Determination of Acid/Base Properties by Temperature Programmed Desorption (TPD) and Adsorption Calorimetry



The characterization of the acidity of zeolites and related materials is of great importance for applications of these materials, particularly in the petrochemical industry and environmental sciences. This chapter provides a comparison of the two most widely used techniques for the study of acid/base properties of zeolites, namely temperature-programmed desorption and adsorption calorimetry. The information needed to perform and interpret these experiments as well as advantages and limitations of these methods are summarized. The curves and data obtained for the two most studied zeolites Y and ZSM-5 are discussed, which can be particularly useful for young researchers in this field.


Acid Site Temperature Programme Desorption Probe Molecule Strong Acid Site Ammonia Adsorption 
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  1. 1.
    Karge HG, Dondur V, Weitkamp J (1991) J Phys Chem 95:283Google Scholar
  2. 2.
    Farneth WE, Gorte RJ (1995) Chem Rev 95:615Google Scholar
  3. 3.
    Auroux A (2002) Top Catal 19:205Google Scholar
  4. 4.
    Auroux A (1997) Top Catal 4:71Google Scholar
  5. 5.
    Bennici S, Auroux A (2009) In: Hargreaves J, Jackson D (eds) Oxides/Oxidation catalysis, Vol 1, Chapter 9, Wiley, Weinheim, p 391Google Scholar
  6. 6.
    Auroux A (2008) Molecular Sieves- Science and technology. Acidity and basicity, vol 6. Springer, Heidelberg, p 45Google Scholar
  7. 7.
    Brunner E (1995) J Mol Struct 355:61Google Scholar
  8. 8.
    Kustov LM (1997) Top Catal 4:131Google Scholar
  9. 9.
    Stöcker M (1996) Micropor Mat 6:235Google Scholar
  10. 10.
    Guimon C, Martinez H (2003) Recent Res Devel Catal 2:81Google Scholar
  11. 11.
    Barthomeuf D (1992) Stud Surf Sci Catal 37:157Google Scholar
  12. 12.
    Paukshtis EA, Yurchenko EN (1983) Russ Chem Rev 52:242Google Scholar
  13. 13.
    Jacobs PA, Beyer HK (1979) J Phys Chem 83:1174Google Scholar
  14. 14.
    Pöppl A, Rudolf T, Michel D (1998) J Am Chem Soc 120:4879Google Scholar
  15. 15.
    Remy MJ, Stanica D, Poncelet G, Feijen EJP, Martens GPJ, JA JPA (1996) J Phys Chem 100:12440Google Scholar
  16. 16.
    Shannon RD, Gardner KH, Staley RH, Bergeret G, Gallezot P, Auroux A (1985) J Phys Chem 89:4778Google Scholar
  17. 17.
    Zecchina A, Spoto G, Bordiga S (2005) Phys Chem Chem Phys 7:1627Google Scholar
  18. 18.
    Shen J, Auroux A (2004) In: Occelli M (ed) Fluid catalytic cracking VI, preparation and characterization of catalysts, Proceedings of the international symposium, New York, 7–11 September 2003, Elsevier, Amsterdam, p 35; Stud Surf Sci Catal 149:35Google Scholar
  19. 19.
    Corma A (1997) Chem Rev 97:2373Google Scholar
  20. 20.
    Falconer JL, Schwarz JA (1983) Catal Rev-Sci Eng 25:141Google Scholar
  21. 21.
    Hunger B, Hoffmann J (1988) J Therm Anal 33:933Google Scholar
  22. 22.
    Dondur V, Karge HG (1987) Surf Sci 189/190:873Google Scholar
  23. 23.
    Karge HG, Dondur V (1990) J Phys Chem 94:765Google Scholar
  24. 24.
    Gorte RJ (1996) Catal Today 28:405Google Scholar
  25. 25.
    Sharma SB, Meyers BL, Chen DT, Miller J, Dumesic JA (1993) Appl Catal A 102:253Google Scholar
  26. 26.
    Cvetanović RJ, Amenomiya Y (1967) Adv Catal 17:103Google Scholar
  27. 27.
    Cvetanović RJ, Amenomiya Y (1972) Catal Rev 6:21Google Scholar
  28. 28.
    Katada N, Niwa M (2004) Catal Surv Asia 8:161Google Scholar
  29. 29.
    Rac V, Rakić V, Gajinov S, Dondur V, Auroux A (2006) J Therm Anal Cal 84:239Google Scholar
  30. 30.
    Bhatia S, Beltramini J, Do DD (1990) Catal Today 7:309Google Scholar
  31. 31.
    Niwa M, Iwamoto M, Segawa K (1986) Bull Chem Soc Jpn 59:3735Google Scholar
  32. 32.
    Niwa M, Katada N, Sawa M, Murakami Y (1995) J Phys Chem 99:8812Google Scholar
  33. 33.
    Gorte RJ (1999) Catal Lett 62:1Google Scholar
  34. 34.
    Katada N, Igi H, Kim J-H, Niwa M (1997) J Phys Chem B 101:5969Google Scholar
  35. 35.
    Joly J-P, Perrard A (2001) Langmuir 17:1538Google Scholar
  36. 36.
    Andersen PJ, Kung HH (1995) Catalysis. Royal Soc Chem 11:441Google Scholar
  37. 37.
    Woolery GL, Kuehl GH, Timken HC, Chester AW (1997) Zeolites 19:288Google Scholar
  38. 38.
    Bagnasco G (1996) J Catal 159:249Google Scholar
  39. 39.
    Igi H, Katada N, Niwa M (1999) In: Tracy MMJ, Marcus BK, Bisher ME, Higgins JB (eds) Proceeding of the 12th International Zeolite Conference, Materials Research Society, Warrendale, p 2643Google Scholar
  40. 40.
    Miyamoto T, Katada N, Kim J-H, Niwa M (1998) J Phys Chem B 102:6738Google Scholar
  41. 41.
    Gaillard F, Abdat M, Joly J-P, Perrard A (2004) Appl Surf Sci 238:91Google Scholar
  42. 42.
    Miessner H, Kosslick H, Lohse U, Parlitz B, Tuan V-A (1993) J Phys Chem 97:9741Google Scholar
  43. 43.
    Trunschke A, Hunger B (2002) Top Catal 19:215Google Scholar
  44. 44.
    Niwa M, Nishikawa S, Katada N (2005) Micropor Mesopor Mater 82:105Google Scholar
  45. 45.
    Derouane EG (1987) Chem Phys Lett 142:200Google Scholar
  46. 46.
    Derouane EG (1998) J Mol Catal A-Chem 134:29Google Scholar
  47. 47.
    Derouane EG, Chang CD (2000) Micropor Mesopor Mater 35–36:425Google Scholar
  48. 48.
    Hunger B, Heuchel M, Clark LA, Snurr RQ (2002) J Phys Chem B 106:3882Google Scholar
  49. 49.
    Biaglow AI, Gittleman C, Gorte RJ, Madon GJ (1991) J Catal 129:88Google Scholar
  50. 50.
    Auroux A, Jin YS, Vedrine JC, Benoist L (1988) Appl Catal 36:323Google Scholar
  51. 51.
    Aboul-Gheit AK, Aboul-Fotouh SM, Abdel-Hamid SM, Aboul-Gheit NAK (2006) Appl Catal A-General 297:102Google Scholar
  52. 52.
    Martin A, Wolf U, Berndt H, Lücke B (1993) Zeolites 13:309Google Scholar
  53. 53.
    Narayanan S, Deshpande K (1996) Appl Catal A-General 135:125Google Scholar
  54. 54.
    Robb GM, Zhang W, Smirniotis PG (1998) Micropor Mesopor Mater 20:307Google Scholar
  55. 55.
    Zhang W, Burckle EC, Smirniotis PG (1999) Micropor Mesopor Mater 33:173Google Scholar
  56. 56.
    Makowski W (2007) Thermochim Acta 454:26Google Scholar
  57. 57.
    Stach H, Lohse U, Thamm H, Schirmer W (1986) Zeolites 6:74Google Scholar
  58. 58.
    Klyachko AL, Brueva TR, Mishin IV, Kapustin GI, Rubinshtein AM (1978) In: Fejes P (ed) Proceedings of the International Symposium of Zeolites, Szeged, Hungary, 11–14 Sept 1978; Acta Phys et Chem Nova Series 24:183Google Scholar
  59. 59.
    Siril PF, Davison AD, Randhawa JK, Brown DR (2007) J Mol Catal A - Chem 267:72Google Scholar
  60. 60.
    Parillo DJ, Gorte RJ (1998) Thermochim Acta 312:125Google Scholar
  61. 61.
    Damjanović Lj, Auroux A (2008) In: Brown M, Gallagher P (eds) The handbook of thermal analysis & calorimetry, Vol 5, Further advances, techniques and applications, Chapter 11, Elsevier, Amsterdam, p 387Google Scholar
  62. 62.
    Chen D, Sharma S, Cardona-Martinez N, Dumesic JA, Bell VA, Hodge GD, Madon RJ (1992) J Catal 136:392Google Scholar
  63. 63.
    Klyachko AL, Brueva TR, Mishin IV, Kapustin GI, Rubinshtein AM (1978) Acta Phys Chem 24:183Google Scholar
  64. 64.
    Auroux A, Huang M, Kaliaguine S (1996) Langmuir 12:4803Google Scholar
  65. 65.
    Ferino I, Monaci R, Rombi E, Solinas V (1998) J Chem Soc Faraday Trans 94:2647Google Scholar
  66. 66.
    Kapustin GI, Brueva TR, Klyachko AL, Rubinshtein AM (1981) Kinet Katal 22:1247Google Scholar
  67. 67.
    Brueva TR, Kapustin GI, Mishin IV (2001) Thermochim Acta 379:35Google Scholar
  68. 68.
    Auroux A (1994) In: Imelik B, Vedrine JC (eds) Catalyst characterization: physical techniques for solid materials. Plenum Press, New York, p 611Google Scholar
  69. 69.
    Chen DT, Zhang L, Yi C, Dumesic JA (1994) J Catal 146:257Google Scholar
  70. 70.
    Siperstein F, Gorte RJ, Myers AL (1999) Langmuir 15:1570Google Scholar
  71. 71.
    Dunne JA, Rao M, Sircar S, Gorte RJ, Myers AL (1997) Langmuir 13:4333Google Scholar
  72. 72.
    Brown DR, Groszek AJ (2000) Langmuir 16:4207Google Scholar
  73. 73.
    Groszek AJ (1998) Thermochim Acta 312:133Google Scholar
  74. 74.
    Aguayo AT, Gayubo AG, Erena J, Olazar M, Arandes JM, Bilbao J (1994) J Chem Tech Biotechnol 60:141Google Scholar
  75. 75.
    MYu S, VYu B (1999) Kinet Catal 40:819Google Scholar
  76. 76.
    Groszek AJ (1999) In: Dabrowski A (ed) Adsorption and its application in industry and environmental protection, Elsevier, Amsterdam, 1999, p 143; Stud Surf Sci Catal 120A:143Google Scholar
  77. 77.
    Zajac J, Dutartre R, Jones DJ, Rozière J (2001) Thermochim Acta 379:123Google Scholar
  78. 78.
    Drago RS, Dias SC, Torrealba M, de Lima L (1997) J Am Chem Soc 119:4444Google Scholar
  79. 79.
    Drago RS, Dias SC, Mc Gilvray JM, Mateus ALML (1998) J Phys Chem B 102:1508Google Scholar
  80. 80.
    Savitz S, Myers AL, Gorte RJ, White D (1998) J Am Chem Soc 120:5701Google Scholar
  81. 81.
    Savitz S, Myers AL, Gorte RJ, White D (1999) Micropor Mesopor Mater 31:211Google Scholar
  82. 82.
    De Macedo JL, Dias SCL, Dias JA (2004) Micropor Mesopor Mater 72:119Google Scholar
  83. 83.
    Silvestre-Albero J, Sepulveda-Escribano A, Rodriguez-Reinoso F (2002) In: Rodriguez-Reinoso F, McEnaney B, Rouquerol J, Unger KK (eds), Proceedings of the 6th International Symposium on the Characterization of Porous Solids (COPS-VI), Alicante, Spain, 8–11 May 2002, Elsevier, Amsterdam, 2002, p 107; Stud Surf Sci Catal 144:107Google Scholar
  84. 84.
    Coker EN, Karge HG (1997) Rev Sci Instrum 68:4521Google Scholar
  85. 85.
    Klyachko AL, Brueva TR, Rubinshtein AM (1979) Kinet Catal 20:1256Google Scholar
  86. 86.
    Gravelle PC (1972) Adv Catal 22:191Google Scholar
  87. 87.
    Mitani Y, Tsutsumi K, Takahashi H (1986) Colloid Polymer Sci 264:445Google Scholar
  88. 88.
    Biaglow AI, Parrillo DJ, Kokotailo GT, Gorte RJ (1994) J Catal 148:213Google Scholar
  89. 89.
    Parrillo DJ, Lee C, Gorte RJ (1994) Appl Catal A: Gen 110:67Google Scholar
  90. 90.
    Auroux A, Gravelle PC, Védrine JC, Rekas M (1980) In: Rees LVC (ed) Proceedings of the 5th International Zeolite Conference, Naples, Italy, 2–6 June 1980 Heyden, London, p 433Google Scholar
  91. 91.
    Babitz SM, Williams BA, Kuehne MA, Kung HH, Miller JT (1998) Thermochim Acta 312:17Google Scholar
  92. 92.
    Tsutsumi K, Kawai T, Yanagihara T (1994) In: Hattori T, Yashima T (eds) Proceedings of the International Symposium on Zeolites and microporous crystals, Nagoya, Japan, 22–25 August 1993, Elsevier, Amsterdam, p 217; Stud Surf Sci Catal 83:217Google Scholar
  93. 93.
    Khvoshchev SS, Vasil'eva EA (1982) Izvest Akad Nauk SSSR Ser Khim 5:973Google Scholar
  94. 94.
    Guil JM, Guil-López R, Perdigón-Melón JA, Corma A (1998) Micropor Mesopor Mater 22:269Google Scholar
  95. 95.
    Corma A, Chica A, Guil JM, Llopis FJ, Mabilon G, Perdigón- Melón JA, Valencia S (2000) J Catal 189:382Google Scholar
  96. 96.
    Kunkler PJ, Downing RS, van Bekkum H (2001) In: van Bekkum H, Flanigen EM, Jacobs PA, Jansen JC (eds) Introduction to zeolite science and practice, Elsevier, Amsterdam, p 987; Stud Surf Sci Catal 137:987Google Scholar
  97. 97.
    Guil JM, Guil-López R, Perdgón-Melón JA (2000) Stud Surf Sci Catal 130:2927Google Scholar
  98. 98.
    Gorte RJ, White D (2000) Micropor Mesopor Mater 35–36:447Google Scholar
  99. 99.
    Yang L, Trafford K, Kresnawahjuesa O, Sepa J, Gorte RJ, White D (2001) J Phys Chem B 105:1935Google Scholar
  100. 100.
    Yoda E, Kondo JN, Domen K (2005) J Phys Chem B 109:1464Google Scholar
  101. 101.
    Ruthven DM (2001) In: Robson H (ed) Verified syntheses of zeolitic materials. Elsevier, Amsterdam, p 61Google Scholar
  102. 102.
    Mittelmeijer-Hazeleger MC, van der Linden B, Bliek A (1995) J Porous Mater 2:25Google Scholar
  103. 103.
    Makowski W, Kuśtrowski P (2007) Micropor Mesopor Mater 102:283Google Scholar
  104. 104.
    Corma A, Corell C, Pérez-Pariente J, Guil JM, Guil-López R, Nicolopoulos S, Gonzales Calbert J, Vallet-Regi M (1996) Zeolites 16:7Google Scholar
  105. 105.
    Eder F, Lercher JA (1997) J Phys Chem B 101:1273Google Scholar
  106. 106.
    Eder F, Lercher JA (1997) Zeolites 18:75Google Scholar
  107. 107.
    He YJ, Nivarthy GS, Eder F, Seshan K, Lercher JA (1998) Micropor Mesopor Mater 25:207Google Scholar
  108. 108.
    Stach H, Thamm H, Fiedler K, Grauert B, Wieker W, Jahn E, Öhlmann G (1986) In: Murakami Y, Iijima A, Ward JW (eds) New developments in zeolite science and technology; Proceedings of the 7th International Zeolite Conference, Tokyo, Japan, 17–22 August 1986, Elsevier, Amsterdam, Kodansha, Tokyo, p 539; Stud Surf Sci Catal 28:539Google Scholar
  109. 109.
    Pires J, Brotas de Carvalho M, Ramoa Ribeiro F, Derouane E (1989) Appl Catal 53:273Google Scholar
  110. 110.
    Thamm H, Jerschkewitz HG, Stach H (1988) Zeolites 8:151Google Scholar
  111. 111.
    Nieβen W, Karge HG, Jozefowicz L (1992) In: Suzuki M (ed) Proceedings of the 4th international Conference on fundamentals of adsorption, Kyoto, Japan, 17–22 May 1992, Kodansha, Tokyo, 1993, p 475Google Scholar
  112. 112.
    Weber G, Bouvier F, Simonot-Grange MH (1996) In: Proceedings of AFCAT and GEFTA meeting, 24–26 Sept 1996, Freiburg, Germany, p 85, 177Google Scholar
  113. 113.
    Jänchen J, Stach H, Busio M, van Wolput JHMC (1998) Thermochim Acta 312:33Google Scholar
  114. 114.
    Parrillo DJ, Gorte RJ (1993) J Phys Chem 97:8786Google Scholar
  115. 115.
    Parrillo DJ, Lee C, Gorte RJ, White D, Farneth WE (1995) J Phys Chem. 99:8745Google Scholar
  116. 116.
    Lee C, Parrillo DJ, Gorte RJ, Farneth WE (1998) J Am Chem Soc 118:3262Google Scholar
  117. 117.
    Gorte RJ, White D (1997) Top Catal 4:57Google Scholar
  118. 118.
    Knözinger H (1997) In: Ert G, Knözinger H, Weitkamp J (eds) Handbook of heterogenous catalysis, vol 2. VCH, Weinheim, p 707Google Scholar
  119. 119.
    Knözinger H, Huber S (1998) J Chem Soc Faraday Trans 94:2047Google Scholar
  120. 120.
    Webster CE, Drago RS, Zerner MC (1998) J Am Chem Soc 120:5509Google Scholar
  121. 121.
    Boreave A, Auroux A, Guimon C (1997) Micropor Mater 11:275Google Scholar
  122. 122.
    Shete BS, Kamble VS, Gupta NM, Kartha VH (1998) J Phys Chem 102B:5581Google Scholar
  123. 123.
    Kuroda Y, Mori T, Yoshikawa Y, Kittaka S, Kumashiro R, Nagao M (1999) Phys Chem Chem Phys 1:3807Google Scholar
  124. 124.
    Fanson PT, Stradt MW, Lanterback J, Nickolas Delgass W (2002) Appl Catal B: Environ 38:331Google Scholar
  125. 125.
    Shimokanwabe M, Hirano K, Takezawa N (1998) Catal Today 45:117Google Scholar
  126. 126.
    Zhanpeisov NU, Ju WS, Matsouka M, Anpo M (2003) Struct Chem 14:247Google Scholar
  127. 127.
    Solans-Monfort X, Sodupe M, Branchadell V (2003) Chem Phys Lett 368:242Google Scholar
  128. 128.
    Su BL, Norberg V (1998) Langmuir 14:2352Google Scholar
  129. 129.
    Turnes-Palomino G, Fisicaro P, Bordiga S, Zecchina A, Giamello E, Lamberti C (2000) J Phys Chem B 104:4064Google Scholar
  130. 130.
    Sobalik Z, Dedecek J, Ihonnikov I, Wichterlova B (1998) Micropor Mesopor Mater 21:525Google Scholar
  131. 131.
    Wichterlova B, Dedecek J, Sobalik Z, Vondrova A, Klier K (1997) J Catal 169:194Google Scholar
  132. 132.
    Dedecek J, Sobalik Z, Tvarnzkova Z, Kancky D, Wichterlova B (1995) J Phys Chem 99:16327Google Scholar
  133. 133.
    Kuroda Y, Yoshikawa Y, Kumashiro R, Nagao M (1997) J Phys Chem B 101:6497Google Scholar
  134. 134.
    Gervasini A, Picciau C, Auroux A (2000) Micropor Mesopor Mater 35–36:457Google Scholar
  135. 135.
    Olson D, Reischman P (1996) Zeolites 17:434Google Scholar
  136. 136.
    Eder F, Stockenhuber M, Lercher JA (1997) J Phys Chem B 101:5414Google Scholar
  137. 137.
    Millot B, Methivier A, Jobic H (1998) J Phys Chem B 103:3210Google Scholar
  138. 138.
    Makowski W, Majda D (2004) Thermochim Acta 412:131Google Scholar
  139. 139.
    Savitz S, Myers AL, Gorte RJ (2000) Micropor Mesopor Mater 37:33Google Scholar
  140. 140.
    Serykh A, Kazansky V (2004) Phys Chem Chem Phys 6:5250Google Scholar
  141. 141.
    Sepa J, Lee CC, Gorte RJ, White D (1996) In: Hightower JW, Delgass WN, Iglesia E, Bell AT (eds) Proceedings of the 11th congress on catalysis, Baltimore, Maryland, USA, June 30–July 5 1996, PO 144Google Scholar
  142. 142.
    Kotrla J, Kubelková L, Lee CC, Gorte RJ (1998) J Phys Chem B 102:1437Google Scholar
  143. 143.
    Lee CC, Gorte RJ, Farneth WE (1997) J Phys Chem B 101:3811Google Scholar
  144. 144.
    Sepa J, Lee CC, Gorte RJ, White D, Kassab E, Evleth EM, Jessri H, Allavena M (1996) J Phys Chem 100:18515Google Scholar
  145. 145.
    Stach H, Jänchen J (1991) Zeolites 12:152Google Scholar
  146. 146.
    Li J, Davis RJ (2003) Appl Catal A-General 239:59Google Scholar
  147. 147.
    Chen DT, Sharma SB, Filimonov I, Dumesic JA (1992) Catal Lett 12:201Google Scholar
  148. 148.
    Parrillo DJ, Gorte RJ, Farneth WE (1993) J Am Chem Soc 115:12441Google Scholar
  149. 149.
    Parrillo DJ, Gorte RJ (1992) Catal Lett 16:17Google Scholar
  150. 150.
    Auroux A (1988) In: Grobet PJ, Mortier WJ, Vansant EF, Schulz-Ekloff G (eds) Innovation in zeolite materials science, Proceedings of the International Symposium, Nieuwpoort, Belgium, 13–17 September 1987, Elsevier, Amsterdam, 1988, p 385; Stud Surf Sci Catal 37:385Google Scholar
  151. 151.
    Auroux A, Shi ZC, Echoufi N, Ben Taarit Y (1989) In: Karge HG, Weitkamp J (eds) Zeolites as catalysts, sorbents and detergent builders; Proceedings of the International Symposium, Würzburg, Germany, 4–8 September 1988, Elsevier, Amsterdam, 1989, p 377; Stud Surf Sci Catal 46:377Google Scholar
  152. 152.
    Yang S, Navrotsky A (2000) Micropor Mesopor Mater 37:175Google Scholar
  153. 153.
    Moïse JC, Bellat JP, Méthivier A (2001) Micropor Mesopor Mater 43:91Google Scholar
  154. 154.
    Busco C, Barbaglia A, Broyer M, Bolis V, Foddanu GM, Ugliengo P (2004) Thermochim Acta 418:3Google Scholar
  155. 155.
    Gonzalez MR, Sharma SB, Chen DT, Dumesic JA (1993) Catal Lett 18:183Google Scholar
  156. 156.
    Bolis V, Broyer M, Barbaglia A, Busco C, Foddanu GM, Ugliengo P (2003) J Mol Catal A: Chem 204–205:561Google Scholar
  157. 157.
    Takaishi T, Tsutsumi K, Chuubachi K, Matsumoto A (1998) J Chem Soc. Faraday Trans 94:601Google Scholar
  158. 158.
    Karge HG, Jozefowicz LC (1994) In: Weitkamp J, Karge HG, Pfeifer H, Hölderich W (eds) Zeolites and related microporous materials: State of the art 1994; Proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, 17–22 July 1994, Elsevier, Amsterdam, 1994, p 685; Stud Surf Sci Catal 84:685Google Scholar
  159. 159.
    Spiewak BE, Handy BE, Sharma SB, Dumesic JA (1994) Catal Lett 23:207Google Scholar
  160. 160.
    Kapustin GI, Kustov LM, Glonti GO, Brueva TR, VYu B, Klyachko AL, Rubinshtein AM, Kazanskii VB (1984) Kinet Katal 25:959Google Scholar
  161. 161.
    Tsutsumi K, Mitani Y, Takahashi H (1983) Bull Chem Soc Japan 56:1912Google Scholar
  162. 162.
    Auroux A, Bolis V, Wierzchowski P, Gravelle PC, Védrine JC (1979) JCS Faraday Trans II 75:2544Google Scholar
  163. 163.
    Huang M, Auroux A, Kaliaguine S (1995) Micropor Mat 5:17Google Scholar
  164. 164.
    van Santen RA (1994) In: Jansen JC, Stöcker M, Karge HG, Weitkamp J (eds) Advanced zeolite science and applications, Elsevier, Amsterdam, p 273; Stud Surf Sci Catal 85:273Google Scholar
  165. 165.
    Lohse U, Parlitz B (1989) J Phys Chem 93:3677Google Scholar
  166. 166.
    Stach H, Wendt R, Lohse U, Jänchen J, Spindler H (1988) Catal Today 3:431Google Scholar
  167. 167.
    Mellot CF, Cheetham AK, Harms S, Savitz S, Gorte RJ, Myers AL (1998) Langmuir 14:6728Google Scholar
  168. 168.
    Matsumoto A, Tsutsumi K (1995) J Chem Soc Faraday Trans 91:1707Google Scholar
  169. 169.
    Simonot-Grange M–H, Bertrand O, Pilverdier E, Bellat J–P, Paulin C (1997) J Thermal Anal 48:741Google Scholar
  170. 170.
    Cardona-Martinez N, Dumesic JA (1992) Adv Catal 38:149Google Scholar
  171. 171.
    Lónyi F, Valyon J (2001) Micropor Mesopor Mater 47:293Google Scholar
  172. 172.
    Auroux A, Muscas M, Coster DJ, Fripiat JJ (1994) Catal Lett 28:179Google Scholar
  173. 173.
    Védrine JC, Auroux A, Coudurier G (1984) In: White TE et al. (eds) Catalytic materials, relationship between structure and reactivity. A.C.S. Symposium Series 248, 13:254Google Scholar
  174. 174.
    Védrine JC, Auroux A, Bolis V, Dejaifve P, Naccache C, Wierzchowski P, Derouane EG, van Hoff JCH (1979) J Catal 59:248Google Scholar
  175. 175.
    Jozefowicz LC, Karge HG, Coker EN (1994) J Phys Chem 98:8053Google Scholar
  176. 176.
    Muscas M, Dutel JF, Solinas V, Auroux A, Ben Taarit Y (1996) J Mol Catal A-Chem 106:169Google Scholar
  177. 177.
    Niwa M, Suzuki K, Katada N, Kanougi T, Atoguchi T (2005) J Phys Chem B 109:18749Google Scholar
  178. 178.
    Stach H, Jänchen J, Lohse U (1992) Catal Lett 13:389Google Scholar
  179. 179.
    Stach H, Jänchen J, Jerschkewitz HG, Lohse U, Parlitz B, Hunger M (1992) J Phys Chem 96:8480Google Scholar
  180. 180.
    Barthomeuf D (1988) In: Ward JW (ed) Catalysis 1987, Proceedings of the 10th north american meeting of the catalysis society, San Diego, CA, USA, 17–22 May 1987, Elsevier, Amsterdam, 1988, p 177; Stud Surf Sci Catal 38:177Google Scholar
  181. 181.
    Auroux A, Ben Taarit Y (1987) Thermochim Acta 122:63Google Scholar
  182. 182.
    Williams BA, Babitz SM, Miller JT, Snurr RQ, Kung HH (1999) Appl Catal A: Gen 177:161Google Scholar
  183. 183.
    Barthomeuf D (1990) In: Barthomeuf D, Derouane EG, Hoelderich W (eds) Guidelines for mastering the properties of molecular sieves: relationship between the physicochemical properties of zeolitic systems and their low dimensionality, vol 11. Plenum, New York, p 426Google Scholar
  184. 184.
    Mitani Y, Tsutsumi K, Takahashi H (1983) Bull Chem Soc Jpn 56:1921Google Scholar
  185. 185.
    Mishin IV, Klyachko AL, Brueva TR, Tkachenko OP, Beyer HK (1993) Kinet Catal 34:502Google Scholar
  186. 186.
    Handy BE, Jacobo A, Cardenas Galindo MG, Gonzalez M, Llanos ME, Guzman M, Hernandez F (2002) Top Catal 19:249Google Scholar
  187. 187.
    Delahay G (2004) In: Thibault-Starzyk F (ed) Les Matériaux Micro et Mésoporeux, Caractérisation, EDP sciences. Les Ulis, France, p 234Google Scholar
  188. 188.
    Narayanan S, Sultana A, Le QT, Auroux A (1998) Appl Catal A-Gen 168:373Google Scholar
  189. 189.
    Witzel F, Karge HG, Gutsze A (1992) In: von Ballmoos R, Higgins JB, Treacy MMJ (eds), Proceedings of the 9th international zeolite conference, Montreal, Canada, 5–10 July 1992, Butterworth-Heinemann, Boston, 1993, Vol 2, p 283Google Scholar
  190. 190.
    de Araujo AS, Fernandes VJ Jr, Fernandes GJT (1997) J Therm Anal 49:567Google Scholar
  191. 191.
    Auroux A, Artizzu P, Ferino I, Monaci R, Rombi E, Solinas V (1997) Micropor Mater 11:117Google Scholar
  192. 192.
    Rac V, Rakić V, Gajinov S, Dondur V, Auroux A (2006) J Therm Anal Cal 84:239Google Scholar
  193. 193.
    Viswanadham N, Muralidhar G, Prasada Rao TSR (2004) J Mol Catal A-Chem 223:269Google Scholar
  194. 194.
    Rakic V, Dondur V, Gajinov S, Auroux A (2004) Thermochim Acta 420:51Google Scholar
  195. 195.
    Bolis V, Bordiga S, Turnes Palomino G, Zecchina A, Lamberti C (2001) Thermochim Acta 379:131Google Scholar
  196. 196.
    Kuroda Y, Onishi H, Mori T, Yoshikawa Y, Kumashiro R, Nagao M, Kobayashi H (2002) J Phys Chem B 106:8976Google Scholar
  197. 197.
    Karge HG (2001) In: van Bekkum H, Flanigen EM, Jacobs PA, Jansen JC (eds) Introduction to zeolite science and practice, 2nd edn. Elsevier, Amsterdam, p 707; Stud Surf Sci Catal 137:707Google Scholar
  198. 198.
    Sahoo SK, Viswanadham N, Ray N, Gupta JK, Singh ID (2001) Appl Catal A-Gen 205:1Google Scholar
  199. 199.
    Dejaifve P, Auroux A, Gravelle PC, Védrine JC, Gabelica Z, Derouane EG (1981) J Catal 79:123Google Scholar
  200. 200.
    Uguina MA, Serrano DP, Van Griieken R, Vènes (1993) Appl Catal A 99:85Google Scholar

Copyright information

© Springer Science+Business Media B.V. 2009

Authors and Affiliations

  1. 1.Institut de Recherches sur la Catalyse et l’Environnement de Lyon, UMR 5256 CNRS/Université Lyon1VilleurbanneFrance
  2. 2.University of BelgradeBelgradeSerbia

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