Chapter 2 deals with supercritical fluids and their mixtures. This Chapter consists of two parts: The first is concerned with the structure of the supercritical fluids and their mixtures (2.1–2.3); The second is concerned with the modeling of the physico-chemical properties of supercritical fluids and their mixtures (2.4–2.7).
2.1 On density microheterogeneities in dilute supercritical solutions.
2.2 Why density augmentation occurs in dilute supercritical solutions.
2.3 Fluctuations in dilute binary supercritical mixtures.
2.4 Entrainer effect in supercritical mixtures.
2.5 The solubility of solids in mixtures composed of a supercritical fluid and an entrainer.
2.6 A simple equation for the solubility of a solid in a supercritical fluid cosolvent with a gas or another supercritical fluid.
2.7 Cubic equation of state and local composition mixing rules: correlations and predictions. Application to the solubility of solids in supercritical solvents.
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Ruckenstein, E., Shulgin, I.L. (2009). Supercritical mixtures. In: Thermodynamics of Solutions. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-0440-9_2
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DOI: https://doi.org/10.1007/978-1-4419-0440-9_2
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