Abstract
Molecular separation using membranes is widely considered as an energy-efficient alternative for conventional industrial separation techniques. For the preparation of such membranes sol-gel technology is highly suitable. Using sol-gel techniques thin (50–100 nm) amorphous nanoporous layers having pore sizes in the micropore (<2 nm) or fine mesoporous (<5 nm) region can be prepared on a porous substrate. These layered porous systems, usually in tubular form, can be used for nanofiltration, pervaporation and gas separation applications. The application window is dependent on the material properties, such as the pore size and pore size distribution, the interfacial properties of the pores, and the defect density. The success of this technology in actual industrial applications strongly depends on reproducible large scale production of the sol-gel membranes and on a sufficient stability of the membranes with respect to flux and selectivity. In addition the production cost of the full membrane system is an important aspect. Here, we will focus on the more chemical aspects in the membrane preparation. Main topics are synthesis and properties of the sols, the preparation of microporous thin films, and the search for membrane materials that have a high hydrothermal stability.
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References
M. Asaeda, Sol-gel derived ceramic membranes for separation of molecular mixtures, Porous. Ceram. Mater., Conf. Proc. (2005).
J. F. Vente, H. M. van Veen, and P. P. A. C. Pex, Microporous sol-gel membranes for molecular separations, Ann. Chim. Sci. Mat. 32(2), 231-244 (2007).
B. C. Bonekamp, A. van Horssen, L. A. Correia, J. F. Vente, and W. G. Haije, Macroporous support coatings for molecular separation membranes having a minimum defect density, J. Membr. Sci. 278(1-2), 349-356 (2006).
P. P. A. C. Pex and Y. C. van Delft, in: Carbon dioxide capture for storage in deep geo-logical formations, 1 ed., edited by D. C. Thomas, and S. M. Benson (Elsevier, Amsterdam, 2005), pp. 307-319.
C. J. Brinker, Porous inorganic materials, Curr. Opin. Solid State Mater. Sci. 1, 798-805 (1996).
H. M. van Veen, Y. C. van Delft, C. W. R. Engelen, and P. P. A. C. Pex, Dewatering of organics by pervaporation with silica membranes, Separ. Purif. Technol. 22-23, 361-366 (2001).
C. J. Brinker, R. Sehgal, S. L. Hietala, R. Deshpande, D. M. Smith, D. A. Loy, and C. S. Ashley, Sol-gel strategies for controlled porosity inorganic materials, J. Membr. Sci. 94, 85-102 (1994).
A. W. Burton and S. I. Zones, in: Introduction to zeolite science and practice, edited by J. Cejka, H. van Bekkum, A. Corma, and F. Schüth (Elsevier, Amsterdam, 2007), pp. 137-179.
C. J. Brinker and G. W. Scherer, Sol-gel science - the physics and chemistry of sol-gel processing (Academic, New York, 1990).
C. J. Brinker, N. K. Raman, M. N. Logan, R. Sehgal, R. A. Assink, D.-W. Hua, and T. L. Ward, Structure-property relations in thin films and membranes, J. Sol-gel Sci. Technol. 4, 117-133 (1995).
A. C. Pierre, Introduction to sol-gel processing (Kluwer, Dordrecht, The Netherlands, 1998).
A. J. Burggraaf, in: Fundamentals of inorganic membrane science and technology, edited by A. J. Burggraaf, and L. Cot (Elsevier, Amsterdam, 1996).
A. Rawle, The importance of particle sizing to the coatings industry Part 1: particle size measurement, Adv. Col. Sci. Technol. 5(1), 1-12 (2002).
C. J. Brinker, Review of sol-gel thin film formation, J. Non-cryst. Solids 147/148, 424-436 (1992).
A. J. Hurd and L. Steinberg, The physics of evaporation-induced assembly of sol-gel materials, Granul Matter 3(1-2), 19-21 (2001).
C. Nguyen, K. R. Carter, C. J. Hawker, R. L. Jaffe, R. D. Miller, J. F. Remenar, H.-W. Rhee, P. M. Rice, M. F. Toney, M. Trollsås, and D. Y. Yoon, Low-dielectric nanoporous organo-silicate films prepared via inorganic/organic polymer hybrid templates, Chem. Mater. 11, 3080-3085 (1999).
G. Reiter, Dewetting of thin polymer films, Phys. Rev. Lett. 68, 75-82 (1992).
R. M. de Vos and H. Verweij, High-selectivity, high-flux silica membranes for gas separation, Science 279, 1710-1711 (1998).
B. C. Bonekamp, in: Fundamentals of inorganic membrane science and technology, Volume 4, edited by A. J. Burggraaf and L. Cot (Elsevier, Amsterdam, 1996).
B. E. Yoldas, Alumina gels that form porous transparent Al2O3, J. Mater. Sci. 10, 1856-1860 (1975).
A. F. M. Leenaars, K. Keizer, and A. J. Burggraaf, The preparation and characterization of alumina membranes with ultra-fine pores, Part 1. Microstructural investigations on non supported membranes, J. Mater. Sci. 19, 1077 (1984).
J. Sekuliü, A. Magraso, J. E. ten Elshof, and D. H. A. Blank, Influence of ZrO2 addition on microstructure and liquid permeability of mesoporous TiO2 membranes, Micropor. Mesopor. Mater. 72, 49-57 (2004).
T. van Gestel, C. Vandecasteele, A. Buekenhoudt, C. Dotremont, J. Luyten, R. Leysen, B. van de Bruggen, and G. Maes, Alumina and titania multilayer membranes for nanofiltration: preparation, characterization and chemical stability, J. Membr. Sci. 207, 73-89 (2002).
R. S. A. de Lange, K. Keizer, and A. J. Burggraaf, Aging and stability of microporous sol- gel-modified ceramic membranes, Ind. Eng. Chem. Res. 34, 3838-3847 (1995).
R. J. Uhlhorn, Ceramic membranes for gas separation. Ph.D. thesis, University of Twente (1990).
R. M. de Vos and H. Verweij, Improved performance of silica membranes for gas separa- tion. J. Membr. Sci. 143, 37-51 (1998).
C. J. Brinker, C. Y. Tsai, and Y. Lu, Inorganic dual-layer microporous supported mem- branes. US Patent 6,536,604 (2003).
T. A. Peters, J. Fontalvo, M. A. G. Vorstman, N. E. Benes, R. A. van Dam, Z. A. E. P. Vroon, E. L. J. van Soest-Vercammen, and J. T. F. Keurentjes, Hollow fiber microporous silica membranes for gas separation and pervaporation. Synthesis, performance and stability, J. Membr. Sci. 248, 73-80 (2004).
R. M. de Vos, W. F. Maier, and H. Verweij, Hydrophobic silica membranes for gas separa- tion. J. Membr. Sci. 158(1-2), 277-288 (1999).
J. Campaniello, C. W. R. Engelen, W. G. Haije, P. P. A. C. Pex, J. F. Vente, Long-term pervaporation performance of microporous methylated silica membranes, Chem. Commun. 834-835 (2004).
T. Tsuru, T. Hino, T. Yoshioka, and M. Asaeda, Permporometry characterisation of micro-porous ceramic membranes, J. Membr. Sci., 186(2), 257-265 (2001).
K. J. Shea and D. A. Loy, Bridged polysilsesquioxanes, molecular-engineered hybrid organic- inorganic materials, Chem. Mater., 13, 3306-3319 (2001).
H. L. Castricum, A. Sah, R. Kreiter, D. H. A. Blank, J. F. Vente, and J. E. ten Elshof, Hybrid organosilica membranes: molecular separation under hydrothermal conditions. (submitted) (2007).
A. Sah, Chemically modified ceramic membranes - study of structural and transport proper- ties. Ph.D. thesis, University of Twente (2006).
D. A. Loy, J. P. Carpenter, T. M. Alam, R. Shaltout, P. K. Dorhout, J. Greaves, J. H. Small, and K. J. Shea, Cyclization phenomena in the sol-gel polymerization of α,ω-bis(triethoxysilyl)alkanes and incorporation of the cyclic structures into network silsesquioxane polymers, J. Am. Chem. Soc., 121, 5413-5425 (1999).
H. L. Castricum, R. Kreiter, J. F. Vente, and J. E. ten Elshof, to be published.
C. J. Brinker, W. L. Warren, and S. Wallace, in: Structure and imperfections in amorphous and crystalline silicon dioxide, edited by R. A. B. Devine, J.-P. Duraud, and E. Dooryhée (Wiley, Chichester, 2000), pp. 475-493.
R. M. van Ginhoven, H. Jónsson, B. Park, and L. R. Corrales, Cleavage and recovery of molecular water in silica, J. Phys. Chem. B, 109(21), 10936-10945 (2005).
T. A. Michalske and B. C. A. Bunker, Chemical kinetics model for glass fracture, J. Am. Ceram. Soc., 76, 2613-2618 (1993).
G. Dubois, W. Volksen, T. Magbitang, R. D. Miller, D. M. Gage, and R. H. Dauskardt, Molecular network reinforcement of sol-gel glasses, Adv. Mater., doi: 10.1002/adma.200701193 (2007).
G. I. Spijksma, Modification of zirconium and hafnium alkoxides - the effect of molecular structure on derived materials. Ph.D. thesis, University of Twente (2006).
G. A. Seisenbaeva, S. Gohil, and V. G. Kessler, Influence of heteroligands on the composi-tion, structure and properties of homo- an heteremetallic ziconium alkoxides. Decisive role of thermodynamic factors in their self-assembly, J. Mater. Chem., 21, 3177-3190 (2004).
G. A. Seisenbaeva, S. Gohil, and V. G. Kessler, Molecular design approach to a highly soluble and volatile bimetallic alkoxide of late transition metal and zirconium. Synthesis, X-ray single crystal and mass-spectral study of NiZr2(acac)(OiPr)9, Inorg. Chem. Commun., 10, 94-96 (2007).
G. I. Spijksma, H. J. M. Bouwmeester, D. H. A. Blank, and V. G. Kessler, Stabilization and destabilization of zirconium propoxide precursor by acetylacetone, Chem. Commun., 1874-1875 (2004).
L. Armelao, C. Eisenmenger-Sittner, M. Groenewolt, S. Gross, C. Sada, U. Schubert, E. Tondello, and A. Zattin, Zirconium and hafnium oxoclusters as molecular building blocks for highly dispersed ZrO2 or HfO2 nanoparticles in silica thin films, J. Mater. Chem., 15, 1838-1848 (2005).
U. Schubert, Organofunctional metal oxide clusters as building blocks for inorganic-organic hybrid materials, J. Sol-Gel Sci. Technol., 31, 19-24 (2004).
J. Sekuliü, J. E. ten Elshof, and D. H. A. Blank, A microporous titania membrane for nano-filtration and pervaporation, Adv. Mater., 16(17), 1546-1550 (2004).
S. E. Friberg and J. Sjöblom, in: Industrial applications of microemulsions, edited by C. Solans and H. Kunieda (Marcel Dekker, New York, 1997), pp. 267-277.
E. L. V. Goetheer, A. W. Verkerk, L. J. P. van den Broeke, E. de Wolf, B.-J. Deelman, G. van Koten, and J. T. F. Keurentjes, Membrane reactor for homogeneous catalysis in super-critical carbon dioxide, J. Catal., 219, 126-133 (2003).
G. Garnweitner and M. Niederberger, Nonaqueous and surfactant-free synthesis routes to metal oxide nanoparticles, J. Am. Ceram. Soc., 89(6), 1801-1808 (2006).
M. Niederberger, G. Garnweiter, F. Krumeich, R. Nesper, H. Cölfen, and M. Antonietti, Tailoring the surface and solubility properties of nanocrystalline titania by a nonaqueous in situ functionalization process, Chem. Mater., 16, 1202-1208 (2005).
G. I. Spijksma, C. Huiskes, N. E. Benes, H. Kruidhof, D. H. A. Blank, V. G. Kessler, H. J. M. Bouwmeester, Microporous zirconia-titania composite membranes derived from diethanolamine-modified precursors, Adv. Mater., 18, 2165-2168 (2006).
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Bonekamp, B.C., Kreiter, R., Vente, J.F. (2008). Sol-Gel Approaches in the Synthesis of Membrane Materials for Nanofiltration and Pervaporation. In: Innocenzi, P., Zub, Y.L., Kessler, V.G. (eds) Sol-Gel Methods for Materials Processing. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8514-7_3
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