Abstract
Powders of mesoporous organosilica functionalized with a Non Linear Optical chromophore in the channel pore (azobenzene diethylphosphonate) were achieved in one step and were synthesized by templated-directed co-condensation of tetraethylorthosilicate (TEOS) and the functional organotriethoxysilanes. The materials were characterized by 13C, 31P and 29Si NMR experiments, nitrogen gas adsorption, powder X-ray diffractrion (XRD). Optically transparent and highly ordered multifunctional mesostructured fi lms obtained by evaporation induced self-assembly (EISA approach) approach were deposited on glass or silicon substrates by dipcoating. Thin fi lms were monofunctionalized in the channel pores or bifunctionalized (channel pore/framework) and allowed us to evidence the salt effect induced by an organometallic complex on the structure of the mesostructured fi lm. They were characterized by Grazing Incidence Small Angle X-ray Scattering (GISAXS) and X-ray refl ectivity.
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Besson, E., Mehdi, A., Réyé, C., Gibaud, A., Corriu, R.J.P. (2008). Direct synthesis of Mesoporous Hybrid Organic-Inorganic Silica Powders and Thin Films for Potential Non Linear Optic Applications. In: Ganachaud, F., Boileau, S., Boury, B. (eds) Silicon Based Polymers. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8528-4_16
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DOI: https://doi.org/10.1007/978-1-4020-8528-4_16
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