, Ed., NATO, Brussels, Belgium (1971).

    Google Scholar 

  79. M. Pourbaix in Localized Corrosion”, R. W. Staehle, B. F. Brown, J. Kruger, and A. Agrawal, Eds., p. 12, National Association of Corrosion Engineers, Houston, TX (1974).

    Google Scholar 

  80. D. W. Siitari and R. C. Alkire, J. Electrochem. Soc., 129, 481 (1982).

    Article  CAS  Google Scholar 

  81. N. J. H. Holroyd, G. M. Scamans, and R. Hermann in “Corrosion Chemistry within Pits, Crevices and Cracks”, A. Turnbull, Ed., p. 495, Her Majesty's Stationary Office, London (1987).

    Google Scholar 

  82. J. A. Davis in “Localized Corrosion”, R. W. Staehle, B. F. Brown, J. Kruger, and A. Agrawal, Eds., p. 168, National Association of Corrosion Engineers, Houston, TX (1974).

    Google Scholar 

  83. O. V. Kurov and R. K. Melekhov, Protection Metals, 15, 249 (1979).

    Google Scholar 

  84. T. Hagyard and J. R. Santhipillai, J. Appl. Chem., 9, 323 (1959).

    Article  CAS  Google Scholar 

  85. I. L. Rosenfeld and I. S. Danilov, Corros. Sci., 7, 129 (1967).

    Article  Google Scholar 

  86. H. R. Copson, Trans. Electrochem. Soc., 84, 71 (1943).

    Article  Google Scholar 

  87. H. S. Isaccs in “Localized Corrosion”, R. W. Staehle, B. F. Brown, J. Kruger, and A. Agrawal, Eds., p. 158, National Association of Corrosion Engineers, Houston, TX (1974).

    Google Scholar 

  88. H. S. Isaacs in “Advances in Localized Corrosion”, H. S. Isaacs, U. Bertocci, J. Kruger, and S. Smialowska, Eds., p. 221, National Association of Corrosion Engineers, Houston, TX (1990).

    Google Scholar 

  89. J. P. H. Sukamto, W. H. Smyrl, N. Casillas, M. Al-Odan, P. James, W. Jin, and L. Douglas, Mater. Sci., Eng., A198, 177 (1995).

    Google Scholar 

  90. L. F. Garfias-Mesias and W. H. Smyrl, J. Electrochem. Soc., 146, 2495 (1999).

    Article  CAS  Google Scholar 

  91. P. Leblanc and G. S. Frankel, J. Electrochem. Soc., 149, B239 (2002).

    Article  CAS  Google Scholar 

  92. F. Andreatta, H. Terryn, and J. H. W. de Wit, Electrochim. Acta, 49, 2851 (2004).

    Article  CAS  Google Scholar 

  93. Y. C. Chen and J. R. Stephens, Corrosion, 35, 443 (1979)

    CAS  Google Scholar 

  94. M. G. Alvarez and J. R. Galvele, Corrosion, 32, 285 (1976).

    CAS  Google Scholar 

  95. P. M. Natishan, E. McCafferty, and G. K. Hubler, J. Electrochem. Soc., 135, 321 (1988).

    Article  CAS  Google Scholar 

  96. P. P. Trzaskoma, E. McCafferty, and C. R. Crowe, J. Electrochem. Soc., 130, 1804 (1983).

    Article  CAS  Google Scholar 

  97. H.-H. Strehblow and B. Titze, Corros. Sci., 17, 461 (1977).

    Article  CAS  Google Scholar 

  98. M. G. Alvarez and J. R. Galvele, Corros. Sci., 24, 27 (1984).

    Article  CAS  Google Scholar 

  99. Y. F. Wang , C. R. Clayton, G. K. Hubler, W. H. Lucke, and J. K. Hirvonen, Thin Solid Films, 63, 11 (1978).

    Article  Google Scholar 

  100. J. G. N. Thomas and A. K. Tiller, Br. Corros. J., 7, 256 91972).

    Google Scholar 

  101. G. Cragnolino and J. R. Galvele in “Passivity of Metals”, R. P. Frankenthal and J. Kruger, Eds, p. 1053, The Electrochemical Society, Princeton, NJ (1978).

    Google Scholar 

  102. I. Dugdale and J. B. Cotton, Corros. Sci., 4, 397 (1964).

    Article  CAS  Google Scholar 

  103. C. T. Fujii, “Electrochemical and Chemical Aspects of Localized Corrosion”, Rapport Technique 213, CEBELCOR, Belgium (1974).

    Google Scholar 

  104. A. Pourbaix, Corrosion, 27, 449 (1971).

    CAS  Google Scholar 

  105. C. W. Petersen, G. C. Soltz, and K. Mairs, Corrosion, 30, 366 (1974).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2010 Springer Science+Business Media, LLC

About this chapter

Cite this chapter

McCafferty, E. (2010). Crevice Corrosion and Pitting. In: Introduction to Corrosion Science. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-0455-3_10

Download citation

Publish with us

Policies and ethics