Abstract
High porous carbon material was prepared by template synthesis. Ni-carbon materials were formed by deposition of Ni2+ salts into the carbon supporter pores and by following reducing of adsorbed Ni2+ to Ni. The structure peculiarities of nickel— carbon materials were studied by small-angle X-ray scattering methods. Obtaining Ni-carbon materials used as electrodes in proton pump were enabled to raise its power and to reduce the price. The Ni-nanocarbon electrodes in proton pump have shown the high catalytic activity in electrode processes of hydrogen ionization. It was demonstrated the influence of proton current on the rate of some catalytic reactions such as propene hydration, isopropyl alcohol dehydration, synthetic gas to dimethyl ether conversion and isopropylbenzene hydrocracking. The use of Ni-carbon nanostructured materials as electrodes and proton current increases essentially the hydrogenating function of industrial catalysts in isopropylbenzene hydrocracking process.
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References
Yevdokymenko V.O., Bortyshevskyy V.A., Melnykova S.L. Membrane catalyst of olefins hydration. Hydrated proton influence into productivity. Chemical Industry of Ukraine 2005; 1: 44–47
Tkachenko T.V., Bortyshevskyy V.A., Motorniy V.G. New method for investigation of proton transport in organic ion-exchanging membranes. Catalysis and Petrochemistry 2003; 12: 84–88
Smotkin E.S. Hydrogen permeable membrane for use in fuel cells and partial reformate fuel cell system having reforming catalysts in the anode fuel cell compartment. Pat. US 2002/0031695A1. Publ. 2002, Mar 14
Barata-Rodrigues P.M., Mays T.J., Moggridge G.D. Structured carbon adsorbents from clay, zeolite, and mesoporous aluminosilicate templates. Carbon 2003; 41(12): 2231–2246
Vasiliev A.N., Golovko L.V., Povazhny V.A., Zlotnikov E., Chen J., Khinast J.G. Functionalized nanoporous carbon as a catalyst for Suzuki coupling reactions. Microporous and Mesoporous Materials 2007; 101(3): 342–347
Stiles A.B. Catalyst supports and supported catalysts: Theoretical and applied concepts. Stoneham, MA: Butterworths, 1987
Vonk C.G. FFSAXS's Program for the processing of small-angle Xxray scattering data. Geleen: DSM, 1974
Beaucage G. Small-angle scattering from polymeric mass fractals of arbitrary mass-fractal dimension. Journal of Applied Crystallography 1996; 29(2): 134–146
Boehm H.P. Some aspects of the surface chemistry of carbon blacks and other carbons. Carbon 1994; 32(5): 759–769
Korshak V.V., Sladkov A.M., Kudryavtsev Yu.P. Synthesis of acetylene polymers. High Molecular Compounds 1960; 2(12): 1824–1827
Lunin A.F., Paushkin Ya.M. Homopolycondensation of carbamide to polycyanamide -nitrogen-containing polymer with conjugated bonds. High Molecular Compounds 1964; 6 (8): 1467–1469
Radchenko E.D., Nefedov P.K., Alyiev R.R. Industrial catalysts of hydrogenation processes refining. Moscow, RU: Chemistry, 1987
Golovko L., Gomza Yu., Bortyshevskyy V., Nesin S., Povazhny V., Kamenskyh D. Structure peculiarities and catalytic activity of nickel nanoclusters in carbon nanopores. Thesis of the 2nd International Conference on Surfaces, Coatings and Nanostructured Materials. Alvor, Algarve, Portugal, 9–11 July 2007, P. 306
Frumkin A.N. Selected works. Electrode processes. Moscow, RU: Science, 1987
Koryta J., Dvorak J., Bogachkova V. Electrochemistry. Moscow: Mir, 1977, 472 p. (in Russian)
Faro Jr. A.C., dos Santos A.C.B. Cumene hydrocracking and thiophene HDS on niobia-supported Ni, Mo and Ni-Mo catalysts. Catalysis Today 2006; 118: 402–409
Yevdokymenko V.O. Isopropanol obtaining over proton conductive catalytic membranes. Abstract of the candidate's dissertation. Kiyv, UA, 2005
Tkachenko T.V., Bortyshevskyy V.A. Proton pump use for alcohol dehydration. Thesis of the V Ukrainian Science Conference. “Modern Problems of Chemistry”. Kiyv, 2004. P. 123
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Bortyshevskyy, V.A. et al. (2008). SYNTHESIS OF CARBONIC-NICKEL NANOSTRUCTURES AND THEIR APPLICATION FOR PROTON PUMPS. In: Baranowski, B., Zaginaichenko, S.Y., Schur, D.V., Skorokhod, V.V., Veziroglu, A. (eds) Carbon Nanomaterials in Clean Energy Hydrogen Systems. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8898-8_12
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DOI: https://doi.org/10.1007/978-1-4020-8898-8_12
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