Skip to main content

Effect of Stress on the Fire Reaction Properties of Polymer Composite Laminates

  • Conference paper
Engineering Against Fracture

Abstract

A small-scale loading frame was used to apply tensile and compressive stresses to glass vinyl ester and glass polyester laminates in a cone calorimeter under a heat flux of 75kW m−2. It was found, for the first time, that stress has a small but significant effect on the fire reaction properties. Increasing tensile stress increased heat release rate and smoke production, while shortening the time-to-ignition. Compressive stress had the reverse effect. This was attributed to the fact that tensile stress promotes the formation of matrix microcracks, facilitating the evolution of flammable volatiles. This hypothesis is further supported by the observation that stress has the greatest effect on the early heat and smoke release peaks, with a lower effect on the final ‘run-out’ values.

Stress rupture (time-to-failure) curves were produced for tension and compression. In tension, the behaviour was fibre dominated, with times-to-failure being roughly ten times those in compression. Compressive failure involved resin dominated local fibre kinking, initiated near to the rear face of the specimen. The failure time was determined by a significant proportion of the specimen reaching its glass transition temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. Mouritz AP, Gibson AG. Fire Properties of Polymer Matrix Composites. Springer, Dordrecht, 2006.

    Google Scholar 

  2. Lyon RE, Demario J, Walters RN, Crowley S. Flammability of glass fibre-reinforced polymer composites. In: Proceedings of the 4th International Conference on Composites in Fire, Newcastle upon Tyne, England, 2005.

    Google Scholar 

  3. Mouritz AP, Mathys Z, Gibson AG. Heat release of polymer composites in fire. Composites, Part A 2006; 37:1040–1054.

    Article  Google Scholar 

  4. Koo JH, Muskop F, Venumbaka R, Van Dine R, Spencer B, Sorathia U. Flammability properties of polymer composites for marine applications. In: Proceedings of the 32nd International SAMPE Technical Conference, 5–9 November 2000.

    Google Scholar 

  5. Brown JR, Mathys Z, Reinforcement and matrix effects on the combustion properties of glass reinforced polymer composites. Composites, Part A 1997; 28(7):675–681.

    Article  Google Scholar 

  6. Beeson HD, Hshieh F-Y. Flammability testing of flame-retarded epoxy composites and phenolic composites. Fire and Materials 1997; 21(1):41–49.

    Article  Google Scholar 

  7. Lyon RE. Plastics and rubber. In: C.A. Harper, editor. Chapter 3 in Handbook of Building Materials for Fire Protection. McGraw-Hill, New York, 2004.

    Google Scholar 

  8. Mouritz AP, Mathys Z. Post-fire mechanical properties of marine polymer composites. Composite Structures 1999; 47: 643–653.

    Article  Google Scholar 

  9. Mouritz AP, Mathys Z. Post-fire mechanical properties of glass-reinforced polyester composites. Composites Science and Technology 2001; 61(4):475–490.

    Article  CAS  Google Scholar 

  10. Gibson AG, Wright PNH, Wu Y-S, Mouritz AP, Mathys Z, Gardiner CP. Modelling residual mechanical properties of polymer composites after fire. Plastics, Rubber and Composites 2003; 32(2):81–90.

    Article  CAS  Google Scholar 

  11. Gibson AG, Wright PNH, Wu Y-S, Mouritz AP, Mathys Z, Gardiner CP. The Integrity of polymer composites during and after fire. Journal of Composite Materials 2004; 38(15):1283–1307.

    Article  CAS  Google Scholar 

  12. Bausano J, Boyd S, Lesko J, Case S. Composite lifetime during combined compressive loading and one-sided simulated fire exposure. Composites, Part A: 2005; 37(7):1092–1100.

    Article  Google Scholar 

  13. Easby RC, Feih S, Konstantis C, La Delfa G, Urso Miano V, Elmughrabi A, Mouritz AP, Gibson AG. Failure model for phenolic and polyester pultrusions under load in fire. Plastics, Rubber and Composites 2007; 36(9):379–388.

    Article  CAS  Google Scholar 

  14. Feih S, Mathys Z, Mathys G, Gibson AG, Robinson M, Mouritz AP. Influence of water content on failure of phenolic composites in fire. Polymer Degradation and Stability 2008; 93(2):376–382.

    Article  CAS  Google Scholar 

  15. Gibson AG, Wright PNH, Wu Y-S, Evans JT. Laminate theory analysis of composites under load in fire. Journal of Composite Materials 2006; 40(7):639–658.

    Article  Google Scholar 

  16. Feih S, Mathys Z, Gibson AG, Mouritz AP. Modelling the compression strength of polymer laminates in fire. Composites, Part A 2007; 38(11):2354–2365.

    Article  Google Scholar 

  17. Feih S, Mouritz AP, Mathys Z, Gibson AG. Tensile strength modelling of glass fiber-polymer composites in fire. Journal of Composite Materials 2007; 41(19):2387–2410.

    Article  CAS  Google Scholar 

  18. Feih S, Mathys Z, Gibson AG, Mouritz AP. Modelling the tension and compression strengths of polymer laminates in fire. Composites Science and Technology 2007; 67(3–4):551–564.

    Article  CAS  Google Scholar 

  19. Babrauskas V. Development of the Cone Calorimeter: A Bench Scale Heat Release Rate Apparatus Based on Oxygen Consumption (NBSIR 82-2611), USA. National Bureau of Standards, 1982.

    Google Scholar 

  20. Babrauskas V, Peacock RD. Heat release rate: the single most important variable in fire hazard. Fire Safety Journal 1992; 18:255–272.

    Article  CAS  Google Scholar 

  21. Huggett C Estimation of rate of heat release by means of oxygen consumption measurements. Fire and Materials 1980; 4:61–65.

    Article  CAS  Google Scholar 

  22. Henderson JB, Wiecek TE. A mathematical model to predict the thermal response of decomposing expanding polymer composites. Journal of Composite Materials 1987; 21:373–393.

    Article  CAS  Google Scholar 

  23. Henderson JB, Wiebelt JA, Tant MR. A model for the thermal response of polymer composite materials with experimental verification. Journal of Composite Materials 1995; 19:579–594.

    Article  Google Scholar 

  24. Gibson AG, Wu Y-S, Chandler HW, Wilcox JAD, Bettess P. A model for the thermal performance of thick composite laminates in hydrocarbon fires. Revue de l’Institut FranÇais du Pétrole 1995; 50(1):69–74.

    CAS  Google Scholar 

  25. Dodds N, Gibson AG, Dewhurst D, Davies JM. Fire behaviour of composite laminates. Composites, Part A 2000; 31(7):689–702.

    Article  Google Scholar 

  26. Lua J, O’Brien J, Key C, Wu Y-S, Lattimer B. A temperature and mass dependent thermal model for fire response prediction of marine composites. Composites, Part A 2006; 37(7):1024–1039.

    Article  Google Scholar 

  27. Liu L, Kardomateas GA, Simitses GJ, Li R. Response of a sandwich panel subject to fire or elevated temperature on one of the surfaces. Composites, Part A 2006; 37(7):981–988.

    Article  CAS  Google Scholar 

  28. Liu L, Kardomateas GA, Birman V, Holmes JW, Simitses GJ. Thermal buckling/bending of a heat-exposed, axially restrained composite column. Composites, Part A 2006; 37(7):981–988.

    Article  CAS  Google Scholar 

  29. Budiansky B, Fleck N. Compressive failure of fiber composites, Journal of the Mechanics and Physics of Solids, 1993; 41:183–211.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. G. Gibson .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2009 Springer Science+Business Media B.V

About this paper

Cite this paper

Elmughrabi, A.E., Robinson, A.M., Gibson, A.G. (2009). Effect of Stress on the Fire Reaction Properties of Polymer Composite Laminates. In: Pantelakis, S., Rodopoulos, C. (eds) Engineering Against Fracture. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-9402-6_12

Download citation

Publish with us

Policies and ethics