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Carbon Nanomaterials in Clean Energy Hydrogen Systems pp 241–250Cite as

Esr Study Of Hydrogen Sorption/Desorption Kinetics In Poly(Ortho-Anisidine) And Poa/Swnts Composite Films

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Abstract

The cyclic hydrogen storage properties of poly(ortho-anisidine) (POA) and POA/SWNTs composite films have been investigated using the ESR spectroscopy. The ESR signals with g ͌ 2.0033 were observed in both types of the initial films for the first time. The temperature dependencies of ESR parameters suggest the polaron origin of the paramagnetic states in these films. A substantial effect due to oxygen, stored within the films, has been observed in the ESR response of composite films as well.

A strong increase of the ESR signal has been detected for composite samples kept in hydrogen atmosphere at pressure of ̃1.1 bar at room temperature. The less pronounced effect of hydrogen has been detected for the pure polymer films. The kinetics of the hydrogen adsorption — desorption processes in the samples was investigated and the results was interpreted in the frame of the hydrogen physisorption processes. The discussion of the H-induced effects in polymer and composite was carried out taking into account the morphology of the samples and the presence of paramagnetic defects.

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Author information

Authors and Affiliations

  1. Institute of Semiconductor Physics, NAS of Ukraine, 45 Pr. Nauki, Kyiv, 03028, Ukraine

    A. A. Konchits, S. P. Kolesnik, V. S. Yefanov & F. V. Motsnyi

  2. Dipartimento di Scienze e Technologie Chimiche and INFM Universita di Roma“Tor Vergata”, Via del politecnico 1, Roma, 00133, Italy

    E. Tamburri & M. -L. Terranova

Authors
  1. A. A. Konchits
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  2. S. P. Kolesnik
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  3. V. S. Yefanov
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  4. F. V. Motsnyi
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  5. E. Tamburri
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  6. M. -L. Terranova
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Editor information

Editors and Affiliations

  1. Institute of Physical Chemistry of PAS, Warsaw, Poland

    Bogdan Baranowski

  2. Institute of Hydrogen and Solar Energy, Kiev, Ukraine

    Svetlana Yu. Zaginaichenko

  3. Institute for Problems of Materials Science of NAS, Kiev, Ukraine

    Dmitry V. Schur  & Valeriy V. Skorokhod  & 

  4. International Association for Hydrogen Energy, University of Miami, Miami, USA

    Ayfer Veziroglu

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Konchits, A.A., Kolesnik, S.P., Yefanov, V.S., Motsnyi, F.V., Tamburri, E., Terranova, M.L. (2008). Esr Study Of Hydrogen Sorption/Desorption Kinetics In Poly(Ortho-Anisidine) And Poa/Swnts Composite Films. In: Baranowski, B., Zaginaichenko, S.Y., Schur, D.V., Skorokhod, V.V., Veziroglu, A. (eds) Carbon Nanomaterials in Clean Energy Hydrogen Systems. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8898-8_24

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