ENERGETICS OF METAL HYDRIDES FORMATION IN ELECTROCHEMICAL SYSTEMS

Zvyagintseva, A. V.; Shalimov, Y. N.

doi:10.1007/978-1-4020-8898-8_16

A. V. Zvyagintseva⁵ &
Y. N. Shalimov⁵

Part of the book series: NATO Science for Peace and Security Series C: Environmental Security ((NAPSC))

1412 Accesses

Abstract

We have determined that in low-temperature annealing conditions for Cr-samples (t_annealing < 300°?) the secondary hydrogenation is possible which is proved by the fixation of damping peak on the graphic chart Q⁻ = f(T). The amount of the absorbed hydrogen accurate within the experimental error proves that all hydrogen is fixed on the borders of structure's defects. The character of distribution confirms with the result received by the experiment. Current density distribution is rather homogeneous (difference between the center and angular point does not exceed 12%) and is characterized by smooth variation along electrode surface.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Chapter: USD 29.95; Price excludes VAT (USA)

eBook: USD 129.00; Price excludes VAT (USA)

Softcover Book: USD 169.99; Price excludes VAT (USA)

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

References

Makkey K. Hydrogen metals' compounds. Moscow: Mir Press: 1968, 244 p
Google Scholar
Povetkin V.V., Kovenski I.M. The structure of electrolitic coatings. Moscow: Metallurgiya, 1989, 136 p. (in Russian)
Google Scholar
Sadakov G.A. Galvanoplastics. Moscow: Energoatomizdat, 1987, 288 p. (in Russian)
Google Scholar
Zvyagintseva A.V., Falicheva A.I. Physico-mechanical properties of Ni coatings alloyed by boron/electroplating and surfaces processing. Galvanotekhnika i obrabotka poverkhnosti, 19975 (2): 24–31. (in Russian)
CAS Google Scholar
Soltsev Y.P., Pryakhin E.M. Materials science: Text book for higher educational institutions. Saint-Petersburg: Himizdat Press: 2004, 736 p
Google Scholar
Dukovic I., Tobias Ch.W. The influence of attached bubbes on potential drop and current distribution at gasevolving electrodesJournal of Electrochemical Society, 1987134 (2): 331–342
Article CAS Google Scholar
Zvyagintseva A.V. Boron influence on Ni film hydrogen saturationAlternative Power Engineering and Ecology, 2006 (5): 85–87
Google Scholar

Download references

Author information

Authors and Affiliations

Voronezh State Technical University, Voronezh, 394026, Russia
A. V. Zvyagintseva & Y. N. Shalimov

Authors

A. V. Zvyagintseva
View author publications
You can also search for this author in PubMed Google Scholar
Y. N. Shalimov
View author publications
You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

Institute of Physical Chemistry of PAS, Warsaw, Poland
Bogdan Baranowski
Institute of Hydrogen and Solar Energy, Kiev, Ukraine
Svetlana Yu. Zaginaichenko
Institute for Problems of Materials Science of NAS, Kiev, Ukraine
Dmitry V. Schur & Valeriy V. Skorokhod &
International Association for Hydrogen Energy, University of Miami, Miami, USA
Ayfer Veziroglu

Rights and permissions

Reprints and permissions

Copyright information

About this paper

Cite this paper

Zvyagintseva, A.V., Shalimov, Y.N. (2008). ENERGETICS OF METAL HYDRIDES FORMATION IN ELECTROCHEMICAL SYSTEMS. In: Baranowski, B., Zaginaichenko, S.Y., Schur, D.V., Skorokhod, V.V., Veziroglu, A. (eds) Carbon Nanomaterials in Clean Energy Hydrogen Systems. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8898-8_16

Download citation

DOI: https://doi.org/10.1007/978-1-4020-8898-8_16
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-8897-1
Online ISBN: 978-1-4020-8898-8
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)

Publish with us

Policies and ethics