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Aldehyde and Carboxy Functional Polysiloxanes

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Silicon Based Polymers

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Abstract

Aldehyde functional polysiloxanes (1) (Fig. 1) can be selectively prepared in high yield and purity by oxidation of the corresponding carbinols with -technical bleach and catalytic amounts of TEMPO. This simple oxidation method is also successfully used for the preparation of the corresponding carboxylic acids 2 (Fig. 1). The stability, reactivity and chemical properties of new compounds 1 and 2 are -investigated.

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Authors and Affiliations

  1. Wacker Chemie AG, Consortium für elektrochemische Industrie, Zielstattstraβe 20-22, D-81379, München, Germany

    Elke Fritz-Langhals

Authors
  1. Elke Fritz-Langhals
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Correspondence to Elke Fritz-Langhals .

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Editors and Affiliations

  1. Ecole Nationale Supérieure de Chimie de Montpellier, UMR 5253 - Institut Charles Gerhardt, Ingénierie et Architectures Macromoléculaires, 8 rue de l’Ecole Normale, 34296, Montpellier CX 05, France

    François Ganachaud

  2. Institut de Chimie et des Matériaux, Paris-Est (ICMPE) SPC-CNRS, 2 à 8 rue Henri Dunant, 94320, Thiais, France

    Sylvie Boileau

  3. Université Montpellier II, Institut Charles Gerhardt, Chimie Moléculaire et organisation du solide, place Eugène Bataillon, 34095, Montpellier CX 05, France

    Bruno Boury

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Fritz-Langhals, E. (2008). Aldehyde and Carboxy Functional Polysiloxanes. In: Ganachaud, F., Boileau, S., Boury, B. (eds) Silicon Based Polymers. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8528-4_4

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