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Ruthenium Oxidation Complexes pp 135–172Cite as

Oxidation of Alcohols, Carbohydrates and Diols

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Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 34))

Abstract

This is one of the most important classes of oxidation effected by Ru complexes, particularly by RuO4, [RuO4]−, [RuO4]2− and RuCl2(PPh3)3, though in fact most Ru oxidants effect these transformations. The chapter covers oxidation of primary alcohols to aldehydes (section 2.1), and to carboxylic acids (2.2), and of secondary alcohols to ketones (2.3). Oxidation of primary and secondary alcohol functionalities in carbohydrates (sugars) is dealt with in section 2.4, then oxidation of diols and polyols to lactones and acids (2.5). Finally there is a short section on miscellaneous alcohol oxidations in section 2.6.

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Notes

  1. 1.

    As indicated in 1.2.2 these abbreviations take the form: Ru starting material/co-oxidant/solvent; temperatures are only indicated if not ambient. For brevity, RuO2 and RuCl3 denote the hydrates RuO2.nH 2O and RuCl3.nH2O.

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  1. Department of Chemistry, Imperial College, London, SW7 2AZ, United Kingdom

    Prof. William P. Griffith

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Griffith, W.P. (2009). Oxidation of Alcohols, Carbohydrates and Diols. In: Ruthenium Oxidation Complexes. Catalysis by Metal Complexes, vol 34. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-9378-4_2

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