Abstract
Molecular sieve adsorbents have been prepared by the sol-gel route comprising simultaneous hydrolysis of tetraethylorthosilicate (TEOS) and polymerization of furfuryl alcohol (FA). The mixtures of TEOS (10%) and FA (90%) have been forced to interaction in the presence of small amounts of water (hydrolyzing agent) and sulfuric acid (polymerization catalyst) under ambient conditions, and successive carbonization at 923–1,023 K under argon. Adsorption of nitrogen at 77 K appears to be essentially non-equilibrium indicating activated character of diffusion. The ratio of CO2/N2 adsorption uptake at 1 bar changes from 9:1 for carbon, obtained without TEOS additives under other similar conditions, to ∼1:3 for carbon-silica composite, indicating the reciprocal change of the adsorption selectivity factor.
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Mel’Gunov, M.S., Vodennikov, A.N., Fenelonov, V.B. (2008). Sol-Gel Route to Carbon-Silica Molecular Sieving Adsorbents. In: Innocenzi, P., Zub, Y.L., Kessler, V.G. (eds) Sol-Gel Methods for Materials Processing. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8514-7_30
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DOI: https://doi.org/10.1007/978-1-4020-8514-7_30
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