Abstract
A novel class of advanced materials based on the nanometer-scaled heterogeneous metal oxides systems MIO - MIIO (nanocomposites) is discussed regarding gas sensor applications. Recent work focused on developing new types of highly selective sensor materials — complex oxide structure based on SnO2 nanocrystallites coated with catalysts Fe2O3, MoO3, and V2O5. The additives reduce the interactions between the SnO2 crystallites, inhibit the crystallite growth, and therefore stabilize the structure and electrical properties of non-homogeneous nanostructured composite materials. Depending on the molar ratio of their components, each system differs in nanostructure, redox properties, acidity/basicity of the surface. These parameters determine sensing and catalytic properties of the nanocrystalline oxide systems.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
N. Yamazoe, Toward innovations of gas sensor technology, Sens. Actuators B 108, 2–14 (2005)
W. Gopel and K. D. Schierbaum, SnO2 sensors: current status and future prospects, Sens. Actuators B 26–27, 1–12 (1995)
N. Barsan, M. Schweizer-Berberich, and W. Gopel, Fundamental and practical aspects in the design of nanoscaled SnO2 gas sensors: a status report, Fresenius J. Anal. Chem. 365, 287–304 (1999)
K. Takahata, in: Chemical Sensor Technology, edited by T. Seiyama (Elsevier, Amsterdam, 1988), pp. 39–55
E. Souteyrand, in: Les Capteurs Chimiques, edited by C. Pijolat (CMC2, Ecole Centrale de Lyon, 1997), pp. 52–62
T. H. Wolkenstein, The Electronic Theory of Catalysis on Semi-conductors (Pergamon, Oxford, 1963)
H. Idriss and M. A. Barteau, Active sites on oxides: from single crystals to catalysts, Adv. Catal. 45, 261–331 (2000)
A. Cimino and F. S. Stone, Oxide sold solutions as catalysts, Adv. Catal. 47, 141–306 (2002)
H.-J. Freund, M. Bäumer, and H. Kuhlenbeck, Catalysis and surface science: what do we learn from studies of oxide-supported cluster model systems? Adv. Catal. 45, 333–384 (2000)
S. M. Kudryavtseva, A. A. Vertegel, S. V. Kalinin, N. N. Oleynikov, L. I. Ryabova, L. L. Meshkov, S. N. Nesterenko, M. N. Rumyantseva, and A. M. Gaskov, Effect of micro structure on the stability of nanocrystalline tin dioxide ceramics, J. Mater. Chem. 7, 2269–2272 (1997)
O. Safonova, I. Bezverkhy, P. Fabritchny, M. Rumyantseva, and A. Gaskov, Mechanism of sensing CO in nitrogen by nanocrystalline SnO2 and SnO2(Pd) studied by Mossbauer spectroscopy and conductance measurements, J. Mater. Chem. 12, 1174–1178 (2002)
M. N. Rumyantseva, O. V. Safonova, M. N. Boulova, L. I. Ryabova, and A. M. Gaskov. Dopants in nanocrystalline tin dioxide, Russ. Chem. Bull. 52(6), 1217–1238 (2003)
M. N. Rumyantseva, V. V. Kovalenko, A. M. Gaskov, T. Pagnier, D. Machon, J. Arbiol, and J. R. Morante, Nanocomposites SnO2/Fe2O3: wet chemical synthesis and nanostructure characterization, Sens. Actuators B 109(1), 64–74 (2005)
E. A. Makeeva, M. N. Rumyantseva, and A. M. Gaskov, Synthesis, micro structure and gas-sensing properties of SnO2/MoO3 nanocomposites, Inorg. Materials 41(4), 370–377 (2005)
M. N. Rumyantseva, A. M. Gaskov, N. Rosman, T. Pagnier, and J. R. Morante, Raman surface vibration modes in nanocrystalline SnO2 prepared by wet chemical methods: correlations with the gas sensors performances, Chem. Mater. 17(4), 893–901 (2005)
V. V. Yuscshenko, Calculation of the acidity spectra of catalysts from temperature — programmed ammonia desorption data, Zh. Fiz. Khim. 71, 628–632 (1997)
R. D. Shannon and C. T. Prewitt, Effective ionic radii in oxides and fluorides, Acta Cryst. B 25, 925–949 (1969)
P. B. Fabrichnyi, A. M. Babeshkin, A. N. Nesmeyanov, and V. N. Onuchak, Mössbauer effect on tin-119 impurity nuclei in α-ferric oxide, Fiz. Tverd. Tela 12, 2032–2034 (1970)
V. V. Kovalenko, M. N. Rumyantseva, P. B. Fabritchnyi, and A. M. Gaskov, The unusual distribution of the constituants in the (Fe2O3)0.8(SnO2)0.2 nanocomposite evidenced by 57Fe and 119Sn Mössbauer spectroscopy, Mendeleev Commun. 14(4), 140–141 (2004)
L. Abello, B. Bochu, A. Gaskov, S. Koudryavtseva, G. Lucazeau, and M. Rumyantseva, Structural characterization of nanocrystalline SnO2 by X-Ray and Raman Spectroscopy, J. Solid State Chem. 135, 78–85 (1998)
M. Boulova, A. Galerie, A. Gaskov, and G. Lucazeau, Reactivity of SnO2-CuO nanocrystalline materials with H2S: a coupled electrical and Raman spectroscopic study, Sens. Actuators B 71, 134–139 (2000)
W. Kündig, H. Bömmel, G. Constabaris, and R. H. Lindquist, Some properties of supported small α-Fe2O3 particles determined with the Mössbauer effect, Phys. Rev. 142, 327–333 (1966)
P. B. Fabritchnyi, A. M. Babeshkin, and A. N. Nesmeianov, Etude par effet Mössbauer de structure hyperfine nucleaire de 119Sn dans α-Fe2O3, J. Phys. Chem. Solids 32, 1701–1703 (1971)
P. B. Fabritchnyi, E. V. Lamykin, A. M. Babeshkin, and A.N. Nesmeianov, Étude de transition de morin dans l’hématite (α-Fe2O3) contenant l’impureté d’étain par effet Mössbauer sur 119Sn et 57Fe, Solid State Commun. 11, 343–348 (1972)
V. V. Berentsveig, Z. A. Hasan, P. B. Fabritchnyi, T. M. Ivanova, and A. P. Rudenko, Physico-chemical properties of iron-tin mixed oxide catalysts in cyclohexane oxidation, React. Kinet. Catal. Lett. 15, 239–243 (1980)
D. A. Khramov and V. S. Urusov, Study of solid solutions in α-Fe2O3-SnO2 by Mössbauer effect, Inorg. Materials 19(11), 1880–1886 (1983)
S. Ichiba and T. Yamaguchi, Mössbauer study of tin in α-Fe2O3, Chem. Lett. 13(10), 1681–1682 (1984)
F. Schneider, K. Melzer, H. Mehner, and G. Dehe, Tin-119 hyperfine fields in α-Fe2O3, Phys. Status Solidi A 39(2), K115–K117 (1977)
F. J. Berry, C. Greaves, J. G. McManus, M. Mortimer, and G. Oates, The structural characterization of tin- and titanium-doped α-Fe2O3 prepared by hydrothermal synthesis, J. Solid State Chem. 130(2), 272–276 (1997)
V. V. Kovalenko, Synthesis of SnO2-Fe2O3 and SnO2-V2O5 nanocomposites and study of interaction of them with the gas phase, Ph.D. thesis (Moscow State University, 2006)
J. Arbiol, J. R. Morante, P. Bouvier, T. Pagnier, E. Makeeva, M. Rumyantseva, and A. Gaskov, SnO2/MoO3-nanostructure and alcohol detection, Sens. Actuators B 118, 156–162 (2006)
F. Harb, B. Gerand, G. Nowogrocki, and M. Figlarz, Structural filiation between a new molybdenum oxide hydrate (MoO3l/3H2O) and a new monoclinic form of MoO3 obtained by dehydration, Solid State Ionics 32–33, 84–90 (1989)
M. S. Moreno, R. F. Egerton, and P.A. Midgley, Differentiation of tin oxides using electron energy-loss spectroscopy, Phys. Rev. B 69, 233304/1–233304/4 (2004)
M. S. Moreno, R. F. Egerton, J. J. Rehr, and P. A. Midgley, Electronic structure of tin oxides by electron energy loss spectroscopy and real-space multiple scattering calculations, Phys. Rev. B 71, 035103/1–035103/6 (2005)
D. Wang, D. S. Su, and R. Schlögl, Electron beam induced transformation of MoO3 to MoO2 and a new phase MoO, Z. Anorg. Allg. Chem. 630, 1007–1014 (2004)
A. A. Tsyganenko, D. V. Pozdnyakov, and V. N. Filimonov, Infrared study of surface species arising from ammonia adsorption on oxide surfaces, J. Mol. Struct. 29, 299–318 (1975)
I. E. Wachs, J.-M. Jehng, and W. Ueda, Determination of the chemical nature of active surface sites present on bulk mixed metal oxide catalysts, J. Phys. Chem. B 109, 2275–2284 (2005)
C. Morterra, M. P. Mentruit, and G. Cerrato, Acetonitrile adsorption as an IR spectroscopic probe for surface acidity/basicity of pure and modified zirconias, Phys. Chem. Chem. Phys. 4, 676–687 (2002)
B. M. Reddy, K. Narsimha, C. Sivaraj, and P. K. Rao, Titration of active sites for partial oxidation of methanol over V2O5/SnO2 and MoO3/SnO2 catalysts by a low-temperature oxygen chemisorption technique, Appl. Catal. 55, L1–L4 (1989)
P. J. Pomonis and J. C. Vickerman, Methanol oxidation over vanadium-containing model oxide catalysts influence of charge-transfer effects on selectivity, Faraday Discuss. Chem. Soc. 71, 247–262 (1981)
K. Chen, A. T. Bell, and E. Iglesia, Kinetics and mechanism of oxidative dehydrogenation of propane on vanadium, molybdenum, and tungsten oxides, J. Phys. Chem. B 104, 1292–1299 (2000)
V. V. Kovalenko, A. A. Zhukova, M. N. Rumyantseva, A. M. Gaskov, V. V. Yushchenko, I. I. Ivanova, and T. Pagnier, Surface chemistry of nanocrystalline SnO2: Effect of thermal treatment and additives, Sens. Actuators B 126, 52–55 (2007)
V. A. Burmistrov, Hydrated Oxides of IV and V Groups (Nauka, Moscow, 1986)
M. W. Abee and D.F. Cox, NH3 chemisorption on stoichiometric and oxygen-deficient SnO2 (110) surfaces, Surf. Science 520, 65–77 (2002)
G. Ramis, M. A. Larrubia, and G. Busca, On the chemistry of ammonia over oxide catalysts: Fourier transform infrared study of ammonia, hydrazine and hydroxylamine adsorption over iron-titania catalyst, Topics in Catal. 11/12, 161–166 (2000)
M. Rumyantseva, V. Kovalenko, A. Gaskov, E. Makshina, V. Yushchenko, I. Ivanova, A. Ponzoni, G. Faglia, and E. Comini, Nanocomposites SnO2/Fe2O3: sensor and catalytic properties, Sens. Actuators B 118, 208–214 (2006)
H.-Y. Lin, Y.-W. Chen, and C. Li, The mechanism of reduction of iron oxide by hydrogen, Thermochim. Acta 400, 61–67 (2003)
X. Wang, and Y.-C. Xie, Total oxidation of CH4 on iron-promoted tin oxide: novel and thermally stable catalysts, React. Kinet. Catal. Lett. 72, 229–237 (2001)
P. W. Park, H. H. Kung, D.-W. Kim, and M. C. Kung, Characterization of SnO2/Al2O3 lean NOX catalysts, J. Catal. 184, 440–454 (1999)
F. Okada, A. Satsuma, A. Furuta, A. Miyamoto, T. Hattori, and Y. Murakami, Surface active sites of V2O5-SnO2 catalysts, J. Phys. Chem. 94, 5900–5908 (1990)
M. Niwa, Y. Habuta, K. Okumura, and N. Katada, Solid acidity of metal oxide monolayer and its role in catalytic reactions, Catal. Today 87, 213–218 (2003)
Y. Habuta, N. Narishige, K. Okumura, N. Katada, and M. Niwa, Catalytic activity and solid acidity of vanadium oxide thin layer loaded on TiO2, ZrO2, and SnO2, Catal. Today 78,131–138 (2003)
M. Ai, The oxidation activity and acid-base properties of SnO2-based binary catalysts. I. The SnO2-V2O5 system, J. Catal. 40, 318–326 (1975)
E. M. Gaigneaux, S. R. G. Carrazan, P. Ruiz, and B. Delmon, Role of the mutual contamination in the synergetic effects between MoO3 and SnO2, Thermochim. Acta 388, 27–40 (2002)
P. Arnoldy, J. C. M. De Jonge, and J. A. Moulijn, Temperature-programmed reduction of molybdenum(VI) oxide and molybdenum(IV) oxide, J. Phys. Chem. 89, 4517–4526 (1985)
F. Goncalves, P. R. S. Medeiros, J. G. Eon, and L. G. Appel, Active sites for ethanol oxidation over SnO2-supported molybdenum oxides, Appl. Catal. A 193, 195–202 (2000)
N. G. Valente, L. A. Arrua, and L. E. Cadus, Structure and activity of Sn-Mo-O catalysts: partial oxidation of methanol, Appl. Catal. A 205, 201–214 (2001)
T. Jinkawa, G. Sakai, J. Tamaki, N. Miura, and N. Yamazoe, Relationship between ethanol gas sensitivity and surface catalytic property of tin oxide sensors modified with acidic or basic oxides, J. Mol. Catal. A 155, 193–200 (2000)
H. Idriss, and E. G. Seebauer, Reactions of ethanol over metal oxides, J. Mol. Catal. A 152, 201–212 (2000)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2009 Springer Science + Business Media B.V
About this paper
Cite this paper
Gaskov, A., Rumyantseva, M. (2009). Metal Oxide Nanocomposites: Synthesis and Characterization in Relation with Gas Sensing Phenomena. In: Baraton, MI. (eds) Sensors for Environment, Health and Security. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-9009-7_1
Download citation
DOI: https://doi.org/10.1007/978-1-4020-9009-7_1
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-9010-3
Online ISBN: 978-1-4020-9009-7
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)