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Physicochemical Aspects of Polymer at~Interfaces

Summary

A discussion of the behavior of polymers at interfaces where the Langmuir monolayers and Langmuir–Blodgett films are studied. Amphiphilic polymers at the air–water interface are studied through the Langmuir technique. The study and discussion of surface pressure-area isotherms for different polymers are performed by using a surface film balance and the results obtained from this technique are analyzed in terms of the shape of the isotherms. The collapse pressure for different systems is discussed in terms of the chemical structure of the polymer. The adsorption of polymers by spreading and from solution is also discussed. Wetting of solids by a liquid described in terms of the equilibrium contact angle $\uptheta$. At the appropriate interfacial tensions in the equilibrium the forces acting are analyzed using the Young’s equation.

Interface Langmuir monolayer Adsorption process Spreading solvent Surface tension Surface isotherm Langmuir–Blodgett film Collapse pressure Amphiphilic polymer 

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References

  1. 1.
    E.D. Goddard, and B. Vincent (Eds), Polymer Adsorption and Dispersion Stability; Am. Chem., Sec. Symps, Series 240, 227 (1984)Google Scholar
  2. 2.
    D.H. Napper, “Polymeric Stabilization of Colloidal Dispersion”, Academic Press, London (1983)Google Scholar
  3. 3.
    A. Leiva, A. Farias, L. Gargallo, D. Radić, Eur. Polym. J., 44, 2589 (2008)Google Scholar
  4. 4.
    R.Jones, R. Richards, “Polymers at Surfaces and Interfaces”, Cambridge University Press (1999)Google Scholar
  5. 5.
    T. Maruyama, J. Langer, G.G. Fuller, C.W. Frank, C.R. Robertson, Langmuir, 14, 1836 (1998)Google Scholar
  6. 6.
    A. Leiva, L. Gargallo, D. Radić, J. Macromol. Sci. Part A: Pure Appl. Chem. 41 (5), 577 (2004)Google Scholar
  7. 7.
    A. Asnacias, D. Langevin, F.J. Argillier, Macromolecules, 29, 23, 7412 (1999)Google Scholar
  8. 8.
    P.F. Luckham, “Polymer Surfaces and Interfaces”, W. J-Feast and H.S. Munro, John Wiley and Sons Ltd (1987)Google Scholar
  9. 9.
    L. Gargallo, D. Radić, Curr. Trends Polym. Sci., 6, 121–133 (2001)Google Scholar
  10. 10.
    G.J. Fleer, J.M.H.M. Scheutjens, Adv. Colloid Interface Sci., 16, 341 (1982)Google Scholar
  11. 11.
    A.W. Adamson, A.P. Gast, “Physical Chemistry of Surfaces” 6th Ed. Wiley Interscience, New York 1997Google Scholar
  12. 12.
    F.J. Holly, M.F. Refojo, J. Biomed. Mater. Res. 9, 315 (1975)Google Scholar
  13. 13.
    B.D. Ratner, J. Appl. Polym. Sci. 22, 643 (1978)Google Scholar
  14. 14.
    B.D. Ratner; in “Biomaterials: Interfacial Phenomena and Applications” Cooper and Peppas, Eds., ACS Advances in Chemistry Series Vol. 199. Washington, DC, (1982)Google Scholar
  15. 15.
    L. Lavielle, J. Schultz, J. Colloid Interface Sci. 106, 438 (1985)Google Scholar
  16. 16.
    J.D. Andrade, D.E. Gregonis and L.M. Smith in “Physicochemical Aspects of Polymer Surfaces”, K.L. Mittal, Ed. Vol. 2, p. 911 Plenum, New York (1983)Google Scholar
  17. 17.
    E. Ruckenstein, S.V. Gourisankar, J. Colloid Interface Sci. 109, 557 (1985)Google Scholar
  18. 18.
    S.H. Le, E. Ruckenstein, J. Colloid Interface Sci. 117, 172 (1987)Google Scholar
  19. 19.
    D.T. Clark, A. Dilka, D. Shuttleworth, in “Polymer Surfaces”, D.T. Clark and W.J. Feast, Eds. P. 185. Wiley, New York (1978)Google Scholar
  20. 20.
    H. Yasuda, H.C. Marsh, S. Brandt and C.N. Reilley, J. Polym. Sci. Polym. Chem. Ed. 15, 991 (1977)Google Scholar
  21. 21.
    A. Baszkin, M. Nishino, L. Ter-Minassian-Saraga, J. Colloid. Interface Sci. 59, 516 (1977)Google Scholar
  22. 22.
    B.D. Ratner, in “Polymer Science and Technology “, Lee, Ed. Vol. 12B p. 691. Plenum, New York (1980)Google Scholar
  23. 23.
    A. Leiva, M. Urzua, L. Gargallo and D. Radić, J. Colloid Interface Sci. 299, 70 (2006)Google Scholar
  24. 24.
    B. Miranda, L. Gargallo, A. Leiva, M. Urzùa, F. Gonzàlez-Nilo, D. Radić, Polymer, 44, 3969 (2003)Google Scholar
  25. 25.
    S.H. Lee, E. Ruckenstein, J. Colloid Interface Sci. 120, 529 (1987)Google Scholar
  26. 26.
    A. Dilks., Anal. Chem., 53, 802A (1981)Google Scholar
  27. 27.
    D. Clark, W. Feast, Polym. Surf., Wiley, New York (1978)Google Scholar
  28. 28.
    S.L., Regen, P. Kirszensztejn, A. Singh, Macromolecules, 16, 335 (1983)Google Scholar
  29. 29.
    R.J. Vig, J. Vac. Sci. Tech., A3, 1027 (1985)Google Scholar
  30. 30.
    R. Foerch, N.S. McIntyre, D.H. Hunter, J. Polym. Sci. Part A. Polym. Chem., 28, 803 (1990)Google Scholar
  31. 31.
    G. Gillberg, J. Adhesion, 21, 129 (1987)Google Scholar
  32. 32.
    F. MacRitchie, J. Colloid Interface Sci., 105, 1, 119 (1985)Google Scholar
  33. 33.
    I. Langmuir, D.F., Waugh, J. Am. Chem. Soc., 62, 2771 (1940)Google Scholar
  34. 34.
    G. Gonzàlez, F. MacRitchie, J. Colloid Interface Sci., 32, 55 (1970)Google Scholar
  35. 35.
    F. MacRitchie and L. Ter-Minassian-Saraga, Colloids Surf., 10, 53 (1984)Google Scholar
  36. 36.
    I. Langmuir, Science, 87, 493 (1938)Google Scholar
  37. 37.
    K.B. Blodgett, J. Am. Chem. Soc., 57, 1007 (1935)Google Scholar
  38. 38.
    M.C. Petty, “Langmuir-Blodgett Films”, Cambridge University Press, Cambridge (1996)Google Scholar
  39. 39.
    D. Crisp, in “Surface Phenomena in Chemistry and Biology”, Pergamon, New York (1958)Google Scholar
  40. 40.
    N. Beredjik, in “Newer Methods of Polymer Characterization”, Interscience, New York, (1964)Google Scholar
  41. 41.
    G.L. Gaines, Jr., “Insoluble Monolayers at Liquid – Gas Interfaces, Wiley, New York (1966)Google Scholar
  42. 42.
    G.L. Gaines, Jr., Langmuir, 7, 834 (1991)Google Scholar
  43. 43.
    A. Ulman, “An Introduction to Ultytrathin Organic Films from Langmuir – Blodgett to Self – Assembly”, Academic Press, New York (1991)Google Scholar
  44. 44.
    L. Gargallo, A. Leiva, L. Alegria, B. Miranda, D. Radić, J. Macromol. Sci. Phys., B43, 5, 913 (2004)Google Scholar
  45. 45.
    M. Heskin, J.E. Guillet, J. Macromol. Sci. Chem. 2 (8), 1441 (1968)Google Scholar
  46. 46.
    L. Gargallo, B. Miranda, A Leiva, A. Gonzalez, C. Sandoval, D. Radić, L.H. Tagle, J. Macromol. Sci. PartB: Phys., 45, 105 (2006)Google Scholar
  47. 47.
    J.A. Bergeron, G.L. Gaines, Jr., W.D. Bellamy, J. Colloid Interface Sci. 25, 97 (1967)Google Scholar
  48. 48.
    T. Yamashita, Nature, 231, 445 (1971)Google Scholar
  49. 49.
    G. Gabrielli, M. Pugelli, R. Faccioli, J. Colloid Interface Sci. 37, 213 (1971)Google Scholar
  50. 50.
    G. Gabrielli, A. Maddij, J. Colloid Interface Sci., 64, 19 (1978)Google Scholar
  51. 51.
    M. Kawagushi, S. Komatsu, M. Matsuzumi, A. Takahashi, J. Colloid Interface Sci., 102, 356 (1984)Google Scholar
  52. 52.
    S.Y. Mumby, J.D. Swalen, J.F. Rabolt, Macromolecules, 19, 1054 (1986)Google Scholar
  53. 53.
    J. Kumaki, Macromolecules, 19, 2258 (1986)Google Scholar
  54. 54.
    M.A. Noordegraaf, G.J. Kuiper, A.T.M. Marcelis, E.J.R. Sudholter, Macromol. Chem. Phys. 198, 3681 (1997)Google Scholar
  55. 55.
    F. Davis, P. Hodge, C.R. Towns, Z. Ali-Adib, Macromolecules, 24, 5695 (1991)Google Scholar
  56. 56.
    M.C. Petty, “Polymer Surfaces and Interfaces”, Ed. by W.J. Feast and H.S. Munro, John Willey and Sons, Chichester (1987)Google Scholar
  57. 57.
    K. Gong, S. Feng, M.L. Go, P.H. Soew, Coll. Surf. A: Physiochem. Eng. Aspects 207, 113 (2002)Google Scholar
  58. 58.
    C. Ringard-Lefebvre, A. Baszkin, Langmuir, 10, 2376 (1994)Google Scholar
  59. 59.
    F. Monroy, F. Ortega, R.G. Rubio, Phys. Rev. E, 58, 6, 7629–7641 (1998)Google Scholar
  60. 60.
    F. Monroy, F. Ortega, R.G.Rubio, Eur. Phys. J., B, 13, 745 (2000)Google Scholar
  61. 61.
    P.G. de Gennes, Scaling concepts in Polymer Physics, Cornell University Press, Ithaca, NY (1979)Google Scholar
  62. 62.
    P.G.de Gennes, Phys. Lett, A38, 339 (1972)Google Scholar
  63. 63.
    R. Vilanove, F. Rondelez, Phys. Rev. Lett. 45, 1502 (1980)Google Scholar
  64. 64.
    D.K. Chattoraj, K.S. Birdi, Adsorption and the Gibbs surface excess, Plenum Press, New York (1984)Google Scholar
  65. 65.
    A. Leiva, L. Gargallo, A. Gonzalez, D. Radić, Eur. Polym. J. 40, 2349 (2004)Google Scholar
  66. 66.
    S. Havlin, D. Ben Avraham, Phys. Rev. A 27, 2759 (1983)Google Scholar
  67. 67.
    R. Vilanove, D. Poupinet, F. Rondelez, Macromolecules, 19, 1054 (1986)Google Scholar
  68. 68.
    L. Gargallo, B. Miranda, A. Leiva, D. Radić, Polymer, 46, 824 (2001)Google Scholar
  69. 69.
    L. Gargallo, A. Leiva, M. Urzua, L. Alegria, B. Miranda, D. Radić, Polym. Int., 53, 1652 (2004)Google Scholar
  70. 70.
    L. Gargallo, B. Miranda, A. Leiva, D. Radić, M. Urzua, H. Rios, Polymer, 45, 5145 (2004)Google Scholar
  71. 71.
    I.I. Maleev, N.S. Tsvetkov, I.E. Twardon, Sintez Fiziko-Khim Polim. 16, 111 (1975)Google Scholar
  72. 72.
    P. Baglioni, E. Gallori, G. Gabrielli, C. Ferroni, J. Colloid Interface Sci., 88, 221 (1982)Google Scholar
  73. 73.
    J. Israelachvili, Langmuir, 10, 3774 (1994)Google Scholar
  74. 74.
    Z. Li, W. Zhao, J. Quinn, M.H. Rafailovich, J. Sokolov, R.B. Lennox, A. Eisenberg, X.Z. Wu, M.W. Kim, S.K. Sinha, M. Tolan, Langmuir, 11, 4785 (1995)Google Scholar
  75. 75.
    J. Zhu, A. Eisenberg, R.B. Lennox, Macromolecules, 25, 6547 (1992)Google Scholar
  76. 76.
    C. Chovino, P. Gramain, Macromolecules, 31, 7111 (1998)Google Scholar
  77. 77.
    J.R. Dann, J. Colloid Interface Sci., 32, 302 (1970)Google Scholar
  78. 78.
    P.G. de Gennes, Adv. Colloid Interface Sci., 27, 189 (1987)Google Scholar
  79. 79.
    M. Urzua, L. Gargallo, D. Radić, J. Macromol. Sci. Pure Appl. Chem., A37, 37 (2000)Google Scholar
  80. 80.
    L Gargallo, B. Miranda, H. Rios, F. Gonzalez – Nilo, D. Radić, Polym. Int., 50, 858 (2001)Google Scholar
  81. 81.
    L. Gargallo, B. Miranda, A. Leiva, H. Rios, F. Gonzalez-Nilo, D. Radić, J. Colloid Int. Sci., 271, 181 (2004)Google Scholar
  82. 82.
    M. Kawaguchi, S. Itoh, A. Takahashi, Macromolecules, 20, 1052 (1987)Google Scholar
  83. 83.
    M. Kawagushi, S. Itoh, A. Takahashi, Macromolecules, 21, 1056 (1987)Google Scholar
  84. 84.
    F. Davis, P. Hodge, X.-H. Liu, Z. Ali – Adib, Macromolecules, 27, 1957 (1994)Google Scholar
  85. 85.
    P. Dynarowicz-Latka, A. Dhanabalan, O. Oliveira, J. Phys. Chem. B, 103, 5992–6000 (1999)Google Scholar
  86. 86.
    N.R. Pallas, B.A. Pethica, Langmuir, 1, 509 (1995)Google Scholar
  87. 87.
    J.C. Earnshaw, P.J. Winch, Thin Solid Films, 159, 159 (1988)Google Scholar
  88. 88.
    D.M. Taylor, Y. Dong, C.C. Jones, Thin Solid Films 284, 5, 130 (1996)Google Scholar
  89. 89.
    J. Krägel, G. Kretzchmar, J.B. Li, G. Loglio, R. Miller, Thin Solid Films, 284–285, 361 (1996)Google Scholar
  90. 90.
    R.C.W. Liu, S. Cantin, F. Perrot, F.M. Winnik, Polym. Adv. Technol., 17, 798 (2006)Google Scholar
  91. 91.
    H.G. Schild, Prog. Polym. Sci., 17, 163 (1992)Google Scholar
  92. 92.
    X. Wang, X. Qiu, C. Wu, Macromolecules, 31, 2972 (1998)Google Scholar
  93. 93.
    W. Saito, M. Kawaguchi, T. Kato, T. Imae, Langmuir, 12, 5947 (1996)Google Scholar
  94. 94.
    P. Kujawa, C.C.E. Goh, D. Calvet, F.M. Winnik, Macromolecules, 34, 6387, (2001)Google Scholar
  95. 95.
    P. Kujawa, R.C.W. Liu, F.M. Winnik, J. Phys. Chem. B., 106, 5578 (2002)Google Scholar
  96. 96.
    B.A. Noskov, T.U. Zubkova, J. Colloid Interface Sci., 170, 1 (1995)Google Scholar
  97. 97.
    M. Kawaguchi, Prog. Polym. Sci., 18, 341 (1993)Google Scholar
  98. 98.
    F.C. Goodrich, Proc. R. Soc. London, Ser. A, 374, 341 (1981)Google Scholar
  99. 99.
    H.E. Gaub, H.M. McConnell, J. Phys. Chem., 90, 6830 (1986)Google Scholar
  100. 100.
    B.A. Noskov, Colloid Polym. Sci., 273, 263 (1995)Google Scholar
  101. 101.
    M. Kawaguchi, B.B. Sauer, H. Yu, Macromolecules, 22, 1735 (1989)Google Scholar
  102. 102.
    A. Halperin, M. Tirrell, T.P. Lodge, Adv. Polym. Sci., 100, 31 (1992)Google Scholar
  103. 103.
    K.R. Shull, E.J. Kramer, Macromolecules, 23, 4769 (1990)Google Scholar
  104. 104.
    Z. Tuzar, P. Kratochvil, Adv. Colloid Interfaces Sci., 6, 201 (1976)Google Scholar
  105. 105.
    A. Halperin, Macromolecules, 20, 2943 (1987)Google Scholar
  106. 106.
    A. Johner, J.F. Joanny, Macromolecules, 23, 5299 (1990)Google Scholar
  107. 107.
    J. Zhu, A. Eisenberg, R.B. Lennox, Macromolecules, 25, 6556 (1992)Google Scholar
  108. 108.
    M. Niwa, N. Katsurada, N. Higashi, Macromolecules, 21, 1878 (1988)Google Scholar
  109. 109.
    I. Langmuir, J. Chem. Phys. 1, 756, (1933)Google Scholar
  110. 110.
    S. Li, C.J. Clarke, R.B. Lennox, A. Eisenberg, Colloid Surf. A 133, 191 (1998)Google Scholar
  111. 111.
    Z. Li, W. Zhao, J. Quinn, M.H. Rafailovich, J. Sokolov, R.B. Lennox, A. Eisenberg, X.Z. Wu, M.W. Kim, S.K. Sinha, M. Tolan, Langmuir, 11, 4785 (1995)Google Scholar
  112. 112.
    K. Letchford, H. Burt, Eur. J. Pharm. Biopharm. 65, 259 (2007)Google Scholar
  113. 113.
    A. Halperin, J. Macromol. Sci., Part C: Polym. Rev., 46, 173 (2006)Google Scholar
  114. 114.
    O.V. Borisow, E.B. Zhulina, Macromolecules, 38, 2506 (2005)Google Scholar
  115. 115.
    P.G. de Gennes, Adv. Colloid Interface Sci., 27, 180 (1987)Google Scholar
  116. 116.
    C.M. Marques, J.F. Joanny, Macromolecules, 22, 1454 (1989)Google Scholar
  117. 117.
    J.A. Hubbell, Science 300, 595 (2003)Google Scholar
  118. 118.
    D.J. Pochan, Z. Chen, H. Cui, K. Hales, K. Oi, K.L. Wooley, Science, 306, 94 (2004)Google Scholar
  119. 119.
    R. Mezzenga, J. Ruokolainen, G.H. Fredrickson, E.J. Kramer, D. Moses, A.J. Heeger, O. Ikkala, Science, 299, 1872 (2003)Google Scholar
  120. 120.
    T.P. Russell, Science, 297, 964 (2002)Google Scholar
  121. 121.
    C.A. Devereaux, S.M. Baker, Macromolecules, 35, 1921 (2002)Google Scholar
  122. 122.
    Y. Seo, J.H. Im, J.S. Lee, J.H. Kim, Macromolecules, 34, 4842 (2001)Google Scholar
  123. 123.
    Y. Seo, A.R. Esker, D. Sohn, H.J. Kim, S. Paek, H. Yu, Langmuir, 19, 3313 (2003)Google Scholar
  124. 124.
    Y. Ikada, H. Iwata, S. Nagaoka, F. Horii, J. Macromol. Sci., Phys. B17, 191 (1980)Google Scholar
  125. 125.
    E. Bringuier, R. Vilanova, Y. Gallot, J. Selb, F. Rondelez, J. Colloid Interface Sci., 104, 95 (1985)Google Scholar
  126. 126.
    M. Niwa, T. Hayashi, N. Higashi, Langmuir, 6, 263 (1990)Google Scholar
  127. 127.
    M. Yoshikawa, J.D. Worsfold, T. Matsuura, A. Kimura, T. Shimidzu, Polym. Commun. 31, 414 (1990)Google Scholar
  128. 128.
    J. Kumaki, Macromolecules, 21, 749 (1988)Google Scholar
  129. 129.
    A. Wesemann, H. Ahrens, R. Steitz, S. Föster, C.A. Helm, Langmuir, 19, 709 (2003)Google Scholar
  130. 130.
    S. Yamamoto, Y. Tsujii, K. Yamada, T. Takeshi, T. Miyamoto, Langmuir, 12, 3671 (1996)Google Scholar
  131. 131.
    Y. Kim, J. Pyun, J.M.J. Frechet, C.J. Hawker, C.W. Frank, Langmuir, 21, 10444 (2005)Google Scholar
  132. 132.
    Y. Park, Y-W. Choi, S. Park, C.S. Cho, M.J. Fasolka, D. Sohn, J. Colloid Interf. Sci., 283, 322 (2005)Google Scholar
  133. 133.
    C.S. Cho, J.W. Nah, Y.I. Jeong, J.B. Cheon, S. ASayama, H. Ise, T. Akaike, Polymer, 40, 6769 (1999)Google Scholar
  134. 134.
    H. Yim, M.D. Foster, J. Engelking, H. Menzel, A.M. Ritcey, Langmuir, 16, 9792 (2000)Google Scholar
  135. 135.
    S.Garnier, A. Laschewsky, Langmuir, 22, 4044 (2006)Google Scholar
  136. 136.
    S.Creutz, J. van Stam, F.C. De Schryver, R. Jerome, Macromolecules, 31, 681 (1998)Google Scholar
  137. 137.
    G. Riess, Prog. Polym. Sci., 28, 1107 (2003)Google Scholar
  138. 138.
    J.B. Vieira, R.K. Thomas, Z.X. Li, J. Penfold, Langmuir, 21, 4441 (2005)Google Scholar
  139. 139.
    S. Antoun, J.F. Gohy, R. Jerome, Polymer, 42, 3641 (2001)Google Scholar
  140. 140.
    G. Riess, C. Labbe, Macromol. Rapid. Commun. 25, 401 (2004)Google Scholar
  141. 141.
    T. Rager, W.H. Meyer, G. Wegner, Macromolecules, 30, 4911 (1997)Google Scholar
  142. 142.
    J. Des Cloizeaux, J. Phys. France, 49, 699 (1988)Google Scholar
  143. 143.
    P.G. de Gennes, Macromolecules, 14, 1637 (1981)Google Scholar
  144. 144.
    G.J. Fleer, J.M.H.M. Scheutjens, M.A. Cohen, Stuart. Colloid Surf., 31, 1 (1988)Google Scholar
  145. 145.
    T.C. Patton, “Paint Flow and Pigment Dispersion”, Interscience, New York (1964)Google Scholar
  146. 146.
    D.K. Owens, R.C. Wendt, J. Appl. Polym. Sci. 13, 1741 (1969)Google Scholar
  147. 147.
    D.H. Kaeble, J. Adhes., 2, 50 (1970)Google Scholar
  148. 148.
    R.C. Hayward, A.S. Utada, N. Dan, D.A. Weitz, Langmuir, 22, 4457 (2006)Google Scholar

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